地球深部物质电学性质实验研究

地球深部物质电学性质的实验研究是了解地幔热结构和地幔动力学特征的重要手段之一,已越来越受到地球物理学家的重视。介绍了地球深部物质电学性质实验研究的基本原理、基本方法、电导的影响因素、实验研究的意义和今后的研究方向。     

Iodine (and Other Halogens) in Twenty Six Geological Reference Materials by ICP-MS and Ion Chromatography

Analytical results for iodine in twenty six geological reference materials (RM) are presented. Bromine, fluorine and chlorine were also determined in some samples. Pyrohydrolysis in a heated quartz tube under a wet oxygen flow was used for the separation of the halogens from the matrix and the evolved gas was absorbed in a trap solution. The halogens were measured by ICP-MS and ion chromatography (IC). All four halogens can be collected in the trap solution from one combustion procedure. The analysed samples range in type from igneous rocks to terrestrial and marine sediments. Precision, detection limits, and accuracy are also presented.     

Determination of Iodine in Thirty Two International Geochemical Reference Materials

Thirty two geochemical reference samples have been analysed for their iodine contents by a pyrohydrolysis extraction technique, followed by colourimetry. In spite of the existence of few reported values for iodine, limiting comparison with results from this study, the four available "reference" values show good agreement with the work reported here.     

二郎坪花岗岩体地球化学特征及成岩物质来源探讨

通过对河南西峡二郎坪花岗岩体的岩石学、岩石化学、地球化学特征研究,作者认为岩体为岩浆成因,且其源岩为宽坪群的变基性火山岩和变泥砂质岩石。用Ｇ．Ｆａｕｒｅ（１９８６）给出的简单二元混合方程,通过对Ｓｍ－Ｎｄ同位素的计算得出二郎坪岩体由约６４％的变基性火山岩和约３６％的变泥砂质岩石熔融而成。     

海洋浮游植物分解和代谢产物中高分子有机物的紫外、红外和~1H-核磁共振光谱特征

用GDX 102树脂从海洋浮游植物三角褐指藻(Phaeodactylum tricornutum)的分解产物和代谢产物中分离提取腐植类物质(DHS,EHS)及乙醇可溶物(DES,EES),用~1H-NMR,IR和UV光谱进行结构分析,并同海水中腐植质(HS)和乙醇可溶物(ES)做了比较。结果表明,DHS,EHS和HS都以高支链烷烃、碳水化合物和氨基酸结构为主要组分,另有少量芳烃和杂环化合物。它们的化学结构很相似,说明DHS和EHS是海水腐植质的重要来源。     

面向对象的产品物料清单多视图定义技术研究

为了实现产品全生命周期中的物料清单(BOM)数据的一致性和协同性，在阐述了企业中BOM数据的主要使用部门的基础上，分析了企业BOM的主要使用类型、功能需求和技术特点。提出了BOM视图和BOM视图空间的基本定义，讨论了BOM视图空间的主要类型。基于单一数据源的思想，采用面向对象的建模方法，定义了BOM对象模型和BOM对象的主要视图类型及其关键属性。该技术的应用对于实现CIMS环境下的BOM信息集成具有重要的意义。     

四川盆地须家河组砂岩储层中自生绿泥石的来源与成岩演化

由于在成岩过程中能有效抵抗上覆岩层的机械压实作用,抑制石英在颗粒表面成核的数量,自生绿泥石包膜对四川盆地须家河组砂岩储层的原生粒间孔的保存起到了重要的作用。须家河组早期自生绿泥石物质来源主要有同沉积的富铁沉积物的溶解、河流溶解铁的絮凝沉淀以及相邻泥岩压释水的贯入,主要以新生沉淀形式集中形成于同生期至早成岩早期。成岩中后期,由于下伏富Mg流体沿裂缝系统的持续进入,须2段的自生绿泥石的继续生长得到了充足的物质来源,其MgO的含量随地层深度明显增加,而须4段后期再生长现象不明显。该区自生绿泥石包膜对储层物性的影响通过绿泥石含量与参与孔隙度的关系以及孔隙度分布频率图可以得到较好的评估。从对储层的影响来说,自生绿泥石包膜存在一个最合适的厚度值,超过或低于这个值就会对储层造成负面影响而无法保护储层,该区此最适合的厚度值为5～10 μm。     

Sulfur Isotope Tracing of Ore-forming Hydrothermal Fluid for Metallic Sulfide Deposit

How to utilize sulfur isotope for many domestic and foreign researchers to trace the sulfur source of metallic sulfide deposit has been explored for many years. Fruitful results have been gained now. Based on summing up the characteristics of sulfur isotopic composition of hydrothermal mineral from metallic sulfide deposits, this paper illuminated the total sulfur isotopic composition of ore-forming fluids is the key factor in estimating the sulfur source. This paper also summarized three approaches about how to obtain the total sulfur isotopic composition (δ³⁴S_∑S) of ore-forming fluids. They are physical-chemical equilibrium analysis, mineral paragenetic association analysis and Pinckey-Rafter, respectively. We gave some applied examples and made a brief comment of them as well. There are three points worth noting. Firstly, choosing appropriate approach is a critical factor to acquire the δ³⁴S_∑S successfully according to the characteristics of different types of metallic sulfide deposit. Secondly, currently, these above mentioned approaches and applications are effective after the establishment of equilibrium state of sulfur isotope. As to the sulfur isotopic disequilibrium condition in metallic sulfide deposits probably resulted from lower temperature or rapid emplacement, there are quite some problems in theory and technique. Therefore, an in-depth study should also be continued. Thirdly, it is a new development trend to study isotope composition of different forms of sulfur and to discuss their source, forming environment and process respectively, which is probably more effective and significant for tracing sulfur sources of metallic sulfide deposits.     

