塔东地区古城4井上寒武统—中、上奥陶统流体地球化学示踪

通过对塔东地区古城4井上寒武统和中、上奥陶统碳酸盐岩围岩及充填物的碳、氧、锶同位素地球化学和流体包裹体成分的对比研究表明,充填于中、上奥陶统和上寒武统的流体分属于2个不同来源的流体体系。充填于中、上奥陶统灰岩裂缝中方解石脉的w(87Sr)/w(86Sr)介于0.7084~0.7088,它与早奥陶世海水的w(87Sr)/w(86Sr)相近;流体体系为CH4-H2O体系;充填物与围岩间具有明显的碳、氧同位素差异,表明上部流体体系中的流体来自于奥陶系地层本身。上寒武统白云岩裂缝中方解石脉的w(87Sr)/w(86Sr)为0.7138,明显地高于同时代海水的锶同位素值;流体体系为CO2-H2O体系;下部流体体系中的流体为外来富锶流体。上、下流体体系间互不连通暗示着上寒武统地层具有相对较好的保存条件。     

The characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin

The Central Gas Field is a famous large-sized gas field in the Ordos Basin of China. However, identification of main gas sources of the Ordovician reservoirs in this gas field remains puzzling. On the basis of a lot of geochemical data and geological research on natural gases, the characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin were studied. The results indicated that natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin have similar chemical and isotopic compositions to highly mature and over-mature dry gases. Both coal-derived gases and oil-type gases coexist in the Central Gas Field in the Ordos Basin. The former was derived mainly from Carboniferous-Permian coal measures and the latter from Lower Paleozoic marine carbonates. It is suggested that coal-derived gases occur in the eastern part of the Central Gas Field while oil-type gases may be produced mainly in the northern, western and southern parts of the Central Gas Field in the Ordos Basin.     

Application of Spectral Decomposition to Detection of Fracture-Cavity Carbonate Reservoir Beds in the Tahe Oiifieid, Tarim Basin, NW China

Ordovician fracture-cavity carbonate reservoir beds are the major type of producing formations in the Tahe oilfield, Tarim Basin. The seismic responses of these beds clearly changes depending on the different distance of the fracture-cavity reservoir bed from the top of the section. The seismic reflection becomes weak or is absent when the fracture-cavity reservoir beds are less than 20 ms below the top Ordovician. The effect on top Ordovician reflection became weaker with deeper burial of fracture-cavity reservoir beds but the developed deep fracture-cavity reservoir beds caused stronger reflection in the interior of the Ordovician. This interior reflection can be divided into strong long-axis, irregular and bead string reflections, and was present 80 ms below the top Ordovician. Aimed at understanding reflection characteristics, the spectral decomposition technique, which uses frequency to ＂tune-in＂ bed thickness, was used to predict Ordovician fracture-cavity carbonate formations in the Tahe oilfield. Through finely adjusting the processing parameters of spectral decomposition, it was found that the slice at 30 Hz of the tuned data cube can best represent reservoir bed development. Two large N-S-trending strong reflection belts in the mid-western part of the study area along wells TK440- TK427-TK417B and in the eastern part along wells TK404-TK409 were observed distinctly on the 30 Hz slice and 4-D time-frequency data cube carving. A small N-S trending reflection belt in the southern part along wells T403-TK446B was also clearly identified. The predicted reservoir bed development area coincides with the fracture-cavities connection area confirmed by drilling pressure testing results. Deep karst cavities occur basically in three reservoir bed-development belts identified by the Ordovician interior strong reflection. Spectral decomposition proved to be a useful technique in identifying fracture-cavity reservoir beds.     

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters     

鄂尔多斯盆地靖边气田马五_(1+2)气藏储集单元研究

综合地震、地质、测井等信息,考虑沉积、成岩、地貌、生产动态等多因素,在沟槽识别和致密带研究基础上,通过井间干扰、油层压力变化和试井边界响应分析,按照局部、就近原则对靖边气田马五1+2气藏进行了储集单元划分。共划分出111个储集单元,其中独立型69个,复合型42个。这些储集单元的面积多介于10～50km2之间,单个储集单元的井数一般少于6口。在对气藏储层特征综合认识的基础上,确定流动单元划分思路与流程,并认为关键环节包括古沟槽识别、致密带研究、动静结合确定储集单元等3个方面。储集单元一方面受控于被致密岩相包围的有利成岩相带,宏观上与弱—中等充填泥粉晶白云岩相对应性好;另一方面又受各级古沟槽夹持,在两个一级古沟槽之间往往共生多个储集单元,而这些储集单元边界又严格地受二级或三级沟槽切割控制。     

Multiple magnetization events in the Red River carbonates, Williston Basin, Canada: Evidence for fluid-flow?

