Synthesis and Characterization of Poly(2‐hydroxyethylmethacrylate‐hydroxyapatite) a Novel Composite for the Removal of Lead(II) from Aqueous Solutions

In the present study, a novel adsorbent, poly (2‐hydroxyethylmethacrylate‐hydroxyapatite) [P(HEMA‐Hap)], was prepared and characterized. The synthesis was achieved by means of free‐radical polymerization and a number of structural characterization methods, including FT‐IR, XRD, TGA, SEM, BET‐porosity, and swelling tests. Pb²⁺ adsorption was performed using a series of pH, time, and temperature ranges. The reusability of the composite was also tested. The results obtained indicated that the novel adsorbent is able to bind Pb²⁺ ions with strong chemical affinity. The adsorption results were fitted to the classic Langmuir, Freundlich, and Dubinin–Radushkevich (D–R) sorption models. Thermodynamic parameters obtained demonstrated that the sorption process was spontaneous (ΔG < 0), endothermic (ΔH > 0), as expected. The process was also consistent with the pseudo‐second‐order model, and chemical adsorption was determined to be the rate‐controlling step. It was also shown that the composite could be used for five consecutive adsorption processes.     

Inferring the emission regions for different kinds of gamma‐ray bursts

Using a theoretical model describing pulse shapes, we have clarified the relations between the observed pulses and their corresponding timescales, such as the angular spreading time, the dynamic time as well as the cooling time. We find that the angular spreading timescale caused by curvature effect of fireball surface only contributes to the falling part of the observed pulses, while the dynamic one in the co‐moving frame of the shell merely contributes to the rising portion of pulses provided the radiative time is negligible. In addition, the pulses resulted from the pure radiative cooling time of relativistic electrons exhibit properties of fast rise and slow decay (a quasi‐FRED) profile together with smooth peaks. Besides, we interpret the phenomena of wider pulses tending to be more asymmetric to be a consequence of the difference in emission regions. Meanwhile, we find the intrinsic emission time is decided by the ratios of lorentz factors and radii of the shells between short and long bursts. Based on the analysis of asymmetry, our results suggest that the long GRB pulses may occur in the regions with larger radius, while the short bursts could locate at the smaller distance from central engine. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Robust dual‐sensor data sea‐surface ghost attenuation for quality control purposes

Three‐dimensional receiver ghost attenuation (deghosting) of dual‐sensor towed‐streamer data is straightforward, in principle. In its simplest form, it requires applying a three‐dimensional frequency–wavenumber filter to the vertical component of the particle motion data to correct for the amplitude reduction on the vertical component of non‐normal incidence plane waves before combining with the pressure data. More elaborate techniques use three‐dimensional filters to both components before summation, for example, for ghost wavelet dephasing and mitigation of noise of different strengths on the individual components in optimum deghosting. The problem with all these techniques is, of course, that it is usually impossible to transform the data into the crossline wavenumber domain because of aliasing. Hence, usually, a two‐dimensional version of deghosting is applied to the data in the frequency–inline wavenumber domain. We investigate going down the “dimensionality ladder” one more step to a one‐dimensional weighted summation of the records of the collocated sensors to create an approximate deghosting procedure. We specifically consider amplitude‐balancing weights computed via a standard automatic gain control before summation, reminiscent of a diversity stack of the dual‐sensor recordings. This technique is independent of the actual streamer depth and insensitive to variations in the sea‐surface reflection coefficient. The automatic gain control weights serve two purposes: (i) to approximately correct for the geometric amplitude loss of the Z data and (ii) to mitigate noise strength variations on the two components. Here, Z denotes the vertical component of the velocity of particle motion scaled by the seismic impedance of the near‐sensor water volume. The weights are time‐varying and can also be made frequency‐band dependent, adapting better to frequency variations of the noise. The investigated process is a very robust, almost fully hands‐off, approximate three‐dimensional deghosting step for dual‐sensor data, requiring no spatial filtering and no explicit estimates of noise power. We argue that this technique performs well in terms of ghost attenuation (albeit, not exact ghost removal) and balancing the signal‐to‐noise ratio in the output data. For instances where full three‐dimensional receiver deghosting is the final product, the proposed technique is appropriate for efficient quality control of the data acquired and in aiding the parameterisation of the subsequent deghosting processing.     

Effects of differing coverage of moss‐dominated soil crusts on hydrological processes and implications for disturbance in the Mu Us Sandland,China

To study the effects of biological soil crusts (BSCs) on hydrological processes and their implications for disturbance in the Mu Us Sandland, the water infiltration, evaporation and soil moisture of high coverage (100% BSCs), middle coverage (40% BSCs) and low coverage (0% BSCs, bare sand) of moss‐dominated crusts were conducted in this study, respectively. The conclusions are as follows: (1) the main effects of moss‐dominated crusts in the Mu Us Sandland on the infiltration of rainwater were to reduce the infiltration depths and to retain the limited rainwater in shallow soil; (2) moss‐dominated crusts have no significant effects on daily evaporation when the volumetric water content at 4 cm depth in 100% BSCs (VWC4) was over 24.7%, on enhanced daily evaporation when the VWC4 ranged from 6.5% to 24.7% and on reduced daily evaporation when the VWC4 was less than 6.5%; and (3) decreasing the coverage of moss‐dominated crusts (from 100% to 40%) did not significantly change its effects on infiltration, evaporation and soil moisture. Our results demonstrated that for the growth and regeneration of shrubs, which were dominated by Artemisia ordosica in the Mu Us Sandland, high coverage of moss‐dominated crusts has negative effects on hydrological processes, and these negative effects could not be significantly reduced by decreasing the coverage of moss‐dominated crusts from 100% to 40%. Therefore, for the sustained and healthy development of shrub communities in the Mu Us Sandland, it is necessary to take appropriate measures for the well‐developed BSCs in the sites with high vegetation coverage in the rainy season. Copyright © 2015 John Wiley & Sons, Ltd.     

