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91.
Ultrahigh temperature (UHT) granulites in the Eastern Ghats Province (EGP) have a complex P–T–t history. We review the P–T histories of UHT metamorphism in the EGP and use that as a framework for investigating the P–T–t history of Mg–Al‐rich granulites from Anakapalle, with the express purpose of trying to reconcile the down‐pressure‐dominated P–T path with other UHT localities in the EGP. Mafic granulite that is host to Mg–Al‐rich metasedimentary granulites at Anakapalle has a protolith age of c. 1,580 Ma. Mg–Al‐rich metasedimentary granulites within the mafic granulite at Anakapalle were metamorphosed at UHT conditions during tectonism at 960–875 Ma, meaning that the UHT metamorphism was not the result of contact metamorphism from emplacement of the host mafic rock. Reworking occurred during the Pan‐African (c. 600–500 Ma) event, and is interpreted to have produced hydrous assemblages that overprint the post‐peak high‐T retrograde assemblages. In contrast to rocks elsewhere in the EGP that developed post‐peak cordierite, the metasedimentary granulites at Anakapalle developed post‐peak, generation ‘2’ reaction products that are cordierite‐absent and nominally anhydrous. Therefore, rocks at Anakapalle offer the unique opportunity to quantify the pressure drop that occurred during so‐called M2 that affected the EGP. We argue that M2 is either a continuation of M1 and that the overall P–T path shape is a complex counter‐clockwise loop, or that M1 is an up‐temperature counter‐clockwise deviation superimposed on the M2 path. Therefore, rather than the rocks at Anakapalle having a metamorphic history that is apparently anomalous from the rest of the EGP, we interpret that other previously studied localities in the EGP record a different part of the same P–T path history as Anakapalle, but do not preserve a significant record of pressure decrease. This is due either to the inability of refractory rocks to extensively react to produce a rich mineralogical record of pressure decrease, or because the earlier high‐P part of the rocks history was erased by the M1 loop. Irrespective of the specific scenario, models for the tectonic evolution of the EGP must take the substantial pressure decrease during M2 into account, as it is probable the P–T record at Anakapalle is a reflection of tectonics affecting the entire province.  相似文献   
92.
Controversy over the plate tectonic affinity and evolution of the Saxon granulites in a two‐ or multi‐plate setting during inter‐ or intracontinental collision makes the Saxon Granulite Massif a key area for the understanding of the Palaeozoic Variscan orogeny. The massif is a large dome structure in which tectonic slivers of metapelite and metaophiolite units occur along a shear zone separating a diapir‐like body of high‐P granulite below from low‐P metasedimentary rocks above. Each of the upper structural units records a different metamorphic evolution until its assembly with the exhuming granulite body. New age and petrologic data suggest that the metaophiolites developed from early Cambrian protoliths during high‐P amphibolite facies metamorphism in the mid‐ to late‐Devonian and thermal overprinting by the exhuming hot granulite body in the early Carboniferous. A correlation of new Ar–Ar biotite ages with published PTt data for the granulites implies that exhumation and cooling of the granulite body occurred at average rates of ~8 mm/year and ~80°C/Ma, with a drop in exhumation rate from ~20 to ~2.5 mm/year and a slight rise in cooling rate between early and late stages of exhumation. A time lag of c. 2 Ma between cooling through the closure temperatures for argon diffusion in hornblende and biotite indicates a cooling rate of 90°C/Ma when all units had assembled into the massif. A two‐plate model of the Variscan orogeny in which the above evolution is related to a short‐lived intra‐Gondwana subduction zone conflicts with the oceanic affinity of the metaophiolites and the timescale of c. 50 Ma for the metamorphism. Alternative models focusing on the internal Variscan belt assume distinctly different material paths through the lower or upper crust for strikingly similar granulite massifs. An earlier proposed model of bilateral subduction below the internal Variscan belt may solve this problem.  相似文献   
93.
Concentration–discharge (C-Q) relationships are an effective tool for identifying watershed biogeochemical source and transport dynamics over short and long timescales. We examined stormflow C-Q, hysteresis, and flushing patterns of total suspended sediment (TSS) and soluble reactive phosphorus (SRP) in two stream reaches of a severely impaired agricultural watershed in northeastern Wisconsin, USA. The upper watershed reach—draining a relatively flat, row crop-dominated contributing area—showed predominantly anti-clockwise TSS hysteresis during storms, suggesting that particulate materials were mobilized more from distal upland sources than near- and in-channel areas. In contrast, the incised lower watershed reach produced strong TSS flushing responses on the rising limb of storm hydrographs and clockwise hysteresis, signalling rapid mobilization of near- and in-channel materials with increasing event flows. C-Q relationships for SRP showed complex patterns in both the upper and lower reaches, demonstrating largely non-linear chemodynamic C-Q behaviour during events. As with TSS, anti-clockwise SRP hysteresis in the upper reach suggested a delay in the hydrologic connectivity between SRP sources and the stream, with highly variable SRP concentrations during some events. A broad range of clockwise, anti-clockwise, and complex SRP hysteresis patterns occurred in the lower watershed, possibly influenced by in-channel legacy P stores and connection to tile drainage networks in the lower watershed area. Total suspended sediment and SRP responses were also strongly related to precipitation event characteristics including antecedent precipitation, recovery period, and precipitation intensity, highlighting the complexity of stormflow sediment and phosphorus responses in this severely impaired agricultural stream.  相似文献   
94.
