Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks?

The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd.     

厚碳酸盐岩覆盖区RVSP三维地震勘探应用效果分析

该文以中国南方一厚碳酸盐岩覆盖区的RVSP三维地震勘探实例,对RVSP三维地震勘探观测系统和数据采集参数的确定、地面等效处理和波场分离等关键处理技术及地质效果进行了阐述和分析,说明了RVSP在克服表浅层复杂地质条件及环境条件对资料的影响及提高地震资料的分辨率有其特定的优势,同时也提出了RVSP三维地震在采集和处理过程中的难点。     

Suspended sediment and total dissolved solid yield patterns at the headwaters of Urumqi River,northwestern China: a comparison between glacial and non‐glacial catchments

In order to understand the differences in the suspended sediment and total dissolved solid (TDS) yield patterns between the glacial and non‐glacial catchments at the headwaters of Urumqi River, northwestern China, water samples were collected from a glacier catchment and an empty cirque catchment within the region, during three melting seasons from 2006 to 2008. These samples were analyzed to estimate suspended sediment and TDS concentrations, fluxes and erosion rates in the two adjoining catchments. There were remarked differences in suspended sediment and TDS yield patterns between the two catchments. Suspended sediment concentrations were controlled mainly by the sediment source, whereas TDS concentrations were primarily related to the hydrologic interaction with soil minerals. Generally, the glacial catchment had much higher suspended sediment and TDS yields, together with higher denudation rates, than the non‐glacial catchment. Overall, glacial catchment was mainly dominated by physical denudation process, whereas the non‐glacial catchment was jointly influenced by physical and chemical denudation processes. The observed differences in material delivery patterns were mainly controlled by the runoff source and the glacial processes. The melting periods of glacier and snow were typically the most important time for the suspended sediment and TDS yields. Meanwhile, episodic precipitation events could generate disproportionately large yields. Subglacial hydrology dynamics, glaciers pluck and grind processes could affect erodibility, and the large quantities of dust stored on the glacier surface provided additional sources for suspended sediment transport in the glacial catchment. These mechanisms imply that, in response to climate change, the catchment behaviour will be modified significantly in this region, in terms of material flux. Copyright © 2013 John Wiley & Sons, Ltd.     

Variational analysis of dynamics of fissured poroelastic rocks

Rocks can be modeled in a continuum framework as fissured, poroelastic materials, i.e., materials with two degrees of porosity, one due to the fissures and another one due to the pores. The governing equations of motion of fissured poroelastic rocks established by Beskos are rederived here by establishing a variational statement which also provides the boundary conditions of the problem. This is accomplished by considering strain, dissipation and kinetic energies as well as the work of external forces. The above statement is also derived here by employing the method of weighted residuals.     

Hydrological cycle and water balance estimates for the megadune–lake region of the Badain Jaran Desert,China

The hydrology and water balance of megadunes and lakes have been investigated in the Badain Jaran Desert of China. Field observations and analyses of sand layer water content, field capacity, secondary salt content, and grain size reveal 3 types of important natural phenomenon: (a) vegetation bands on the leeward slope of the megadunes reflect the hydrological regime within the sandy vadose zone; (b) seepage, wet sand deposits, and secondary salt deposits indicate the pattern of water movement within the sandy vadose zone; (c) zones of groundwater seeps and descending springs around the lakes reflect the influence of the local topography on the hydrological regime of the megadunes. The seepage exposed on the sloping surface of the megadunes and gravity water contained within the sand layer confirm the occurrence of preferential flow within the vadose zone of the megadunes. Alternating layers of coarse and fine sand create the conditions for the formation of preferential flows. The preferential flows promote movement of water within the sand layer water that leads to deep penetration of water within the megadunes and ultimately to the recharging of groundwater and lake water. Our results indicate that a positive water balance promotes recharge of the megadunes, which depends on the high permeability of the megadune material, the shallow depth of the surface sand layer affected by evaporation, the occurrence of rainfall events exceeding 15 mm, and the sparse vegetation cover. Water balance estimates indicate that the annual water storage of the megadunes is about 7.5 mm, accounting for only 8% of annual precipitation; however, the shallow groundwater per unit area under the megadunes receives only 3.6% of annual precipitation, but it is still able to maintain a dynamic balance of the lake water. From a water budget perspective, the annual water storage in the megadunes is sufficient to serve as a recharge source for lake water, thereby enabling the long‐term persistence of the lakes. Overall, our findings demonstrate that precipitation is a significant component of the hydrological cycle in arid deserts.     

New P–T constraints on the Tamayen glaucophane‐bearing rocks,eastern Taiwan: Perple_X modelling results and geodynamic implications

