Geochemical Features and Metallogenic Prediction of the Caixiashan‐Weiquan Area in the East Tianshan Region

The Caixiashan-Weiquan area is an important ore concentration area in the eastern Tianshan metallogenic belt. Firstly, this paper studies geochemical features of 1564 samples of 1:200000 stream sediments of the Matoutan mapsheet, where the Caixiashan and Weiquan deposits are located. Processing, analysis and explanation of exploration geochemical data play an important role in the procedure of finding the ore, which are related to whether the measured elements content of geochemical samples can effectively guide the work of mineral exploration. As a highly nonlinear dynamical system, the neural network is more analogous to the human brains in terms of principles and features compared with conventional geochemical approaches. It can adapt itself to the environment, sum up laws, complete pattern recognition. Secondly, the authors used the Kohonen neural network to classify all samples based on 10 mineralization elements of stream sediment samples in order to determine possible mineral ores, reduce the scope of ore targets and study indicator elements of the ninth group of samples, which is the mostly closest to the deposit. The results show that the neural network can delineate metallogenic prospective areas and is effective in the discovery of deep geochemical information.     

云南东川区播卡金矿地球化学分带模式及深部隐伏矿体预测

为了探索播卡深部的找矿空间及找矿方向,本文在播卡矿区钻孔样品分析数据的基础上,研究了播卡金矿床的元素富集规律、元素组合、元素异常在地表及空间的分布特征,建立了播卡金矿的原生晕分带模型、地球化学勘查模式,提出了不同深度的原生晕判别指标,在此基础上对播卡金矿的深部隐伏矿体进行了预测。结果显示播卡金矿的深部及邻区具有寻找隐伏矿体的良好前景。     

广西沙子江矿床深部及外围铀矿普查钻探施工技术

总结了广西资源县沙子江矿床深部及外围铀矿普查钻探施工技术。在花岗岩地层钻进中,解决了孔内漏水、掉块、垮孔及金刚石钻头寿命短、钻杆和钻杆接头磨损、钻孔弯曲等一系列问题。为在花岗岩地层钻进中积累了宝贵的钻探施工经验。     

Re–Os and U–Pb Geochronology of the Erlihe Pb–Zn Deposit, Qinling Orogenic Belt, Central China, and Constraints on Its Deposit Genesis

The Erlihe Pb–Zn deposit is an important mine of the Pb–Zn metallogenic zone in the South Qinling Orogen. It has been considered a sedimentary exhalative deposit in previous investigations because the ore body occurs concordantly at the transitional location of an upright fold. Re and Os isotopic analyses for paragenetic pyrites with sphalerite and galena from the ore body have been used to determine the timing of mineralization and to trace the source of metallogenic materials. The Re–Os isotopic data of four pyrite samples construct an isochron, yielding a weighted average age of 226±17 Ma (mean square weighted deviation=1.7), which is considered the main mineralization age. A dioritic porphyrite vein sample, showing weaker mineralization, was also dated using the SHRIMP zircon U–Pb isotopic method to constrain the youngest metallogenic age of the ore deposit, because it distributes along a group of tensional joints cutting not only the upright fold in the deposit field, but also the main ore bodies. The dioritic porphyrite sample yields a weighted mean 206Pb/238U age of 221±3 Ma, which is slightly younger than the Re–Os isotopic isochron age of the pyrites, considered as the upper age limit of the mineralization, namely the ending age of the mineralization. The Os isotopic compositions of sulfide minerals distribute within a range between Os isotopic compositions of the crust and the mantle, indicating that the ore deposit can be derived from magma-related fluid, and the metallogenic materials are most likely derived from the mixing source of the crust and the mantle. The Erlihe Pb–Zn deposit and associated dioritic porphyrite vein, important records of Qinling tectonic–magmatism–mineralization activities, were formed during the Triassic collisional orogeny processes.     

降扎铀矿床的成矿规律

通过对降扎铀矿床地质条件的分析,总结了矿床围岩蚀变、控矿构造形式、矿石矿物特征、铀矿体主要特征、矿物组合、成矿流体、盲矿体地表放射性物化探异常等矿床特征和成矿规律,指出向阳沟矿段等已知矿段深部、向阳沟以西地段、热乎东地段为以后的找矿靶区.     

