发射光谱法测定区域化探样品中的Pb、Sn、Mo、V元素

采用发射光谱法测定区域化探样品中Pb、Sn、Mo、V元素,以焦硫酸钾、氟化钠、三氧化二铝和碳粉的混合物为固体缓冲剂,采用外加内标法以锗（Ge）作为内标元素,选择合适的分析线对,选取国家一级地球化学标准物质（GBW水系沉积物、土壤）平行测定（n=12次）.测试结果准确度达到规范要求,满足区域化探样品的检测要求.     

Zircon U–Pb and Wolframite Sm–Nd Dating of the Bayinsukhtu Tungsten Deposit in Southern Mongolia and its Geological Significance

The Bayinsukhtu tungsten deposit is a newly discovered quartz‐vein tungsten deposit in the Xing'an–Mongolia Orogenic Belt (XMOB) in southern Mongolia, hosted by the Bayinsukhtu granite porphyry. The granite porphyry is located mainly south of the study area, over 3 km². The rock consists of quartz and feldspar phenocrysts in a fine‐grained matrix, also mainly composed of feldspar and quartz. The granite porphyry samples demonstrate high SiO₂ and high alkalinity. All samples also straddle the high‐potassium calc‐alkaline series. In a plot of the molar ratios of A/NK versus A/CNK, the granites are metaluminous. The chondrite‐normalized REE patterns are characterized by large negative Eu anomalies and fractionated LREEs. The U–Pb age of zircons from the granite porphyry is 298.8 ± 1.8 Ma, and the Sm–Nd age of the five wolframite samples from the tungsten deposit is 303 ± 19 Ma. The cooling age of the granite porphyry and tungsten mineralization is within the error of measurement and is of the Late Carboniferous age. Geological and geochronological evidence shows that the tungsten mineralization and the granite porphyry at Bayinsukhtu are genetically closely related and that they are results of Carboniferous magmatism. Their tectonic setting is related to the accretion of the Central Asian Orogenic Belt during the late Paleozoic era.     

Middle Jurassic–Early Cretaceous tectonic evolution of the Bayanhushuo area,southern Great Xing’an Range,NE China: constraints from zircon U–Pb geochronological and geochemical data of volcanic and subvolcanic rocks

This study presents new zircon U–Pb geochronology, geochemistry, and zircon Hf isotopic data of volcanic and subvolcanic rocks that crop out in the Bayanhushuo area of the southern Great Xing’an Range (GXR) of NE China. These data provide insights into the tectonic evolution of this area during the late Mesozoic and constrain the evolution of the Mongol–Okhotsk Ocean. Combining these new ages with previously published data suggests that the late Mesozoic volcanism occurred in two distinct episodes: Early–Middle Jurassic (176–173 Ma) and Late Jurassic–Early Cretaceous (151–138 Ma). The Early–Middle Jurassic dacite porphyry belongs to high-K calc-alkaline series, showing the features of I-type igneous rock. This unit has zircon ε_Hf(t) values from +4.06 to +11.62 that yield two-stage model ages (T_DM2) from 959 to 481 Ma. The geochemistry of the dacite porphyry is indicative of formation in a volcanic arc tectonic setting, and it is derived from a primary magma generated by the partial melting of juvenile mafic crustal material. The Late Jurassic–Early Cretaceous volcanic rocks belong to high-K calc-alkaline or shoshonite series and have A₂-type affinities. These volcanics have ε_Hf(t) and T_DM2 values from +5.00 to +8.93 and from 879 to 627 Ma, respectively. The geochemistry of these Late Jurassic–Early Cretaceous volcanic rocks is indicative of formation in a post-collisional extensional environment, and they formed from primary magmas generated by the partial melting of juvenile mafic lower crust. The discovery of late Mesozoic volcanic and subvolcanic rocks within the southern GXR indicates that this region was in volcanic arc and extensional tectonic settings during the Early–Middle Jurassic and the Late Jurassic–Early Cretaceous, respectively. This indicates that the Mongol–Okhotsk oceanic plate was undergoing subduction during the Early–Middle Jurassic, and this ocean adjacent to the GXR may have closed by the Late Middle Jurassic–Early Late Jurassic.     

粤东鸿沟山金矿区流纹斑岩锆石SHRIMP U-Pb定年、Lu-Hf同位素组成及其地质意义

鸿沟山矿区位于华南粤东莲花山钨矿床的中部,是近年来通过地质矿产调查新发现具有找寻金矿潜力的矿床之一。本文以与鸿沟山金等多金属矿化关系密切的流纹斑岩为研究对象,开展了锆石SHRIMP U-Pb定年、流纹斑岩和矿石岩石地球化学、锆石Lu-Hf同位素组成特征研究。获得流纹斑岩锆石206Pb/238U加权平均年龄为169.1±1.5Ma,说明岩体形成于中侏罗世。在微量元素特征方面,流纹斑岩都表现为相对亏损大离子亲石元素Ba、Sr和高强场元素Nb、P、Zr、Hf,富集大离子亲石元素Rb,高强场元素U、Ce、Sm和轻稀土元素La、Nd,流纹斑岩与矿石稀土元素特征基本相似,Eu具中等负异常,但随着矿化强度的增强稀土元素更加富集。流纹斑岩εHf(t)(-15.0~2.2)分布范围宽,二阶段模式年龄TDM2主要变化范围为0.82~0.93 Ga,表明成岩物质主要来源于新元古代古老地壳变质泥岩和变质砂岩部分熔融,并有幔源物质的加入。因此,围绕着该时间段的流纹斑岩岩体,对于找寻W、Cu、Pb、Zn、Bi、Au、稀土、稀有和稀散元素矿产具有重要意义。     