内蒙古索伦地区中二叠统哲斯组有机质的拉曼光谱特征及地质意义

笔者研究了内蒙古索伦地区中二叠统哲斯组泥质岩石中有机质的激光拉曼光谱特征,并探讨了拉曼光谱参数对有机质热演化程度的表征。研究区样品D1谱带吸收峰平均值位于1 350.55 cm~(-1)附近,G谱带吸收峰平均值位于1 602.55 cm~(-1)附近,G谱带与D1谱带的位置差变化于252.00±;G谱带与D1谱带的面积比集中在0.52附近,表明有机质经历的热演化温度约为250℃。应用拉曼光谱地质温度计估算了有机质的热演化温度,其平均温度为265℃;采用镜质体反射率地质温度计估算的有机质热演化平均温度为273℃,两者吻合。综合分析部分估算温度偏高的原因,结合无机矿物的成因标志,揭示研究区中二叠统哲斯组地层经历的极低级变质温度可能250℃。     

Chemical and Isotopic Characters of the Water and Suspended Particulate Materials in the Yellow River and Their Geological and Environmental Implications

The chemical and isotopic characteristics of the water and suspended particulate materials(SPM)in the Yellow River were investigated on the samples collected from 29 hydrological monitoring stations in the mainstem and several major tributaries during 2004 to 2007.TheδD andδ~(18)O values of the Yellow River water vary in large ranges from-32‰to-91‰and from-3.1‰to-12.5‰,respectively.The characters of H and O isotope variations indicate that the major sources of the Yellow River water are meteoric water and snow melting water,and water cycle in the Yellow River basin is affected strongly by evaporation process and human activity.The average SPM content(9.635g/L)of the Yellow River is the highest among the world large rivers.Compared with the Yangtze River,the Yellow River SPM has much lower clay content and significantly higher contents of clastic silicates and carbonates.In comparison to the upper crust rocks,the Yellow River SPM contains less SiO_2,CaO,K_2O and Na_2O,but more TFe_2O_3,Co,Ni,Cu,Zn,Pb and Cd.The abnormal high Cd contents found in some sample may be related to local industrial activity.The REE contents and distribution pattern of the Yellow River SPM are very close to the average value of the global shale.The averageδ~(30)Si_(SPM)in the Yellow River(-0.11‰)is slightly higher than the average value(-0.22‰)of the Yangtze River SPM.The major factors controlling theδ~(30)Si_(SPM)of the Yellow River are the soil supply,the isotopic composition of the soil and the climate conditions.The TDS in the Yellow River are the highest among those of world large rivers.Fair correlations are observed among Cl~-,Na~+,K~+,and Mg~(2+)contents of the Yellow River water,indicating the effect of evaporation.The Ca~(2+)and Sr~(2+)concentrations show good correlation to the SO_4~(2-)concentration rather than HCO_3~-concentration,reflecting its origin from evaporates.The NO_3~-contents are affected by farmland fertilization.The Cu,Zn and Cd contents in dissolved load of the Yellow River water are all higher than those of average world large rivers,reflecting the effect of human activity.The dissolved load in the Yellow River water generally shows a REE distribution pattern parallel to those for the Yangtze River and the Xijiang River.Theδ~(30)Si values of the dissolved silicon vary in a range from 0.4‰to 2.9‰,averaging1.34‰.The major processes controlling the D_(Si)andδ~(30)Si_(Diss)of the Yellow River water are the weathering process of silicate rocks,growth of phytolith in plants,evaporation,dissolution of phytolith in soil,growth of fresh water diatom,adsorption and desorption of aqueous monosilicic acid on iron oxide and human activities.The averageδ~(30)Si_(Diss)value of the Yellow River is significantly lower than that of the Nile River,Yangtze River and Siberia rivers,but higher than those of other rivers,reflecting their differences in chemical weathering and biological activity.Theδ~(34)S_(SO4)values of the Yellow River water range from-3.8‰to 14.1‰,averaging 7.97‰.There is some correlation between SO_4~(2-)content andδ~(34)S_(SO4).The factors controlling theδ~(34)S_(SO4)of the Yellow River water are the SO_4 in the meteoric water,the SO_4 from gypsum or anhydrite in evaporite rocks,oxidation and dissolution of sulfides in the mineral deposits,magmatic rocks and sedimentary rocks,the sulfate reduction and precipitation process and the sulfate from fertilizer.The~(87)Sr/~(86)Sr ratios of all samplesrange from 0.71041 to 0.71237,averaging 0.71128.The variations in the~(87)Sr/~(86)Sr ratio and Sr concentration of river water are primarily caused by mixing of waters of various origins with different~(87)Sr/~(86)Sr ratios and Sr contents resulting from water-rock interaction with different rock types.