New pseudosection modelling was applied to better constrain the P–T conditions and evolution of glaucophane‐bearing rocks in the Tamayen block of the Yuli belt, recognized as the world's youngest known blueschist complex. Based on the predominant clinoamphibole, textural relationships, and mineral compositions, these glaucophane‐bearing high‐P rocks can be divided into four types. We focused on the three containing garnet. The chief phase assemblages are (in decreasing mode): amphibole + quartz + epidote + garnet + chlorite + rutile/titanite (Type‐I), phengite + amphibole + quartz + garnet + chlorite + epidote + titanite + biotite + magnetite (Type‐II), and amphibole + quartz + albite + epidote + garnet + rutile + hematite + titanite (Type‐III). Amphibole exhibits compositional zoning from core to rim as follows: glaucophane → pargasitic amphibole → actinolite (Type‐I), barroisite → Mg‐katophorite/taramite → Fe‐glaucophane (Type‐II), glaucophane → winchite (Type‐III). Using petrographic data, mineral compositions and Perple_X modelling (pseudosections and superimposed isopleths), peak P–T conditions were determined as 13 ± 1 kbar and 550 ± 40 °C for Type‐I, 10.5 ± 0.5 kbar and 560 ± 30 °C for Type‐II (thermal peak) and 11 ± 1 kbar and 530 ± 30 °C for Type‐III. The calculations yield higher pressures and temperatures than previously thought; the difference is ~1–6 kbar and 50–200 °C. The three rock types record similar P–T retrograde paths with clockwise trajectories; all rocks followed trajectories with substantial pressure decrease under near‐isothermal conditions (Type‐I and Type‐III), with the probable exception of Type‐II where decompression followed colder geotherms. The P–T paths suggest a tectonic environment in which the rocks were exhumed from maximum depths of ~45 km within a subduction channel along a relative cold geothermal gradient of ~11–14 °C km^?1.     

Obsidian from the northern sector of the Main Ethiopian Rift: implications for archeology

Obsidian is abundant in the Main Ethiopian Rift (MER). Petrological and geochemical features of obsidian from four volcanic centers in the MER, namely Birenti, Dofen, Fentale and Kone, are presented. Compositional and petrological variability is noted among the Dofen and Fentale obsidian, but not in those from Kone and Birenti where each have separate but uniform elemental composition. The Fentale and Kone obsidian were source materials for the artifacts of a number of Middle Stone Age and Later Stone Age/Neolithic sites in the region. We have yet to determine whether Dofen and Birenti were sources for archeological artifacts. The study also shows that volcanic episodes from a single center do not necessarily result in compositional variability.     

A newly defined Late Ordovician magmatic‐thermal event in the Mt Painter Province,northern Flinders Ranges,South Australia

Magmatism,metamorphism and metasomatism in the Palaeoproterozoic‐Mesoproterozoic Mt Painter Inlier and overlying Neoproterozoic Adelaidean rocks in the northern Flinders Ranges (South Australia) have previously been interpreted as resulting from the ca 500 Ma Delamerian Orogeny. New Rb–Sr, Sm–Nd and U–Pb data, as well as structural analysis,indicate that the area also experienced a second thermal event in the Late Ordovician (ca 440 Ma). The Delamerian Orogeny resulted in large‐scale folding, prograde metamorphism and minor magmatic activity in the form of a small volume of pegmatites and leucogranites. The Late Ordovician event produced larger volumes of granite (the British Empire Granite in the core of the inlier) and these show Nd isotopic evidence for a mantle component. The high‐temperature stage of this magmatic‐hydrothermal event also gave rise to unusual diopside‐titanite veins and the primary uranium mineralisation in the basement, of which the remobilisation was younger than 3.5 Ma. It is possible that parts of the Mt Gee quartz‐hematite epithermal system developed during the waning stages of the Late Ordovician event. We suggest that the Ordovician hydrothermal system was also the cause of the commonly observed retrogression of Delamerian metamorphic minerals (cordierite, andalusite) and the widespread development of actinolite, scapolite, tremolite and magnetite in the cover sequences. Deformation during the Late Ordovician was brittle. The recognition of the Late Ordovician magmatic‐hydrothermal event in the Mt Painter Province might help to link the tectonic evolution of central Australia and the southeast Australian Lachlan Fold Belt.     

基于开源GIS的黑龙江省农村土地确权影像分发软件开发与应用

黑龙江省农村土地确权影像分发面向地方农委和农业局等弱GIS对象,弱GIS对象缺乏专业GIS知识和软件,在使用、管理、查询、分发影像过程中存在困难。本文基于开源组件Dotsaptial设计和开发黑龙江省农村土地确权影像分发软件,满足相关对象对影像浏览、查询、统计、二次分发的需求,提高了黑龙江省农村土地确权影像分发服务质量。     

Shape of pinch and swell structures as a viscosity indicator: Application to lower crustal polyphase rocks

Pinch and swell structures occur where a more competent layer in a weaker matrix is subjected to layer-parallel extension. In this contribution, we use numerical models to explore the use of pinch and swell structure shape symmetry and asymmetry as a determinant of relative viscosity between layers. Maximum asymmetry is attained when the matrix viscosity on one side is subtly weaker than the competent layer, while the other side is significantly weaker.Our numerical results are directly applied to asymmetrically developed pinch and swell structures in exposed lower continental crust. Here, shape geometries observed in a shear zone comprised of plagioclase-dominated, garnet-dominated and mixed amphibole-plagioclase-dominated bands, reveals that the plagioclase-dominated band is the most competent band and is marginally stronger (2×) and significantly stronger (10–40×) than the fine grained garnet-dominated and mixed amphibole-plagioclase-dominated band, respectively. Based on the experimentally determined viscosity of a plagioclase-dominated material and quantitative microstructural analysis, the viscosity range of the natural rock bands is 2.8 × 10¹⁵ to 1.1 × 10¹⁷ Pa s. Consequently, the assumption that the experimentally-derived plagioclase flow law is an appropriate proxy for the middle to lower continental crust may lead to a viscosity over-estimation by up to forty times.