胶东中生代构造体制转折过程中流体演化和金的大规模成矿

胶东是我国最大的金矿产出集中区,依据矿床和矿点的密集程度,可分为招远-莱州-平度、蓬莱-栖霞、牟平-乳山三个成矿带,区域内金矿类型可主要分为石英脉型和蚀变岩型。高精度的单矿物 Ar-Ar、Rb-Sr 同位素及热液锆石离子探针测年研究业已证买,金成矿的时代为120±10Ma,金矿床载金矿物-黄铁矿、矿石-黄铁矿石英脉、控矿围岩-花岗岩和变质岩等及伴生脉岩的 Sr-Nd 放射性同位素研究也证明,金成矿物质具有多源性,既来自于控矿围岩-花岗岩和变质岩,又来自于幔源的岩浆岩,流体包裹体研究表明,各类金矿具有一致的成矿流体介质条件,为低盐度 H_2O-CO_2-NaCl±CH_4流体,金成矿温度、压力条件近似,主成矿温度为170～335℃,成矿压力为70～250MPa。氢氧等稳定同位素结果表明,成矿流体可能来源于与金矿床伴生的基性幔源岩浆脱水形成的岩浆水,但在地壳浅部遭受到大气降水的混合。因此,胶东各类型金矿是在同一成矿背景下形成的矿床,与区域内中生代构造体制转折作用有关,也是中生代构造体制转折的表现形式之一。     

桐柏造山带古元古代变质基性岩的锆石U-Pb年龄及其地质意义

桐柏造山带位于秦岭和大别造山带之间,其北侧对应于北秦岭中高级变质杂岩,南侧对应于大别山高压/超高压变质杂岩.锆石U-Pb定年在一个榴辉岩中获得其原岩侵位年龄和锆石重结晶或生长年龄分别为(1961±23) Ma和(1949±51) Ma,在一个石榴角闪岩(退变榴辉岩？)中获得其变质年龄为(1936±26) Ma,表明这两种基性岩石在二叠-三叠纪高压变质之前经历了古元古代变质作用的影响.由桐柏—大别—苏鲁造山带可利用的年代学资料确定,扬子陆块北缘发育的古元古代构造热事件可分为两幕,第一幕发生在约1.97～1.93 Ga,可能与Columbia超大陆的聚合有关;第二幕发生在约1.85～1.82 Ga,或者代表Columbia超大陆汇聚的继续,或者是陆块边缘增生过程的结果.     

西藏波龙斑岩铜金矿床的Re-Os同位素年龄及其地质意义

波龙斑岩铜金矿紧邻多不杂矿床,是多龙矿集区内新发现的一个超大型矿床。波龙矿床早期有两次成矿花岗闪长斑岩侵位,随后较晚期花岗斑岩侵位;地表广泛分布绢英岩化蚀变,深部发育钾化。本文对采于波龙斑岩型铜金矿床内石英-辉钼矿脉中的4件辉钼矿样品进行了Re-Os同位素测试,获得等时线年龄为119.4±1.3Ma (MSWD=0.63, n=4)。此年龄代表了波龙矿床的成矿年龄,与多不杂斑岩型铜金矿床的成矿年龄一致。波龙和多不杂斑岩型铜金矿床紧邻,并具有一致的成矿年龄,可能表明两个矿床的成矿受控于相同的构造-岩浆-成矿事件;斑岩铜矿具有成群分布的特征,波龙和多不杂斑岩铜金矿床的发现也暗示多龙矿集区具有找到其他大型斑岩铜金矿的潜力。     