Impact of wildfire on source water contributions in Devil Creek,CA: evidence from end‐member mixing analysis

A geochemical and end‐member mixing analysis (EMMA) is undertaken in Devil Canyon catchment, located in southern California, to further understanding of watershed behaviour and source water contributions after an acute and extensive wildfire. Physical and chemical transformations in post‐fire watersheds are known to increase overland flow and decrease infiltration, mainly due to formation of a hydrophobic layer at, or near, the soil surface. However, less is known about subsurface flow response in burned watersheds. The current study incorporates EMMA to evaluate and quantify source water contributions before, and after, a catchment affected by wildfires in southern California during the fall of 2003. Pre‐ and post‐fire stream water data were available at several sampling sites within the catchment, allowing the identification of contributing water sources at varying spatial scales. Proposed end‐member observations (groundwater, overland flow, shallow subsurface flow) were also collected to constrain and develop the catchment mixing model. Post‐fire source water changes are more evident in the smaller and faster responding sub‐basin (interior sampling point). Early post‐fire storm events are dominated by overland flow with no significant soil water or groundwater flow contribution. Inter‐storm streamwater in this smaller basin shows an increase in groundwater and a decrease in soil water. In the larger, baseflow‐dominated system, source water components appear less affected by fire. A slight increase in lateral flow is observed with only a slight decrease in baseflow. Changes in the post‐fire flow regimes affect nutrient loading and chemical response of the basin. Relatively rapid recovery of the chaparral ecosystem is evidenced, with active re‐growth and evapotranspiration evidenced by the fourth post‐fire rainy season. Copyright © 2008 John Wiley & Sons, Ltd.     

Experimental study of extreme shear stress for shallow flow under simulated rainfall

The raindrop impact and overland flow are two major factors causing soil detachment and particle transportation. In this study, the turbulent characteristics of the shallow rain‐impacted water flow were investigated using a 2‐D fibre‐optic laser Doppler velocimetry (FLDV) and an artificial rainfall simulator. The fluctuating turbulent shear stress was computed using digital data processing techniques. The experimental data showed that the Reynolds shear stress follows a probability distribution with heavy tails. The tail probability increases with an increase of rainfall intensity or raindrop diameter, and it decreases with an increase of Reynolds number. A modified empirical equation was derived using both the raindrop diameter and rainfall intensity as independent variables to provide a better prediction of the Darcy‐Weisbach friction coefficient f under rainfall conditions. Copyright © 2009 John Wiley & Sons, Ltd.     

Application of connectivity theory to model the impact of terrace failure on runoff in semi‐arid catchments

Terraces are a common feature of Mediterranean landscapes. In many places they are no longer maintained so that the number of intact terraces is in prolonged decline. The aim of this paper is to examine the effect of terrace removal and failure on hydrological connectivity and peak discharge in an agricultural catchment (475 ha) in south‐east Spain. The situation of 2006 is compared to that in 1956 and to a scenario without terraces (S2). The spatial distribution of concentrated flow was mapped after four storms in 2006. The degree of connectivity was quantified by means of connectivity functions and related to storm characteristics, land use and topography. For 1956, 2006 and scenario S2, connectivity functions and peak discharge to the river were determined for a storm with a return period of 8·2 years. The results show that the decrease in intact terraces has led to a strong increase in connectivity and discharge. The contributing area to the river system has increased by a factor 3·2 between 1956 and 2006. If all terraces were to be removed (scenario S2), the contributing area may further increase by a factor 6·0 compared to 2006. The spatial extent of concentrated flow and the degree of connectivity are related to storm magnitude as expressed by the erosivity index (EI₃₀). Although a large part of the concentrated flow (25–50%) occurs on dirt roads, it appears that croplands become a major source of runoff with increasing rainfall. The results suggest that connectivity theory can be used to improve rainfall–runoff models in semi‐arid areas. Copyright © 2009 John Wiley & Sons, Ltd.     

Streamflow estimation using optimal regional dependency function

The determination of spatial dependency of regionalized variable (ReV) is important in engineering studies. Regional dependency function that leads to calculation of weighting coefficients is required in order to make regional or point‐wise estimations. After obtaining this dependency function, it is possible to complete missing records in the time series and locate new measurement station. Also determination of regional dependency function is also useful to understand the regional variation of ReV. Point Cumulative Semi‐Variogram (PCSV) is another methodology to understand the regional dependency of ReV related to the magnitude and the location. However, this methodology is not useful to determine the weighting coefficient, which is required to make regional and point‐wise estimations. However, in Point Semi‐Variogram (PSV) proposed here, weighting coefficient depends on both magnitude and location. Although the regional dependency function has a fluctuating structure in PSV approach, this function gradually increases with distance in PCSV. The study area is selected in Mississippi river basin with 38 streamflow stations used for PCSV application before. It is aimed to compare two different geostatistical models for the same data set. PSV method has an ability to determine the value of variable along with optimum number of neighbour stations and influence radius. PSV and slope PSV approaches are compared with the PCSV. It was shown that slope slope point semi‐variogram (SPSV) approaches had relative error below 5%, and PSV and PCSV methods revealed relative errors below 10%. Copyright © 2009 John Wiley & Sons, Ltd.