大兴安岭十八站—韩家园地区中酸性侵入岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其地质意义

大兴安岭北部塔河县十八站—呼玛县韩家园地区发育早古生代中酸性侵入岩。文章选取二长闪长岩和二长花岗岩开展岩石年代学与地球化学研究。二长闪长岩LA-ICP-MS锆石U-Pb年龄为512.4±3.5 Ma,为早—中寒武世岩浆作用的产物。岩石地球化学分析表明,中酸性侵入岩归属于准铝质—弱过铝质(A/CNK=0.77~1.04)钙碱性—高钾钙碱性系列。岩石稀土总量∑REE=69.51×10~(-6)~275.83×10~(-6),轻重稀土分异明显(La/Yb)_N=9.11~26.64。在稀土元素配分图上,显示为LREE富集、HREE相对平缓的右倾型,Eu异常不显著(δEu=0.90~1.35)。微量元素组成具明显富集大离子亲石元素Ba、Sr,显著亏损高场强元素Nb、Ta、Ti的特征。结合区域资料和本文研究,初步分析认为早古生代侵入体形成于活动大陆边缘或岛弧环境,为前古亚洲洋闭合背景下萨拉伊尔造山作用的产物。     

华北克拉通东缘金岭杂岩体岩浆源区及构造背景:来自岩相学、岩石地球化学及年代学的证据

金岭杂岩体由细粒黑云角闪闪长岩、中细粒黑云角闪闪长岩、中细粒黑云角闪二长闪长岩和细粒角闪二长闪长岩组成,是鲁西地区典型矽卡岩型富铁矿(金岭铁矿)控矿岩体。本次研究对细粒黑云角闪闪长岩和细粒角闪二长闪长岩进行了锆石LA‐ICP‐MS U‐Pb定年,其结果分别为129.2±3.2 Ma和132.8±1.2 Ma,表明该杂岩体的侵位时代为早白垩世。样品SiO2、K2O和Na2O含量分别介于54.17%~63.73%、1.92%~4.76%和3.10%~5.41%之间,K2O/Na2O为0.58~0.94,A/CNK为0.60~0.93,具有轻稀土富集,重稀土亏损的右倾型稀土配分模式,轻、重稀土分馏程度中等((La/Yb)N=9.94~23.49),Eu异常不明显(δEu=0.84~1.10),具中—弱负Ce异常(δCe=0.56~0.92)。样品以富集大离子亲石元素(Ba、K、U、Pb等)、亏损高场强元素(Nb、Ta、Ti)以及高Sr/Y为特征。金岭杂岩体为燕山晚期岩浆活动产物,属准铝质高钾钙碱性系列,岩浆主要来源于富集岩石圈地幔的部分熔融,并在岩浆上升侵位的过程中有地壳物质的同化混染。燕山晚期华北克拉通在古太平洋板块俯冲后后撤引起的板内伸展环境下,增厚陆壳减薄阶段,岩浆上侵就位形成金岭杂岩体。     

Rapid U‐Pb Geochronology by Laser Ablation Multi‐Collector ICP‐MS

Detrital zircon (DZ) U‐Pb laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) has revolutionised the way geologists approach many Earth science questions. Although recent research has focused on rapid sample throughput, acquisition rates are limited to 100–300 analyses h^?1. We present a method to acquire zircon U‐Pb dates at rates of 120, 300, 600 and 1200 analyses h^?1 (30, 12, 6 and 3 s per analysis) by multi‐collector LA‐ICP‐MS. We demonstrate the efficacy of this method by analysing twelve zircon reference materials with dates from ~ 3465 to ~ 28 Ma. Mean offset from high‐precision dates increases with faster rates from 0.9% to 1.1%; mean random 1s uncertainty increases from 0.6% to 1.3%. We tested this new method on a sandstone sample previously characterised by large‐n DZ geochronology. Quantitative comparison shows increased correspondence among age distributions comprising > 300 dates. This new method holds promise for DZ geochronology because (a) it requires no major changes to hardware, but rather modifications to software; (b) it yields robust age distributions well‐suited for quantitative analysis and maximum depositional age calculations; (c) there is only a minor sacrifice of accuracy and measurement uncertainty; and (d) there is less burden to researchers in terms of time investment and analytical cost.     

李清地铅锌银矿区成矿地质特征及找矿新进展

李清地铅锌银矿区,是一个勘查多年的老矿区,通过资料的重新开发,按照新的找矿思路,配合有效的勘查方法,发现了新的北西向隐伏Pb、Zn、Ag、Au富厚矿体,取得了找矿实质性进展,使老矿区的找矿重现生机.     

南极长城站附近企鹅栖息地粪土沉积地层放射性核素210Pb定年

用γ谱方法测定了南极长城站附近特有生物群落栖息地沉积物中放射性核素含量,地表沉积物中40K,137Cs,210Pb,226Ra,228Ra,228Th.和238U平均比活度,分别为143,7.56,24.1,3.65,5.36,4.15和6.5Bq/kg.同时测试了阿德雷岛企鹅栖息地粪土沉积地层中放射性核素含量,利用其中的210Pb比活度,210Pb_ex垂向变化特征,推演沉积物的沉积速率和地质历史年代:其中AD1-a柱样时间跨度约为74a(1928~2002年),据此计算了沉积速率为0.063mm/a(r=0.794),并讨论了在南极特定条件下,放射性核素示踪对定年影响以及与区域现代气候环境变化的内在联系.