0.6～2.0GPa压力下部分熔融角闪辉长岩的纵波波速

利用超声波透射-反射法,测量了0.6～2.0 GPa、最高1 085℃条件下角闪辉长岩的纵波波速(vp),详细统计了部分熔融阶段实验产物组分的体积百分含量,利用矿物含量和弹性参数,计算了角闪辉长岩的纵波波速.实验测量和理论计算显示了较一致的vp-t关系,即高压下角闪辉长岩的vp随温度升高先缓慢降低,在温度约800～900℃后转而大幅下降.实验产物显示,样品在温度达812℃(0.6 GPa)、865℃(1.0 GPa)和919℃(2.0 GPa)后发生矿物脱水和部分熔融,熔体含量随温度升高显著增加.熔体是导致高温阶段岩石vp快速降低的主要原因.在初熔阶段vp随熔体增加而降低尤为显著,可能是初熔时矿物脱水生成的自由水及含水量高的熔体,以微细熔体薄膜浸润矿物边界或裂隙所导致.     

Source depletion and extent of melting in the Tongan sub-arc mantle

The fluid immobile High Field Strength Elements (HFSE) Nb and Ta can be used to distinguish between the effects of variable extents of melting and prior source depletion of the Tongan sub-arc mantle. Melting of spinel lherzolite beneath the Lau Basin back-arc spreading centres has the ability to fractionate Nb from Ta due to the greater compatibility of the latter in clinopyroxene. The identified spatial variation in plate velocities and separation of melt extraction zones, combined with extremely depleted lavas make Tonga an ideal setting in which to test models for arc melt generation and the role of back-arc magmatism.We present new data acquired by laser ablation-ICPMS of fused sample glasses produced without the use of a melt fluxing agent. The results show an arc trend towards strongly sub-chondritic Nb/Ta (< 17) with values as low as 7.2. Melting models show that large degree melts of depleted MORB mantle fail to reproduce the observed Nb/Ta. Alternatively, incorporation of residual back-arc mantle that has undergone less than 1% melting into the sub-arc melting regime reproduces arc values. However, the extent of partial melting required to produce the composition of the Lau Basin back-arc basalts averages 7%. This apparent discrepancy can be explained if only the lowermost 4 km of the residua from the mantle melt column beneath the back-arc is added to the source of arc magmas. We have identified that the degree of arc/back-arc coupling displayed in the rock record provides an index of the depth of hydrous melting beneath the arc. In this case, this would imply a depth of ~ 75 km for generation of arc magmas, indicating that hydrous melting in the mantle wedge is triggered by the breakdown of hydrous phases in the subducting slab.     

An Improved Gas Chromatographic Method for the Determination of C6–C12 Petroleum Hydrocarbons in Soil Water

In this work, investigations dealing with the determination of hydrocarbons in contaminated soil water are presented. The hydrocarbons under investigation range from low to high volatility compounds. A GC‐FID method was developed that due to its efficiency, routine suitability, relative rapidity, and low cost is suitable for the analysis of complex chemical mixtures of highly volatile hydrocarbons (with boiling points between 69 and 190°C). The standard used was a gasoline mixture with boiling points ranging from 100 to 190°C. For this standard, no supplementary preparation is needed and it is suitable for the whole range of hydrocarbons under investigation. The determination of the hydrocarbon content of the samples was performed applying univariate and multivariate statistical analysis to the experimental data. In the characterization of a contamination with highly volatile hydrocarbons of soil water originating from different depth layers from the chemistry location Leuna (Sachsen‐Anhalt, Germany), the advantages of a multivariate method are demonstrated in exemplary manner.     

Evolution of the late Pleistocene Mojanda–Fuya Fuya volcanic complex (Ecuador), by progressive adakitic involvement in mantle magma sources

The Mojanda–Fuya Fuya Volcanic Complex consists of two nearby volcanoes, Mojanda and Fuya Fuya. The older one, Mojanda volcano (0.6 to 0.2 Ma), was first constructed by andesites and high-silica andesites forming a large stratovolcano (Lower Mojanda). This edifice was capped by a basaltic andesite and andesitic cone (Upper Mojanda), which collapsed later to form a 3-km-wide summit caldera, after large phreatomagmatic eruptions. The Lower Fuya Fuya edifice was constructed by the extrusion of viscous Si-rich andesitic lavas and dacitic domes, and the emission of a thick sequence of pyroclastic-flow and fallout deposits which include two voluminous rhyolitic layers. An intermediate construction phase at Fuya Fuya is represented by a mainly effusive cone, andesitic in composition (San Bartolo edifice), the construction of which was interrupted by a major sector collapse in the Late Pleistocene. Finally, a complex of thick siliceous lavas and domes was emplaced within the avalanche amphitheatre, forming the Upper Fuya Fuya volcanic centre. This paper shows that the general evolution from an effusive to an explosive eruptive style is related to a progressive adakitic contribution to the magma source. Although all the rocks of the complex are included in the medium-K field of continental arcs, the Fuya Fuya suite (61–75 wt.% SiO₂) shows depletion in Y and HREE and high Sr/Y and La/Yb values, compared to the less silicic Mojanda suite (55–66.5 wt.% SiO₂). The Mojanda calc-alkaline suite was generated by partial melting of an adakite-metasomatised mantle source that left a residue with 2% garnet, followed by fractional crystallization of dominant plagioclase + pyroxene + olivine at shallow, intra-crustal depths. For Fuya Fuya, geochemical and mineralogical data suggest either (1) partial melting of a similar metasomatised mantle with more garnet in the residue (4%), followed by fractional crystallization involving plagioclase, amphibole and pyroxene, or (2) mixing of mafic mantle-derived magma from the Mojanda suite and slab melts, followed by the same fractional crystallization process.     