华北克拉通前寒武纪BIF铁矿研究:进展与问题

研究表明,BIF铁矿在华北克拉通的分布具有一定规律性.大规模BIF铁矿主要发育在绿岩带分布区的鞍山-本溪、冀东、霍邱-舞阳、五台、鲁西和固阳等地;华北克拉通时代最古老的BIF形成于古太古代,最年轻BIF形成于古元古代早期,但BIF铁矿的峰期为新太古代晚期(2.52 ～2.56Ga);BIF铁矿类型可划分为阿尔戈马型和苏比利尔湖型两类,但华北以晚太古代绿岩带中的阿尔戈马型为主,仅吕梁的古元古代袁家村铁矿具典型苏比利尔湖型铁矿特征.根据BIF在绿岩带序列中的产出部位和岩石组合关系,可将华北BIF划分为:1)斜长角闪岩(夹角闪斜长片麻岩)-磁铁石英岩组合;2)斜长角闪岩-黑云变粒岩-云母石英片岩-磁铁石英岩组合;3)黑云变粒岩(夹黑云石英片岩)-磁铁石英岩组合;4)黑云变粒岩-绢云绿泥片岩-黑云石英片岩-磁铁石英岩组合;5)斜长角闪岩(片麻岩)-大理岩-磁铁石英岩组合等5种类型.华北克拉通BIF形成时代与早前寒武纪岩浆活动的时间基本一致(2.5～2.6Ga),但与华北克拉通陆壳增生的峰期(2.7～2.9Ga)有一定偏差,其原因可能与新太古代晚期华北克拉通构造-热事件十分强烈有关.华北克拉通新太古代BIF大多形成于岛弧环境,但局部地区(如固阳)BIF铁矿可能形成于深部有地幔柱叠加的岛弧环境.华北克拉通BIF富矿主要有三种类型:原始沉积、受后期构造-热液叠加改造和古风化壳等,但总体不发育富铁矿,国外发育的风化壳型富铁在我国甚为少见.本文认为在探讨BIF铁矿类型时,需要从绿岩带发育序列进行综合判别.阿尔戈马型铁矿一般产于克拉通基底(绿岩带)环境,苏比利尔湖型铁矿一般形成于稳定克拉通上的海相沉积盆地或被动大陆边缘.华北克拉通BIF铁矿地球化学研究结果表明,BIF铁矿无Ce负异常且Fe同位素为正值,从而暗示铁矿沉淀的环境为低氧或缺氧环境,而铕正异常可能指示BIFs为热水沉积成因,其机制可能为海水对流循环从新生镁铁质-超镁铁质洋壳中淋滤出F(e)和Si等元素,在海底排泄沉淀成矿,而条带状构造的形成可能归咎于成矿流体的脉动式喷溢.但对于BIF铁矿的物质来源、成矿条件和机制、富铁矿成因、华北克拉通不发育苏比利尔湖型铁矿的原因等方面,仍需深入研究.     

四川黑牛洞铜矿床磁黄铁矿的标型特征及成矿指示意义

黑牛洞铜矿床是近年来国内发现的富铜矿床之一.磁黄铁矿是该矿床中含量最高的金属矿物,且与该矿床最重要的矿石矿物黄铜矿共生.本文试图通过研究磁黄铁矿的矿物学特征,为揭示黑牛洞铜矿床的成因提供重要参考信息.本文运用电子探针、扫描电镜、X射线衍射分析和矿相显微镜观测等方法,对黑牛洞不同产状磁黄铁矿进行了形貌、化学组成和结构分析.研究表明不同矿石类型的磁黄铁矿均为六方晶系,其Fe原子含量的百分比变化范围是42.43%～45.58%.在Fe-S相图中,黑牛洞矿床的磁黄铁矿位于磁黄铁矿和黄铁矿共生相区.据研究,黑牛洞矿床中磁黄铁矿的成分、结构和矿物组合中罕见黄铁矿等信息寓示磁黄铁矿的峰期变质温度高于450℃.该矿床中磁黄铁矿至少有两种成因,即主要从流体中沉淀并受变质的磁黄铁矿和少量由黄铁矿变质脱硫而成的磁黄铁矿.黑牛洞矿床矿体和蚀变围岩中石墨广泛发育表明,变质过程处于强还原环境,而还原环境中S在流体中的溶解度较小且易于沉淀.矿床中黑色电气石的普遍产出表明中高温热液存在.这与磁黄铁矿的标型特征相对应.中高温流体存在、强还原环境和碳质的催化作用等为黄铁矿变质形成磁黄铁矿提供了有利的条件,也为黑牛洞铜矿床铜元素在韧性剪切带形成的有利客矿空间中沉淀、再富集提供了必要的物理化学条件.     

