湖沼相富硒土壤的发现及其生态学意义

通过对浙北平原土壤调查与研究,发现一种新类型富硒土壤,其特征为环太湖周边断续出现。土壤硒全量为(0.084~1.296)×10^-6,平均值为0.399×10^-6,标准离差为0.037,变异系数为0.094;土壤有效硒与有机质关系密切,与土壤pH不相关;在土壤有机质丰富和氧化条件下,稻米、玉米、豆类和叶菜类等农产品富硒效果较好。进一步研究表明,该富硒土壤的形成与湖沼相沉积有关,据此提出湖沼相富硒土壤新类型。     

高盐度湖泊艾比湖风生流三维数值模拟

根据高盐度湖泊水动力特征,以西北咸水湖泊艾比湖为例,建立三维水动力数学模型。选取典型风场,分析风力作用下的高盐度湖泊风生流形成过程以及风生流水动力参数的三维空间分布特征。结果表明,艾比湖风生流形成在时间上可分为湖水流向和风向一致阶段、湖水运动方向逐渐偏离风向的过渡阶段及环流形成的稳定阶段等3个阶段。当流场达到稳定状态时,表层水体除中部存在若干小尺度环流外,大部分水域流向与风向基本一致;而湖泊中心区域底层水体流向与表层水体的流向大致相反,表现为很明显的补偿流。总体上,水平方向的流速自表层向下呈现递减的变化趋势,岸边流速大于中心流速,表现出与淡水湖泊基本相似的水动力空间分布特征。水体盐度增加对湖泊环流结构无影响。     

湖泊沉积物的矿物组成、成因、环境指示及研究进展

湖泊沉积物是不同地质、气候、水文条件下各类碎屑、黏土、自生/生物成因矿物以及有机物质等的综合体。沉积矿物蕴含着丰富区域和全球环境演变信息,如湖水的化学组成、流域构造、气候、水文以及人类活动的相互作用等。相关信息可以赋存在矿物外部微形貌、内部微结构、化学组成、物理和化学性质、同位素组成、谱学特征、成因以及共生组合等方面。因此,湖泊科学的许多关键课题都离不开矿物学,特别是在利用湖泊沉积物进行区域及过去全球变化研究中,深入的机理研究归根到底都要涉及矿物学,如流域化学风化作用、粒度组成、生物壳体化学组成、测年材料的选择等。然而,由于湖泊沉积物中矿物的多源性、复杂性,如何有效提取和解译其中的环境信息,是一项长期困扰研究者的课题,湖泊沉积矿物学的研究往往被许多研究者所忽视,中国的相关研究也较为薄弱。笔者综述了湖泊沉积物中碎屑、黏土、自生/生物矿物的矿物组合、特征、成因在(古)环境反演中的作用及最新研究进展,提出除了继续加强对湖泊沉积物中矿物来源、成因和古环境示踪的深入研究以外,矿物相间的转变及其对湖水和孔隙水组成的响应、一些非晶质或隐晶质及低丰度矿物相在湖泊化学和动力学中的作用也是很有潜力的研究领域,最后提出了研究中存在的一些问题、面对的挑战以及对研究前景的展望。     

盐湖丰产元素与Zintl化合物(续完)

Zintl化合物是以Edward Zintl命名的化合物,是一类由电正性的碱金属或碱土金属与电负性的13族或14族元素形成的特殊金属间化合物。其价键模式可以是离子键、金属键和共价键共存,其中的准金属可以共价键的形式形成各种形式的离子簇,因而其结构复杂多样。这类化合物的部分阴离子簇不仅具有稳定的笼状、层状和链状结构,并且具有特殊的光、电、磁等性能,使得在半导体、催化、电极材料等方面都有应用的前景和发展潜力。介绍了几个特殊Zintl化合物体系,盐湖丰产元素在Zintl化合物中的作用,指出了含有盐湖丰产元素的Zintl化合物的应用前景和方向。     

Climatic changes have led to significant expansion of endorheic lakes in Xizang (Tibet) since 1995

Robust climate warming has led to significant expansion of lakes in the central Tibetan Plateau. Using remote sensing data, our quantitative analysis indicates that Siling Co, a saline lake in a characteristic endorheic basin in the central region of the Plateau, has expanded more than 600 km² in area since 1976. Particularly since 1995, the lake has significantly expanded in response to increasing precipitation, decreasing water surface evaporation caused by weaker winds and less solar radiation, and increased glacier meltwater draining to the lake. Glacier–lake interactions are important in governing lake expansion and are also part of a feedback loop that influences the local climate. Worsening climatic conditions (decreased precipitation and increased temperatures) that could have caused the lake to shrink during 1976–1994 were offset by increasing glacier meltwater feeding the lake, which made the lake nearly stable. We demonstrate that this pattern changed during 1995–2009, when glacier meltwater actually decreased but participation runoff increased and evaporation decreased, leading to expansion of the lake. If climatic conditions became suitable for further lake development, which would be indicated by expansion in lake area, glacier meltwater could be saved in a stable reservoir.     