The Timor Orogen represents one of the youngest arc–continent collisions exposed on the Earth. It has the potential to provide some of the key parameters about how this style of orogeny evolves. However, the metamorphic age of the highest-grade rocks formed in the collision remains controversial. Using U–Th–Pb dating of monazite from amphibolite-grade sillimanite and garnet-bearing schists we show the peak metamorphism occurred at 5.5–4.7 Ma. The young age of the monazite and the presence of significant amounts of common Pb required the development of a new protocol to simultaneously account for the 230Th disequilibrium and the 207Pb common Pb correction. The new estimate of metamorphic age is consistent with the estimates based on plate reconstructions for the initiation of arc–continent collision in East Timor. The metamorphic event is a result of this collision.  相似文献   
95.
A unique type of Nb–Zr–REE–Ga-enriched alkali tonstein of pyroclastic origin occurs exclusively within the late Permian coal measures of southwest China. The alkali tonsteins are located within the lowest Xuanwei or Longtan formations of Wuchiapingian age, indicating that their age is later than the main episode of Emeishan Large Igneous Province (ELIP) magmatism. The alkali tonsteins have intermediate–felsic Al2O3/TiO2 values (12.6–34.2, mean 22.0), light rare earth element-enriched chondrite-normalised patterns, negative δEu and incompatible element ratios similar to those of ELIP alkaline Nb–Ta-enriched syenites. All available evidence shows that the alkali tonsteins from southwest China originated from coeval ELIP alkaline magmatism. The enrichment of Nb–Zr–REE–Ga in alkali tonsteins is derived from the ELIP alkaline Nb–Ta-enriched volcanic ashes and may represent the last stage of mineralisation associated with the Emeishan mantle plume activity.  相似文献   
96.
Since it was first proposed in 2000, the concept of the Anthropocene has evolved in breadth and diversely. The concept encapsulates the new and unprecedented planetary-scale changes resulting from societal transformations and has brought to the fore the social drivers of global change. The concept has revealed tensions between generalized interpretations of humanity’s contribution to global change, and interpretations that are historically, politically and culturally situated. It motivates deep ethical questions about the politics and economics of global change, including diverse interpretations of past causes and future possibilities. As such, more than other concepts, the Anthropocene concept has brought front-and-center epistemological divides between and within the natural and social sciences, and the humanities. It has also brought new opportunities for collaboration. Here we explore the potential and challenges of the concept to encourage integrative understandings of global change and sustainability. Based on bibliometric analysis and literature review, we discuss the now wide acceptance of the term, its interpretive flexibility, the emerging narratives as well as the debates the concept has inspired. We argue that without truly collaborative and integrative research, many of the critical exchanges around the concept are likely to perpetuate fragmented research agendas and to reinforce disciplinary boundaries. This means appreciating the strengths and limitations of different knowledge domains, approaches and perspectives, with the concept of the Anthropocene serving as a bridge, which we encourage researchers and others to cross. This calls for institutional arrangements that facilitate collaborative research, training, and action, yet also depends on more robust and sustained funding for such activities. To illustrate, we briefly discuss three overarching global change problems where novel types of collaborative research could make a difference: (1) Emergent properties of socioecological systems; (2) Urbanization and resource nexus; and (3) Systemic risks and tipping points. Creative tensions around the Anthropocene concept can help the research community to move toward new conceptual syntheses and integrative action-oriented approaches that are needed to producing useful knowledge commensurable with the challenges of global change and sustainability.  相似文献   
97.
Occurrence and distributions of geochemical markers on vegetation and in soils covering two self-heating coal waste dumps were investigated with gas chromatography-mass spectrometry (GC–MS) and compared with those of bitumen expelled on the coal waste dump surface. Presence of biomarkers, alkyl aromatic hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and such polar compounds as phenols indicate that components of self-heating coal wastes indeed migrate to soils and plants surface and their characteristic fingerprints can be applied in passive monitoring to investigate migration of contaminants from self-heating coal wastes. Moreover, results allow to discriminate between the Upper- and Lower Silesian coal basins, notwithstanding value shifts caused by heating. Mechanisms enabling the migration of geochemical compounds into soils include mixing with weathered coal-waste material, transport in gases emitted due to self-heating and, indirectly, by deposition of biomass containing geochemical substances. Transport in gases involves mostly lighter compounds such as phenols, methylnaphthalenes, methylbiphenyls, etc. Distributions and values of geochemical ratios are related to differences in their boiling temperatures in the case of lighter compounds but preserve geochemical features in the case of heavier compounds such as pentacyclic trierpanes.  相似文献   
98.
