Organic geochemistry and petrology of barren and Mo–Ni–PGE mineralized marine black shales of the Lower Cambrian Niutitang Formation (South China)

Marine black shales of the Lower Cambrian Niutitang Formation in southern China host Mo–Ni–platinum group elements (PGE) mineralization confined to a phosphate- and pyrite-rich stratiform body (max. 20-cm thick). The H/C atomic ratio, carbon isotopic composition, FTIR spectra of bulk organic matter, and spectra of extractable part of organic matter indicate similar sources and thermal evolution of organic matter in barren and mineralized black shales.The morphology and relative abundance of organic particles in barren and mineralized shales are different. In barren black shales, organic particles comprise only elongated bodies and laminae 2–10 μm across or elongated larger bodies (> 10 μm) with R_max = 2.96–5.21% (Type I particles). Mineralized black shales contain Type I particles in rock matrix (90–95 vol%), small veinlets or irregular organic accumulations (Type II particles, 1–5 vol%) that display weak to well developed mosaic texture and a variable reflectance (R_max = 3.55–8.65%), and small (< 1 to 5 μm) rounded or irregular Type III organic particles (1–4 vol%) distributed within phosphate nodules and sulphide rip-up clasts. Type III particles show similar reflectance as particles of Type I in rock matrix. Type I particles are interpreted as remnants of in situ bacterially reworked organic matter of cyanobacteria/algal type, Type II as solidified products or oil-derived material (migrabitumen), and Type III particles as remnants of original organic matter in phosphatized or sulphidized algal/microbial oncolite-like bodies. Equivalent vitrinite reflectances of Type I and III particles in barren and mineralized rocks are similar and correspond to semi-anthracite and anthracite. Micro-Raman spectra of organic particles in rocks display a wide belt in the area of 1600 cm^− 1 (G belt) and approximately the same belt in the area of 1350 cm^− 1 (D belt). The ratio of integrated areas of the two belts correlate with R_max values.The Mo–Ni–PGE mineralized body is interpreted as to represent a remnant of phosphate- and sulphide-rich subaquatic hardground supplied with organic material derived from plankton and benthic communities as well as with algal/microbial oncolite-like bodies that originated in wave-agitated, shallow-water, nearshore environment.     

铀矿地质样品中有机碳的测定

用盐酸预处理岩矿样品以驱除样品中的碳酸盐碳;滤出酸不溶物并洗净,待干燥后置入900-1000℃的管式炉中,在富氧气流中灼烧,有机碳被氧化成CO2由烧碱石棉吸收后称重,根据烧碱石棉管的增重计算有机碳的含量。对含有机碳为0．23％的样品进行10次测定,标准偏差为0．0116％,变异系数为5．04％。     

Molecular hydrogen line emission from the reflection nebula Parsamyan 18

The newly commissioned University of New South Wales Infrared Fabry–Perot (UNSWIRF) has been used to image molecular hydrogen emission at 2.12 and 2.25 μm in the reflection nebula Parsamyan 18. P 18 is known to exhibit low values of the (1–0)/(2–1) S(1) ratio, suggestive of UV-pumped fluorescence rather than thermal excitation by shocks. Our line ratio mapping reveals the full extent of this fluorescent emission from extended arc-like features, as well as a more concentrated thermal component in regions closer to the central exciting star. We show that the emission morphology, line fluxes and gas density are consistent with the predictions of photodissociation region (PDR) theory. Those regions with the highest intrinsic 1–0 S(1) intensities also tend to show the highest (1–0)/(2–1) S(1) line ratios. Furthermore, variations in the line ratio can be attributed to intrinsic fluctuations in the incident radiation field and/or the gas density, through the self-shielding action of H₂. An isolated knot of emission discovered just outside P 18, and having both an unusually high (1–0)/(2–1) S(1) ratio and relative velocity, provides additional evidence for an outflow source associated with P 18.     

The C/CO ratio in B335 and the decaying dark matter neutrino hypothesis

C¹⁸O J  = 2–1, C¹⁷O J  = 2–1 and [C  I ] ³P₁–³P₀ emission from the dense cold cloud B335 has been observed and modelled in order to determine the C/CO ratio. The observed ratio is compared with a prediction by Tarafdar who assumes a mechanism in which the CO dissociation is caused by photons of energy ∼ 13.8 eV. These were postulated by Sciama to result from the decay of dark matter neutrinos. Our value for the C/CO ratio sets an upper limit to the strength of the neutrino decay dissociation process, thus providing a significant datum for interstellar chemistry theory.     

Mid-infrared imaging of WL 16: the spatial distribution of the hydrocarbon emission features

We present arcsec-resolution images at 8.2, 10.0 and 11.3 μm of the unusual young object WL 16 in Ophiuchus, which has an extended envelope of fluorescing hydrocarbon molecules. To the limit of achieved sensitivity, the faint 10.0-μm continuum has a surface-brightness distribution that is not distinguishable from those at 8.2 and 11.3 μm, where the luminosity is known to be dominated by the polycyclic aromatic hydrocarbon (PAH) emission features. We conclude that the 10-μm continuum either arises from non-equilibrium heating of small dust grains that are well mixed with the hydrocarbons or is quasi-continuous emission from the PAH particles themselves, rather than thermal equilibrium emission from macroscopic dust grains, and that there is no significant silicate absorption variation across the source. The extended hydrocarbon emission may trace a flattened, equatorial distribution of circumstellar material or arise in bipolar lobes. The former case is slightly favoured, based on currently available data, and would imply that WL 16 is a relatively evolved Herbig Ae star, the equatorial plane of which has been almost cleared of normal dust, leaving only fluorescing hydrocarbons and larger coagulated particles as a possibly transient fossil of the original circumstellar disc.     

The influence of organic debris on channel morphology and bedload transport in a New Zealand forest stream

The behaviour and form of, and bedload sediment transport through, a 3.5 m wide forest stream have been monitored for nearly three years. Bedload transport is highly episodic and spatially variable, and is controlled less by water discharge than by sediment availability. Organic debris in the channel creates temporary base levels and sites at which coarse sediment may remain stored for long periods; collapse or disruption of log and debris jams makes sediment available for transport in only a small proportion of the runoff events that are actually competent to move the material. Even then, sediment travels only a short distance before being redeposited, frequently behind debris accumulations further downstream. Rates of sediment transport during a given runoff event can vary markedly over short distances along the stream, again depending on whether sediment was made available for transport by log jam collapse upstream. Organic debris is therefore a major constraint on the application of physical laws and theories to explaining sediment movement in, and the morphology of, this stream.     

CO Clouds around SNR G21.8-0.6 and G32.8-0.1

We made the first CO(I—0) mapping to SNR G21.8-0.6 and SNR G32.8-0.1, both associated with OH 1720 MHz maser.Based on the morphological correspondence and velocity and position agreement between the radio remnant and the CO clouds,we tentatively identify the clouds that are respectively interacting with the two SNRs.