黔西北青杠林铅锌矿区隐伏矿体预测

通过对青杠林铅锌矿床地质、地球物理及地球化学信息进行分析,归纳提取了地质和物化探找矿标志,建立了该矿的地质一地球物理一地球化学找矿模型,并进行隐伏铅锌矿体预测,对青杠林矿区重点地区实施工程查证。     

示波极谱法测量电锌液中微量镍

提出在丁二酮肟-亚硝酸钠-氨水-氯化铵体系中,准确测定电锌液中微量镍的新方法:克服原子吸收光谱法测定微量镍回收率偏低问题。     

芦苇、菖蒲和水葱对水体中Zn2+的富集效应研究

采用水培方法,在不同ZnCl2浓度(0mg/L、50mg/L、100mg/L、300mg/L、800mg/L、1500mg/L和2500mg/L)处理的水体中,对湿地植物芦苇(Phragmites australis)、菖蒲(Acorus calamus)和水葱(Scirpus tabernaemontani)进行培养,研究植物的不同部位对Zn2+的积累能力。结果表明,在相同ZnCl2浓度处理下的水体中,水葱、菖蒲和芦苇体内的平均Zn2+积累浓度存在差异,菖蒲体内的Zn2+积累浓度最高。在不同ZnCl2浓度处理下的水体中,水葱体内的平均Zn2+积累浓度在ZnCl2浓度为1500mg/L时最高,为31050.84mg/kg(植物地上部分为10206.67mg/kg,地下部分为20844.17mg/kg);菖蒲和芦苇体内的平均Zn2+积累浓度则在ZnCl2浓度为2500mg/L时最高,分别为54130.67mg/kg(地上部分为16774.00mg/kg,地下部分为37356.67mg/kg)和25423.34mg/kg(地上部分为4506.67mg/kg,地下部分为20916.67mg/kg)。这3种植物都可以作为利用植物修复重金属污染水体的遴选物种。其中,菖蒲对Zn2+的吸收能力明显高于水葱和芦苇。     

The origin of the Maozu carbonate-hosted Pb–Zn deposit,southwest China: Constrained by C–O–S–Pb isotopic compositions and Sm–Nd isotopic age

The Maozu Pb–Zn deposit, located on the western margin of the Yangtze Block, southwest China, is a typical carbonate-hosted deposit in the Sichuan–Yunnan–Guizhou Pb–Zn metallogenic province with Pb + Zn reserves of about 2.0 million tonnes grading 4.15 wt.% Pb and 7.25 wt.% Zn. Its ore bodies are hosted in Sinian (635–541 Ma) Dengying Formation dolostone and show stratiform, vein and irregular textures. Ores are composed of sphalerite, galena, pyrite, calcite, dolomite, quartz and fluorite with massive, banded, disseminated and veined structures. The C–O–Sm–Nd isotopic compositions of hydrothermal calcites and S–Pb isotopic compositions of sulfides were analyzed to constrain the origin of the Maozu deposit. δ¹³C_PDB and δ¹⁸O_SMOW values of hydrothermal calcites range from −3.7‰ to −2.0‰ and +13.8‰ to +17.5‰, respectively, and plot near the marine carbonate rocks field in a plot of δ¹³C_PDB vs. δ¹⁸O_SMOW, with a negative correlation. It suggests that CO₂ in the hydrothermal fluids was mainly originated from marine carbonate rocks, with limited influence from sedimentary organic matter. δ³⁴S_CDT values of sulfides range from +9.9‰ to +19.2‰, similar to that of Cambrian to Triassic seawater sulfate (+15‰ to +35‰) and evaporate (+15‰ to +30‰) in the Cambrian to Triassic sedimentary strata. It suggests that reduced sulfur was derived from evaporate in sedimentary strata by thermo chemical sulfate reduction. Sulfides have low radiogenic Pb isotope compositions (²⁰⁶Pb/²⁰⁴Pb = 18.129–18.375, ²⁰⁷Pb/²⁰⁴Pb = 15.640–15.686 and ²⁰⁸Pb/²⁰⁴Pb = 38.220–38.577) that plot in the field between upper crust and the orogenic belt evolution curve in the plot of ²⁰⁷Pb/²⁰⁴Pb vs. ²⁰⁶Pb/²⁰⁴Pb, and similar to that of age corrected Proterozoic basement rocks (Dongchuan and Kunyang Groups). This indicates that ore-forming metals were mainly derived from basement rocks. Hydrothermal calcite yields a Sm–Nd isotopic age of 196 ± 13 Ma, possibly reflecting the timing of Pb–Zn mineralization in the SYG province, younger than the Permian Emeishan mantle plume (∼260 Ma). All data combined suggests that hydrothermal fluids circulated through basement rocks where they picked up metals and migrated to surface, mixed with reduced sulfur-bearing fluids and precipitated metals. Ore genesis of the Maozu deposit is different from known magmatic–hydrothermal, Sedimentary Exhalative or Mississippi Valley-types, which maybe represent a unique ore deposit type, named as the SYG-type.     

云南维西娃渣铁铅锌多金属矿床

矿床属与中三叠统中酸性火山岩有关的喷流型（或火山沉积改造型）铁铅锌多金属矿,并受地层构造双重控制.