矿物材料学的内涵与特征

经过20余年的研究与发展,矿物材料学已经成为材料科学与工程中一个相对独立和完善的组成部分,由于其定义、内涵与特征等基本问题与材料科学的从属性和独特性,多年的研究认为:矿物材料学是研究矿物材料的组成与结构、制备与合成、性能和使用效能以及矿物原料性质与特点等五要素及其相互关系和规律的一门学科.这五要素是具有内部互相联系和作用的有机整体,研究这五要素并了解它们之间的相互关系和规律构成了矿物材料学的内涵.矿物原料性质与特点是其他四要素的基本前提或重要基础,矿物原料及其与其他四要素的关系以及矿物在其他四要素中的关键性都体现了矿物材料学的矿物科学属性,正是因为兼具材料科学属性和矿物科学属性的矿物材料学这一重要特征使其有别于其他学科,而具有了理论及实用价值.     

Composition-Induced Variations in SIMS Instrumental Mass Fractionation during Boron Isotope Ratio Measurements of Silicate Glasses

An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

Reference Materials in Geoanalytical Research -Review for 2004 and 2005

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.     

Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.     

新疆准噶尔地区富硫型与贫硫型浅成低温热液金矿床成矿流体与碳、硫、铅同位素

对新疆准噶尔地区浅成低温热液型金矿床中富硫型的阔尔真阔腊金矿、贫硫型的石英滩金矿进行了流依包裹体的均一温度、爆裂温度、包裹体气液相成分、H、O 同位素、矿体围岩及脉石英包裹体 C 同位素、矿体中黄铁矿等 S、Ph 同位素等系统地进行了研究,综合研究表明,本区该类型金矿成矿流体一般温度低、盐度低,来源主要为循环的大气水、矿石中黄铁矿的 S、Pb 同位素均为深源,暗示金的深部来源:矿体石英包裹体中 CO_2的δ~(13)C 为低于-10‰的有机碳,反映了本区年轻的富含有机质的沉积地层参与了金的成矿。此外,本文首次提出了富硫型阔尔真阔腊金矿床成矿流体中有侵入岩浆热液参与,深部有多金属成矿远景;贫硫型石英滩金矿没有侵入岩浆热液的参与,成矿仅与火山古热液活动有关,其成矿较单一。此外,阔尔真阔腊金矿中低温流体活动较强,金矿化也较强:石英滩金矿低温流体活动相对较弱,金矿化也较弱,也体现了该类型金矿床低温流体活动的越强烈,金矿化越强的规律。     

Determining Q of near-surface materials from Rayleigh waves

High-frequency (≥2 Hz) Rayleigh wave phase velocities can be inverted to shear (S)-wave velocities for a layered earth model up to 30 m below the ground surface in many settings. Given S-wave velocity (V_S), compressional (P)-wave velocity (V_P), and Rayleigh wave phase velocities, it is feasible to solve for P-wave quality factor Q_P and S-wave quality factor Q_S in a layered earth model by inverting Rayleigh wave attenuation coefficients. Model results demonstrate the plausibility of inverting Q_S from Rayleigh wave attenuation coefficients. Contributions to the Rayleigh wave attenuation coefficients from Q_P cannot be ignored when Vs/V_P reaches 0.45, which is not uncommon in near-surface settings. It is possible to invert Q_P from Rayleigh wave attenuation coefficients in some geological setting, a concept that differs from the common perception that Rayleigh wave attenuation coefficients are always far less sensitive to Q_P than to Q_S. Sixty-channel surface wave data were acquired in an Arizona desert. For a 10-layer model with a thickness of over 20 m, the data were first inverted to obtain S-wave velocities by the multichannel analysis of surface waves (MASW) method and then quality factors were determined by inverting attenuation coefficients.     

塔里木盆地西部含盐系地层成盐元素的地球化学初步研究

钾矿是我国目前紧缺的矿种之一 ,钾矿的寻找对我国有着十分重要的意义。塔里木盆地是我国第三系地层的广泛发育区域 ,有一定的找钾远景 ,尤其是库车、莎车等地区。通过对塔里木盆地 (坳陷 )西部的区域地质概况、成矿条件等的介绍 ,运用地球化学的分析测试手段 ,对塔里木盆地西部采集到的样品作了地球化学分析。论述了该区成盐沉积的地球化学特征 ,并讨论了该区形成钾矿的可能性。     

地下管线探测工程的资料自动化整理

地下管线探测工程一般分为野外探测和室内资料整理两阶段。内业整理包括成果表的编制、管线综合分布平面图和管线数据库。由于管线探测工程数据多,为了充分利用外业探测成果,应用Visual Basic 6.0(VB6)开发了一套地下管线管理信息系统(UTMIS),该系统实现了地下管线探测工程内业整理的自动化,极大地提高了工作效率数据精确度。     

多孔结构矿物（岩石）及其环境修复材料的实用性

具有多孔结构的矿物(岩石)作为一类特殊的工业原材料，在环境修复领域的应用前景正在成为研究热点。本文从微孔的尺度、结构、形态、成分等表面固体特征出发，概括性地论述了凹凸棒石、海泡石、蒙脱石、沸石、硅藻土等十几种多孔结构矿物(岩石)在环境修复工程中用作过滤材料、吸附剂、离子交换剂和催化剂等材料时的基本特征和使用时应注意的问题。