相图测定成矿压力方法的评述

本文对国内外广泛应用相图测定成矿压力的方法进行了评述。文中讨论了引起相图测定成矿压力不确切性的各种因素,并提出了消除或减弱这些影响因素的措施,以利于进一步提高利用相图进行成矿压力测定的精度。     

Fissure swarms and fracture systems within the Western Volcanic Zone,Iceland – Effects of spreading rates

The Western Volcanic Zone (WVZ) in Iceland is ∼120 km long and 40 km wide. It offers an opportunity to study rift zones in a local ultra-slow spreading area close to a hotspot. Fractures were mapped from aerial photographs and digital elevation models. Most surface fractures are located in the southern part of the WVZ. The majority of the fractures have a north-northeasterly orientation, some deviations occur from this, especially in the north part of the WVZ. Fracture orientations are therefore quite uniform in the southern, faster spreading part of the WVZ, but more irregular in the slower-spreading northern part. This suggests different stress fields in the north part, which could be due to the influence of the Hreppar microplate and possibly also due to stress fields induced by crustal deformation because of changes in glacial load in the area. Such glacially-induced stress fields may have similar or even more influence than crustal spreading in the slower spreading northern part of the WVZ. Lower fracture density towards the north within the WVZ suggests lower frequency of rifting events in the north part, in accordance with less spreading in the north as measured by GPS geodetic measurements.     

Nonlinear aspects of sea surface temperature in Monterey Bay

Nonlinear aspects of sea surface temperature (SST) in Monterey Bay are examined, based on an 85-year record of daily observations from Pacific Grove, California. Oceanic processes that affect the waters of Monterey Bay are described, processes that could contribute to nonlinearity in the record. Exploratory data analysis reveals that the record at Pacific Grove is non-Gaussian and, most likely, nonstationary. A more recent test for stationarity based on a power law approximation to the slope of the power spectrum indicates that the record is stationary for frequencies up to ∼8 cycles per year (∼45 days), but nonstationary at higher frequencies. To examine the record at Pacific Grove for nonlinear behavior, third-order statistics, including the skewness, statistical measures of asymmetry, the bicorrelation, and the bispectrum, were employed. The bicorrelation revealed maxima located approximately 365 days apart, reflecting a nonlinear contribution to the annual cycle. Based on a 365-day moving window, the running skewness is positive almost 80% of the time, reflecting the overall impact of warming influences. The asymmetry is positive approximately 75% of the time, consistent with the asymmetric shape of the mean annual cycle. Based on the skewness and asymmetry, nonlinearities in the record, when they occur, appear to be event-driven with time scales possibly as short as several days, to several years. In many cases, these events are related to warm water intrusions into the bay, and El Niño warming episodes.The power spectrum indicates that the annual cycle is a dominant source of variability in the record and that there is a relatively strong semiannual component as well. To determine whether or not the annual and semiannual cycles are harmonically related, the bispectrum and bicoherence were calculated. The bispectrum is nonzero, providing a strong indication of nonlinearity in the record. The bicoherence indicates that the annual cycle is a major source of nonlinearity and further implies that the annual and semiannual cycles are harmonically related. Based on the wavelet power spectrum (WPS), the appearance of the semiannual cycle is transitory; however, pathways between the annual and semiannual cycles appear at certain times when nonlinear interaction between them could occur. Comparisons between the WPS and the running skewness suggest that there is a tendency for periods when pathways exist, to coincide with increased positive skewness, and, often, with El Niño warming episodes. The Hilbert-Huang transform, a relatively new tool for nonstationary and nonlinear spectral analysis, was used to further examine the origin of the semiannual cycle. The time-dependent Hilbert spectrum reveals large and erratic variations in frequency associated with semiannual cycle but far greater stability associated with the annual cycle. As a result, the time-integrated Hilbert spectrum does not indicate the presence of a semiannual cycle. The method of surrogates from the field of nonlinear dynamics was also employed to test the Hopkins record for nonlinearity. Differences between the data and the surrogates were found that were statistically significant, implying the existence of nonlinearity in the record. Using the method of surrogates together with a one-year moving window, El Niño warming episodes appear to be a likely source of nonlinearity, consistent with the other analyses that were performed. Finally, the influence of stochastic variability due to serial correlation in the data was examined by comparing standardized statistics for the observations and for simulations based on an autoregressive model whose properties were obtained from the observations. The magnitude of the variability for the simulations was found to be far less than that associated with the original data, and thus stochastic variability does not appear to be a factor that significantly affects the interpretation of our results.     