Kajan subvolcanic rocks in the Urumieh–Dokhtar magmatic arc (UDMA), Central Iran, form a Late Miocene-Pliocene shallow-level intrusion. These subvolcanics correspond to a variety of intermediate and felsic rocks, comprising quartz diorite, quartz monzodiorite, tonalite and granite. These lithologies are medium-K calc-alkaline, with SiO2 (wt.%) varying from 52% (wt.%) to 75 (wt.%). The major element chemical data also show that MgO, CaO, TiO2, P2O5, MnO, Al2O3 and Fe2O3 define linear trends with negative slopes against SiO2, whilst Na2O and K2O are positively correlated with silica. Contents of incompatible trace elements (e.g. Ba, Rb, Nb, La and Zr) become higher with increasing SiO2, whereas Sr shows an opposite behaviour. Chondrite-normalized multi-element patterns show enrichment in LILE relative to HFSE and troughs in Nb, P and Ti. These observations are typical of subduction related magmas that formed in an active continental margin. The Kajan rocks show a strong affinity with calc-alkaline arc magmas, confirmed by REE fractionation (LaN/YbN = 4.5–6.4) with moderate HREE fractionation (SmN/YbN = 1.08–1.57). The negative Eu anomaly (Eu/Eu* <1), the low to moderate Sr content (< 400 ppm) and the Dy/Yb values reflect plagioclase and hornblende (+- clinopyroxene) fractionation from a calc-alkaline melt Whole–rock Sr and Nd isotope analyses show that the 87Sr/86Sr initial ratios vary from 0.704432 to 0.705989, and the 143Nd/144Nd initial ratios go from 0.512722 to 0.512813. All the studied samples have similar Sr-Nd isotopes, indicating an origin from a similar source, with granite samples that has more radiogenic Sr and low radiogenic Nd isotopes, suggesting a minor interaction with upper crust during magma ascent. The Kajan subvolcanic rocks plot within the depleted mantle quadrant of the conventional Sr-Nd isotope diagram, a compositional region corresponding to mantle-derived igneous rocks.  相似文献   
99.
This study aims at discriminating eight mangrove species of Rhizophoraceae family of Indian east coast using field and laboratory spectra in spectral range (350–2500 nm). Parametric and non-parametric statistical analyses were applied on spectral data in four spectral modes: (i) reflectance (ii) continuum removed, (iii) additive inverse and (iv) continuum removed additive inverse. We introduced continuum removal of inverse spectra to utilize the advantage of continuum removal in reflectance region. Non-parametric test gave better separability than parametric test. Principal component analysis and stepwise discriminant analysis were applied for feature reduction and to identify optimal wavelengths for species discrimination. To quantify the separability, Jeffries–Matusita distance measure was derived. Green (550 nm), red edge (680–720 nm) and water absorption region (1470 and 1850 nm) were found to be optimal wavelengths for species discrimination. The continuum removal of additive inverse spectra gave better separability than the continuum removed spectra.  相似文献   
100.
Land surface temperature (LST) is an important aspect in global to regional change studies, for control of climate change and balancing of high temperature. Urbanization is one of the influencing factors increasing land surface and atmospheric temperature, by the emission of greenhouse gases (e.g. CO2, NO and methane). In the present study, LST was derived from Landsat-8 of multitemporal data sets to analyse the spatial structure of the urban thermal environment in relation to the urban surface characteristics and land use–land cover (LULC). LST is influenced by the greenhouse gases i.e. CO2 plays an important role in increasing the earth’s surface temperature. In order to provide the evidence of influence of CO2 on LST, the relationship between LST, air temperature and CO2 was analysed. Landsat-8 satellite has two thermal bands, 10 and 11. These bands were used to accurately to calculate the temperature over the study area. Results showed that the strength of correlation between ground monitoring data and satellite data was high. Based on correlation values of each month April (R2 = 0.994), May (R2 = 0.297) and June (R2 = 0.934), observed results show that band 10 was significantly correlating with air temperature. Relationship between LST and CO2 levels were obtained from linear regression analysis. band 11 was correlating significantly with CO2 values in each of the months April (R2 = 0.217), May (R2 = 0.914) and June, (R2 = 0.934), because band 11 is closer to the 15-micron band of CO2. From the results, it was observed that band 10 can be used for calculating air temperature and band 11 can be used for estimation of greenhouse gases.  相似文献   
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