Genesis of high-magnesium andesites and associated basalts from Saga–Futagoyama, northwest Kyushu, southwest Japan

High-magnesium andesites associated with basalts erupted after the opening of the Sea of Japan are present at Saga–Futagoyama in northwest Kyushu, southwest Japan. High Mg/(Mg + Fe) [=0.84] of orthopyroxene phenocrysts and bulk rock Mg–Fe–Ni compositions suggest that these high-magnesium andesites were originally primitive melts insignificantly modified in crustal magma chambers. K_D^Ca–Na [= (Ca/Na)_pl/(Ca/Na)_{bulk rock}] ranges from 1.21 to 0.97 and suggests that the high-magnesium andesite magmas would originally have contained H₂O less than 1.8 wt.%. Nb/La does not show a negative correlation with respect to SiO₂. These lines of evidence indicate that hydrous components derived from the subducting slab would not have played a significant role in the genesis of the high-magnesium andesite magmas. Instead, the normative olivine − quartz − [CaTs + Jd] compositions and a negative correlation between Sr/Nd and SiO₂ indicate that the basalt-high-magnesium andesite association would have been formed by multi-stage partial melting of relatively anhydrous source at pressure ranging from 1.5 to 0.5 GPa.     

聂拉木县冲堆普2002年泥石流成因分析及防治对策

聂拉木县冲堆普于2002年5月23日和6月29日先后两次暴发了大规模泥石流灾害,导致下游的水电站、中尼公路、农牧业生产、通讯设施等遭受严重破坏,总共损失约750余万元,给地方社会经济造成了严重的影响.通过对上游的考察和气象资料分析,查清了灾害的形成原因是冲堆普上游冰川融水和嘉龙湖局部溃决所诱发.这是一种多因子共同作用的新型泥石流类型,不同于以往的冰川融水型泥石流和冰湖溃决型泥石流.针对泥石流的危害,提出了防治措施,包括软性措施和硬性措施.     

大别山花岗质岩浆的形成:胶水或含自由水体系的熔融——以天堂寨和九资河花岗岩为例

本文以北大别地块中典型燕山期花岗岩——天堂寨、九资河花岗岩为例,研究了其黑云母、角闪石的矿物成分及岩石包体特征;并结合当前有关脱水熔融和含自由水体系的熔融实验岩石学成果,对花岗质岩浆的形成方式进行了讨论,认为天堂寨、九资河花岗岩是由含自由水体系的熔融作用形成的,含水流体的主要来源可能为南大别地块。     

辽西北票、义县地区髫髻山旋回火山岩的地球化学特征

北票、义县地区髫髻山组可分为3个岩性段.髫髻山火山旋回划分为2个亚旋回.髫髻山旋回火山岩属于高钾钙碱性岩系,SiO₂=53.67%~75%,Al₂O₃=13.15%~19.16%,K₂O+Na₂O=5.17%,里特曼指数δ=1.46~6.83,平均值为3.06;富碱贫镁,Na₂O>K₂O.Cr、Ni含量低,亲石元素Rb、Sr、Ba等含量高.稀土元素总量较高,富轻稀土,稀土分布模式呈右倾型,稀土元素分馏明显,总体为负铕异常,弱铈异常.成因研究表明,髫髻山旋回火山作用是在与挤压作用相关的大陆边缘活动带构造环境下,受壳断裂控制形成的,具有造山带火山岩特征.火山岩的成岩作用以部分熔融为主,其源区物质为LREE相对富集的下部玄武质地壳.     

埃达克岩研究现状

埃达克岩是一套钙碱系列岩浆岩,其主要地球化学特征为SiO₂ ≥ 56%,Al₂O₃ ≥ 15%,MgO通常小于3%,低重稀土元素和Y(Y ≤ 18×10^-6,Yb ≤ 1.9×10^-6),高Sr(多数大于400×10^-6),无Eu异常或有轻微的负Eu异常,其成因主要有两类,一种为由俯冲板片的熔融形成,另一种由底侵玄武质下地壳熔融形成,埃达克岩具有重要的成矿意义。