华北克拉通北缘三叠纪金矿床地质特征、物质来源与控制因素SCIEI北大核心CSCD

三叠纪是华北克拉通重要的成矿期,三叠纪金矿主要分布在华北克拉通北缘,构成一条近东西向延伸、长约1500km的金成矿带,其中包括乌拉山-大青山、张家口、冀东-辽西、青城子及夹皮沟等多个金矿集中区。华北克拉通北缘三叠纪金矿带的赋矿围岩主要为新太古代-中元古代变质岩系和中生代花岗岩类,金矿床以石英脉型矿化为主,伴随蚀变岩型矿化;中、西段金矿集中区矿化组合表现为金或金钼矿化,东段则以金多金属矿化为主。同位素年代学资料表明,该带金矿主要形成于晚三叠世(240~220Ma);流体包裹体特征表明,成矿流体具中温、低盐度、低密度特征,属于H_(2)O-NaCl-CO_(2)±CH_(4)体系,相分离作用可能是石英脉型金矿金沉淀的主要机制;氢-氧同位素组成进一步表明,成矿流体早期为岩浆水或变质水,后期混入了大气降水。矿石碳、硫、铅、氦-氩同位素及金矿集中区内成矿相关岩体的钕、铪同位素组成表明,华北克拉通北缘三叠纪金矿床的成矿流体和成矿物质均与壳-幔混合作用有关,其中,幔源物质及流体的贡献与区域三叠纪岩浆活动有关,壳源组分的贡献主要来自前寒武纪变质围岩。金矿床形成的构造背景整体上与中亚造山带造山后伸展作用有关:晚三叠世,华北北缘受中亚造山带碰撞后伸展作用的影响,发生岩石圈首次减薄事件,同时发育多条深大断裂及碱性花岗岩-碱性岩的侵入活动,为大规模区域金矿的形成提供了优越条件。金矿带的东段可能同时受扬子克拉通与华北板块碰撞作用的影响,是造成其与中、西段金矿集中区成矿特征有一定差异的主因。     

西南三江金厂河矽卡岩型多金属矿床铁同位素分馏机制及其对成矿物质来源的制约SCIEI北大核心CSCD

金厂河矿床是西南三江成矿省保山地块最具代表性的远端矽卡岩型多金属矿床之一,查明其成矿金属来源对理解该类矿床成因以及区域成矿规律具有重要意义。本文通过分析不同成矿阶段代表性含铁矿物的铁同位素组成,探讨其在成矿过程中的分馏机制,从而示踪成矿金属的源区特征。金厂河矽卡岩型矿床中成矿前阶段未蚀变的石榴子石和氧化物成矿阶段的磁铁矿均相对富集铁的重同位素,其δ;Fe值分别为0.05‰~0.16‰和0.07‰~0.18‰,而硫化物成矿阶段的黄铁矿和黄铜矿则相对富集铁的轻同位素,其δ;Fe值分别为-0.12‰~0.17‰和-0.54‰~-0.38‰,整体显示出从高氧逸度的成矿前阶段向低氧逸度的硫化物成矿阶段演化过程中矿物δ;Fe值逐渐降低的趋势,指示Fe;富集铁的重同位素,Fe;富集铁的轻同位素。同时,金厂河矿床各阶段矿物的δ;Fe值均显著低于碳酸盐围岩,而接近全球花岗岩的δ;Fe值,表明成矿的铁不是由围岩贡献,而是来自于隐伏的中酸性岩体。