Conifer stomata analysis in paleoecological studies on the Loess Plateau: An example from Tianchi Lake, Liupan Mountains

The identification of fossil conifer stomata was conducted from a lake sedimentary sequence on the Liupan Mountains, southwestern Loess Plateau, in order to reconstruct detailed forest history and assess the potential of using stomata as a supplement to pollen analysis to determine the local presence of conifers over the last 3200 years. The pollen has already been analyzed in our previous study. Reference conifer stomata were prepared for the fossil stomata identification and demonstrate that the conifer stomata could be identified to at least genus level. Our stomata and pollen results reveal three clear stages of the forest recession during the late Holocene: mixed conifer-deciduous forest, steppe-forest and steppe. Combined stomata and pollen results confirm the local presence of conifer trees (Abies and Pinus) in the vicinity of the Tianchi Lake. Abundant Abies trees existed during 3200-2200 cal yr BP. Then it decreased and finally demised at ca.210 cal yr BP. Pinus trees have been continuously present with very low abundance throughout the late Holocene. Application of comprehensive studies comprising both stomata and pollen analyses allowed a detailed determination of the stages of conifer trees presence in the vicinity of the Tianchi Lake. Our study suggests that the analysis of fossil stomata is a valuable methodological tool for the provision of unambiguous evidence of the past local presence of the coniferous taxa in this region.     

西藏当雄错盐湖卤水冬季日晒蒸发实验研究

西藏当雄错盐湖位于藏北高原腹地西南侧,其水化学类型属典型的中度碳酸盐型,具有很好的工业开发前景和价值.自然蒸发是盐田日晒工艺的应用基础工作,本文基于室内卤水等温蒸发实验的相关结果,在当雄错湖区现场开展了盐湖卤水冬季日晒蒸发实验,通过考察碳酸盐型盐湖卤水在现场低温条件下自然蒸发过程中液相各元素的富集规律以及矿物的结晶析盐规律,分析了锂、硼、钾等元素的集散行为,并根据卤水蒸发过程中的元素富集、蒸失水量、盐类析出顺序、矿物组合以及物化性质的变化探索了盐类分离的控制条件.以Na+,K+/CO2-3,SO2-4,Cl--H2O五元体系(25℃)介稳相图为参考依据,绘制了当雄错盐湖卤水冬季日晒蒸发的结晶析盐路线.实验结果表明,当雄错盐湖卤水在冬季日晒蒸发过程中依次析出石盐、泡碱、天然碱、硼砂、钾石盐和扎布耶石,另有少量芒硝和泡碱等低温产物会提前析出或被母液夹带析出,利用冬季低温蒸发可制取富锂卤水,蒸发后期的母卤还可用于提取硼砂和钾石盐等矿物资源.实验结果为下一步开展盐田工程设计及制卤工艺操作提供了必要的基础数据,同时也为碳酸盐型盐湖卤水的综合利用和开发提供了理论支持.     

Holocene sedimentary environments in Lake Eyre,South Australia

In late Pleistocene time Lake Dieri (ancestral ‘Greater Lake Eyre') was permanently filled during a wet climatic phase. Towards the close of Pleistocene time the watertable fell, Lake Dieri dried up, and its sediments deflated. Later the watertable rose, establishing ephemeral Lake Eyre in the deflated area, and Holocene sedimentation commenced. At about this time Lake Eyre tilted to the south and three sedimentary environments developed: (1) a saline playa environment without saltcrusts in the northern end of the lake, where water drains away before wholly evaporating; (2) a terminal salina environment in the south end, where evaporation of brines leaves saltcrusts overlying gypseous sediments; and (3) a saline flocculation environment between the playa and salina environments, where sediments are deposited by flocculation when muddy floodwater from the north meets highly saline water of the southern salina.

In the northern playa environment, sedimentation is limited to the top of the capillary fringe above the watertable, below which sediments remain moist and protected from aeolian erosion, but above which they dry and blow out of the lake. In the southern salina environment sedimentation has not kept pace with the Holocene rise in watertable. If and when it does reach such a level, downward leaching of salt and deflation of exposed sediments is likely to occur. In the flocculation environment new deposits of clay are added but kept permanently wet by rising groundwater. When flocculated sediment builds too high, its excess is transferrred by surface water into the salina deposits to the south.