内蒙古中西部宝音图群云母片岩的变质P-T轨迹与锆石年代学研究

位于内蒙古中西部地区的宝音图群,主要由云母片岩、斜长角闪岩、石英岩和大理岩等组成。其中云母片岩中发育典型的巴罗式递增变质带,目前对于该递增变质带的研究非常薄弱。本文对宝音图群的云母片岩开展了系统的岩相学、矿物化学、相平衡模拟以及锆石U-Pb年代学的研究。岩相学研究结果显示,三个云母片岩样品具有不同的峰期矿物组合,分别为石榴子石+白云母+黑云母+斜长石+石英,十字石+白云母+黑云母+斜长石+钛铁矿+石英,石榴子石+蓝晶石+白云母+黑云母+斜长石+钛铁矿+石英。此外,样品LS93和LS07存在晚期红柱石的叠加。相平衡模拟研究限定三个云母片岩的峰期温度压力分别为：577℃、0.73 GPa, 620℃、0.78 GPa和670℃、0.8 GPa,具有递增型特征,其峰期温度压力指示的地热梯度为18～20℃/km,为典型的中压相系;此外,三个样品的P-T轨迹均显示早期升温升压直至峰期阶段,随后降温降压的顺时针型,反映地壳加厚和后期抬升的演化过程。云母片岩中的锆石发育典型的变质边结构,变质边的Th/U=0.004～0.02,锆石U-Pb年代学结果显示该变质年龄为398±6 Ma,代表峰期或近峰期阶...     

石笋的荧光特征及其高分辨率气候环境记录

在分析石笋荧光特征的基础上，综述了石笋荧光应用于高分辨率气候环境记录的研究进展。石笋荧光强度反映了石笋中的有机酸含量，荧光波长特征受石笋中有机酸类型的控制，石笋中的有机酸由地表有机质经土壤水、洞穴滴水运移随碳酸盐而淀积，荧光强度与波长特征都是对地表气候环境信息的响应。通过提高荧光谱扫描精度，可得到高分辨率(1～10a)的气候环境变迁记录。分析了目前研究中存在的问题，并对发展趋势和进一步研究方向提出看法。     

The Pushtashan juvenile suprasubduction zone assemblage of Kurdistan (northeastern Iraq): A Cretaceous (Cenomanian) Neo-Tethys missing link

The Pushtashan suprasubduction zone assemblage of volcanic rocks, gabbros, norites and peridotites occurs in the Zagros suture zone, Kurdistan region, northeastern Iraq. Volcanic rocks are dominant in the assemblage and consist mainly of basalt and basaltic andesite flows with interlayered red shale and limestone horizons. Earlier lavas tend to be MORB-like, whereas later lavas display island arc tholeiite to boninitic geochemical characteristics. Tholeiitic gabbros intrude the norites and display fractionation trends typical of crystallisation under low-pressure conditions, whereas the norites display calc-alkaline traits, suggesting their source included mantle metasomatised by fluids released from subducted oceanic crust. Enrichment of Rb, Ba, Sr, Th and the presence of negative Nb anomalies indicate generation in a suprasubduction zone setting. Trondhjemite and granodiorite intrusions are present in the volcanic rocks, gabbros and norites. SHRIMP U-Pb dating of magmatic zircons from a granodiorite yields a mean~(206)Pb/~(238)U age of 96.0 ±2.0 Ma(Cenomanian). The initial ε_(Hf) value for the zircons show a narrow range from +12.8 to+15.6, with a weighted mean of + 13.90±0.96. This initial value is within error of model depleted mantle at 96 Ma or slightly below that, in the field of arc rocks with minimal contamination by older continental crust. The compositional bimodality of the Pushtashan suprasubduction sequence suggests seafloor spreading during the initiation of subduction, with a lava stratigraphy from earlyerupted MORB transitioning into calc-alkaline lavas and finally by 96 Ma intrusion of granodioritic and trondhjemitic bodies with juvenile crustal isotopic signatures. The results confirm another Cretaceous arc remnant preserved as an allochthon within the Iraqi segment of the Cenozoic Zagros suture zone. Implications for the closure of Neo-Tethys are discussed.     

