Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain)

Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO₄) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr²⁺ and SO₄^2? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO₄^2? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, ⁸⁷Sr/⁸⁶Sr data also suggest that Sr²⁺ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in ¹⁸O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.     

Sulfur Content and Isotopic Ratio of Cambro-Ordovician Carbonate Rocks from South Korea: A Possible Source for Mesozoic Magmatic-hydrothermal Ore Sulfur

Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ³⁴S values. The δ³⁴S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ³⁴S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ³⁴S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ³⁴S value of +12.8 permil (n=24). The estimated δ³⁴S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ³⁴S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ³⁴S values of the Korean ore deposits might be caused to some extent by ³⁴S enrichment from the host carbonates, resulting in the low SSS contents observed.     

天祝-古浪5.4级地震震源机制和发震断层以及海原西断裂大震危险性讨论

研究了发生在海西断裂天祝拉分盆地1996年6月1日5.4级地震的震源机制，利用位于天祝－古浪地区的数字式微震监测台网纪录的余震的精确定位确定了本次地震的发震断层，研究表明这次地震是天祝拉分盆地中垂直于主断裂的近南北向断裂所形成，根据破裂模型和海原西断裂的应力积累状况，讨论了海原西断裂近期的大震危险性。     

2001年11月14日新疆-青海交界8.1级地震

简要介绍了2001年11月14日新疆－青海交界8．1级地震的预测情况，给出了中、美、日等对此次地震的震源参数测定和震源机制，以及余震的分布和加卸载响应比随时间的变化。进而对震区近期地震趋势进行预测。     

PowerBuilder 8.0中C/S模式应用过渡到B/S模式应用的实现技术

简要分析了PowerBuilder 8．0中各种B/S解决方案的优劣，探讨了适用于已有C／S模式应用过渡到B／S模式应用的实现方法，以及利用ASP技术实现对不同类型的客户测览器隐藏底层实现方法的技术，并给出了C／S模式应用过渡到B／S模式应用的一个实例。     

数字地籍测绘实施中的技术问题

数字地籍测绘是目前土地管理部门的首选方案,需要制定街坊划分、界址线设定、工作底图与采集草图一体化作业、数据文件管理、街坊线、图斑的绘制等技术措施。     

地震资料小波剖面制作系统

对不同的小波变换算法和小波基函数进行了研究，得到了适用于地震资料处理的最佳小波基函数，并用Visual C 语言开发了基于Windows操作平台下的地震资料小波剖面制作系统。利用小波剖面制作系统和最佳小波基函数对煤田实际地震资料进行了处理，取得了令人满意的地质效果。