Samples collected from the Upper Ordovician Red River carbonates in a well at the centre of the Williston Basin revealed two paleomagnetic components with different inclinations, 60.3 ± 3.9° (k = 70.7, N = 12) and 20.4 ± 3.3° (k = 141.2, N = 8), but similar declination values in individual specimens. Inclination-only analysis indicates two possible scenarios for the age of these two magnetizations: in scenario (a) the timing of magnetization happened sometime between Late Ordovician to Devonian; and in scenario (b) there are two different remagnetizations, one that overlaps Pennsylvanian to Permian time while the other can have either a Late Jurassic or a Tertiary age. Whereas dolomitization and some isotopic data tend to support scenario (a), previous paleomagnetic data from the Williston Basin and from younger units in the same well, the tectonic evolution of the basin, and the hydrocarbon maturation pattern in the Red River carbonates all favour chemical remagnetization(s) driven by orogenic fluids during the Alleghenian and Laramide orogenies.     

Alpine reworking of Ordovician protoliths in the Western Carpathians: Geochronological and geochemical data on the Muráñ Gneiss Complex, Slovakia

Magmatic protoliths of Ordovician age have been identified in the metamorphic rocks of the Muráñ Gneiss Complex, Veporic Unit (Central Western Carpathians). Vapor digestion single zircon U–Pb dating yields an intrusion age of 464 ± 35 Ma (upper intercept) for the granite protolith. A lower intercept age of 88 ± 40 Ma records amphibolite-facies metamorphic overprint in the Cretaceous, during the Alpine orogeny. Geochemical and isotopic data suggest crustal origin of the orthogneiss. Nd_initial are between − 2.6 and − 5.0 and T_DM^Nd between 1.3 and 1.5 Ga (two-step approach). ⁸⁷Sr / ⁸⁶Sr_initial ratios vary between 0.7247 and 0.7120, and a steep REE pattern further constrains the crustal affinity of these rocks. Associated amphibolite bodies have Nd_initial values of 6.5, ⁸⁷Sr / ⁸⁶Sr_initial ratio of 0.7017, and a flat REE pattern. They are interpreted as MORB derived metabasites. Whole-rock Pb isotope analyses define a linear array in a ²⁰⁶Pb / ²⁰⁴Pb vs. ²⁰⁷Pb / ²⁰⁴Pb diagram with an age of ca. 134 Ma, consistent with intense Alpine metamorphism and deformation.

These basement rocks of the Central Western Carpathians are interpreted as Ordovician magmatic rocks intruded at an active margin of Gondwana. They represent the eastern prolongation of Cambro–Ordovician units of the European Variscides, which were part of the peri-Gondwana superterrane and accreted to Laurussia during the Variscan orogeny. Variscan metamorphic overprint is not recorded by the isotopic data of the Muráñ Gneiss Complex. Alpine metamorphism is the most dominant overprint.     

藏北申扎地区奥陶纪鹦鹉螺类一新属（Variabioceras）

文中材料是采自西藏申扎县塔尔玛乡桥东—扎扛一带鹦鹉螺化石的一部分。描述了3属6种。其中有1个新属Variabioceras gen.nov．和3个新种V．typicum gen．etsp．nov．，V．zangbeiense gen．et sp．nov．，V．robustum gen．et sp．nov．     

渭北东部奥陶系岩溶地下水环境同位素特征分析

本文通过对渭北东部岩溶地下水环境同位素组成特征的研究,分析了大气降水、地表水、地下水三者之间的转化关系,并对研究区岩溶地下水的形成进行了初步探讨,认为大气降水是研究区岩溶地下水的补给源,地表水与地下水之间存在水力联系,地表水对地下水的补给占补给水源的74.3%.西部岩溶裸露区为岩溶水的直接补给区,其周边浅埋区为岩溶水的间接补给区,东南部的岩溶中-深埋区为岩溶水的径流排泄区.     

内蒙古大青山地区寒武系与奥陶系之间的一个重要的层序界面

大青山地区寒武纪－奥陶纪地层分布零星，是由中生代逆冲推覆构造就位于此的一系列近东西向延展的构造岩片组成。下寒武统色麻沟组直接覆盖在太古界变质岩之上，缺失中元古界什那干群，寒武系与奥陶系之间呈假整合接触，标志着区内寒武纪与奥陶纪之间发生过一次抬升构造运动，其形成机制与古亚洲洋内的稳定陆快向华北板块拼贴事件有关，是早奥陶世末期华北板块整体抬升的序幕。这个层序界面的认识，对于恢复华北板块北部边缘构造演化历史具有重要意义。