玲珑金矿区成矿后花岗斑岩脉的锆石SHRIMP U-Pb年龄对胶北地体演化的制约

采用SHRIMP测年技术对玲珑金矿区成矿后花岗斑岩脉的锆石进行了U Pb年龄测定,获得岩脉岩浆锆石的206Pb/238U平均年龄为119.4 Ma,同时获得大量的继承锆石年龄,范围从3 114~127 Ma。继承锆石年龄显示,胶北地体前寒武纪经历了中太古代的陆核生成阶段;新太古代花岗岩绿岩地体增生阶段;古元古代孔兹岩系的沉积阶段;新元古代蓬莱群盖层形成阶段。整个古生代,地体处于稳定的隆升受剥蚀状态,没有明显的岩浆活动。三叠纪,华南与华北克拉通碰撞,郯庐断裂带形成。晚三叠世—中侏罗世,后碰撞的巨大挤压作用导致华北克拉通南缘地壳增厚,玲珑和蚌埠荆山等花岗岩生成。中晚侏罗世,郯庐断裂带发生了巨大的左行平移,胶北地体从蚌埠—五河的东部推移到现在的位置。早白垩世,郯庐断裂由左旋压扭向右行拉张转化,导致胶北地体上郭家岭岩体生成。中晚白垩世,郯庐断裂发生了大规模的拉张,导致沂沭裂谷、胶莱盆地、青山组火山岩、金矿床形成和隆起区大量脉岩侵入。     

SHRIMP zircon dating and Nd isotopic systematics of Palaeoproterozoic migmatitic orthogneisses in the Epupa Metamorphic Complex of northwestern Namibia

The Epupa Metamorphic Complex constitutes the southwestern margin of the Congo Craton and is exposed in a hilly to mountainous terrain of northwestern Namibia, bordering the Kunene River and extending into southern Angola. It consists predominantly of granitoid gneisses which are migmatized over large areas. This migmatization locally led to anatexis and produced crustal-melt granites such as the Otjitanda Granite. We have undertaken reconnaissance geochemical studies and single zircon U–Pb SHRIMP and Pb–Pb evaporation dating of rocks of the Epupa Complex. The granitoid gneisses, migmatites and anatectic melts are similar in composition and constitute a suite of metaluminous to peraluminous, calc-alkaline granitoids, predominantly with volcanic arc geochemical signatures. The zircon protolith ages for the orthogneisses range from 1861 ± 3 to 1758 ± 3 Ma. Anatexis in the migmatitic Epupa gneisses was dated from a melt patch at 1762 ± 4 Ma, and the anatectic Otjitanda Granite has a zircon age of 1757 ± 4 Ma. Migmatization and anatexis therefore occurred almost immediately after granitoid emplacement and date a widespread high-temperature Palaeoproterozoic event at ∼1760 Ma which has not been recorded elswhere in northern Namibia. The Nd isotopic systematics of all dated samples are surprisingly similar and suggest formation of the protolith from a source region that probably separated from the depleted mantle about 2.4–2.0 Ga ago. A major Archaean component in the source area is unlikely.     

西藏曲水县达布斑岩铜(钼)矿床成岩成矿年代学研究

本文采用锆石LA-ICP-MS微区U-Pb测年技术,对冈底斯成矿带东段曲水县达布斑岩Cu(Mo)矿床北部达布矿区含矿斑岩体、南部显角囊含矿花岗闪长斑岩岩体进行了年代学研究,通过对3件岩体样品中单颗粒锆石的分析,达布主矿体花岗闪长斑岩样品206Pb/238U年龄加权平均值为16.5±0.05Ma(n=15,MSWD=3),达布主含矿体二长花岗斑岩样品年龄为16.1±0.13Ma(n=15,MSWD=1.03),南部显角囊矿体花岗闪长斑岩年龄为16.2±0.04Ma(n=13,MSWD=0.0064)。对达布矿床斑岩Cu(Mo)矿床主矿体中4件辉钼矿样品,显角囊矿体中6件辉钼矿样品,分别进行了Re-Os同位素测试,等时线年龄分别为14.6±0.50Ma(MSWD=0.35,主矿体)、14.8±0.23Ma(MSWD=1.3,显角囊)。结合前人研究以及本次测年结果认为:1)达布斑岩铜(钼)矿床岩体侵位的年龄应限定在16Ma左右,成矿时代为14Ma左右,成矿时间差小于0.86Ma,与区域上"成矿瞬时发生"的成矿规律是一致的;2)矿床产出于印度-亚洲大陆板块后碰撞伸展环境。     

内蒙古东乌旗巴彦都兰铜矿床地质和地球化学特征及其意义

内蒙古巴彦都兰铜矿床位于二连—东乌旗成矿带,该矿区出露下泥盆统泥鳅河组粉砂岩和海西中期黑云母花岗岩体,铜矿体呈脉状产出于泥鳅河组粉砂岩中,严格受断裂控制。主要金属矿物为黄铁矿、磁黄铁矿、黄铜矿等,脉石矿物主要为石英和碳酸盐岩等。矿区黑云母花岗岩La-ICP-MS锆石~(206)Pb/~(238) U加权平均年龄为303.5 Ma±1.1 Ma,铜矿床属于晚古生代构造-岩浆作用的产物。岩石地球化学特征反映黑云母花岗岩属准铝质-弱过铝质高钾钙碱性系列,A/CNK值介于0.99~1.04之间,高碱(w(K_2O+Na_2O)=7.36%~8.73%),富钾(w(K_2O)/w(Na_2O)=1.08~1.66),其形成具有岛弧或后碰撞环境I型花岗岩特征;微量元素特征显示岩体可能形成于后碰撞伸展阶段早期的构造环境中。黄铜矿硫同位素组成介于0.1×10~(-3)~2.1×10~(-3)之间,反映成矿所需的硫可能来自于岩浆,巴彦都兰铜矿区花岗岩很可能是成矿硫的提供者。     

Holocene rockfalls in the southern Negev Desert,Israel and their relation to Dead Sea fault earthquakes

Rockfall ages in tectonically active regions provide information regarding frequency and magnitude of earthquakes. In the hyper-arid environment of the Dead Sea fault (DSF), southern Israel, rockfalls are most probably triggered by earthquakes. We dated rockfalls along the western margin of the DSF using terrestrial cosmogenic nuclides (TCN). At each rockfall site, samples were collected from simultaneously exposed conjugate boulders and cliff surfaces. Such conjugate samples initially had identical pre-fall (“inherited”) TCN concentrations. After boulder detachment, these surfaces were dosed by different production rates due to differences in post-fall shielding and geometry. However, in our study area, pre-rockfall inheritance and post-rockfall production rates of TCN cannot be evaluated. Therefore, we developed a numerical approach and demonstrated a way to overcome the above-mentioned problems. This approach can be applied in other settings where rockfalls cannot be dated by simple exposure dating. Results suggest rockfall ages between 3.6 ± 0.8 and 4.7 ± 0.7 ka. OSL ages of sediment accumulated behind the boulders range between 0.6 ± 0.1 and 3.4 ± 1.4 ka and support the TCN results. Our ages agree with dated earthquakes determined in paleoseismic studies along the entire length of the DSF and support the observation of intensive earthquake activity around 4–5 ka.     

难熔元素和代表性放射性同位素体系分析技术的进展、问题和应用展望

Pt-Os、Re-Os和Hf-W同位素体系的母体和子体Pt、Os、Re、Hf和W以及其它铂族元素（PGE）化学性质上都是难熔的,我们将这些元素和相关同位素称为难熔元素和难熔元素放射性同位素体系。难熔元素及其放射性同位素体系不仅可以直接测定金属矿床、油气藏和沉积岩系的年龄,而且还可以有效示踪地球深部的核幔反应等过程,这是其它地球化学工具不可替代的。本文评述了当前Pt-Os、Re-Os和Hf-W同位素体系和PGE元素分析技术的研究进展,指出：（1）目前Re-Os同位素定年误差仍较大,迫切需要优化改进分析技术,大幅提高Re-Os同位素定年的准确度和成功率;（2）Pt-Re-Os和W同位素的分析技术需要简化繁琐的化学分离流程和提高仪器分析的效率,同时探索建立新的化学分离和仪器分析方法,进一步提高分析精度,实现对更低Pt、Re、Os和W含量样品的准确分析,才能更有效地示踪地球深部物质循环过程;（3）PGE的元素分析技术尚需改进,分析精度仍需要进一步提升。我们预期随着进一步提升难熔元素和代表性放射性同位素的分析精度,显著降低同位素定年误差,其将在核-幔、幔-幔和壳-幔物质循环过程示踪、金属矿床精细定年和成因机制、复杂含油气系统的定年和示踪以及中元古代环境变化等研究中得到更广泛的应用。

     

江西岿美山钨矿矿床的成矿年龄及地质特征

江西省定南县岿美山钨矿区位于南岭东西向构造带东段与武夷山北东-北北东向构造带南段的复合部位,是赣南地区以石英脉型黑钨矿和矽卡岩型白钨矿共生为特征的钨矿床,其是否为南岭地区燕山期的成矿作用,一直没有精确的年代学研究成果。本文采用锆石SHRIMP U-Pb定年和辉钼矿Re-Os同位素定年技术,对岩体年龄和成矿年龄进行了精细的测定,获得成矿黑云母花岗岩体的锆石SHRIMP U-Pb年龄为（157.7±2.7） Ma（n=11,MSWD=1.9）,黑钨矿石英脉的辉钼矿Re-Os等时线年龄为（153.7±1.5） Ma（n=5,MSWD=0.16）,显示岿美山区是华南地区中生代钨矿大规模成岩成矿作用的产物之一。根据“五层楼+地下室”的找矿模型,并结合矿区的最新找矿线索,研究认为在矿区深部岩体的内外接触带具有存在新矿体的可能性,该区深部具有较大的找矿潜力,同时探索性地提出赣南地区石英脉型钨矿深边部存在矽卡岩型钨矿化的可能,对区域钨矿的深边部找矿工作具有指导意义。