罕见矿物--六方球方解石的发现及特征

大庆油田部分三元复合驱抽油井结垢现象比较严重。井中结垢损害抽油设备，增加了生产成本。通过运用XRD，IR，SEM和化学分析手段对抽油井垢的研究发现，垢的主要化学成分为CaO和SiO2，其含量分别为67％和28％，油井垢中的主要矿物成分是罕见矿物——六方球方解石。六方球方解石呈微晶状(1—10μm)，并常常以微晶聚集的球粒状出现，同时伴生有无定形SiO2。呈游离态的SiO2和有机质对于六方球方解石的形成起到了重要作用。     

兰坪白秧坪铜银多金属矿床成矿物质来源的铅和硫同位素示踪

白秧坪铜银多金属矿床主要产于白垩系下统景星组石英砂岩、粉砂岩中，矿石铅同位素组成特征与景星组砂岩的铅同位素组成比较接近，表明壳源物质参与了成矿作用。作ZartMan图解和△γ—△β图解表明，矿石铅属于壳幔混合来源。矿石铅μ值介于9．43—9．65之间，Th/U比值介于3．72—3．87之间，表明矿石铅为壳幔混合铅。该矿床硫同位素组成表明，硫来源于深部地幔硫遭受地壳硫的混入。该矿床的成矿作用发生于开放体系之中，成矿物质来源为深部幔源物质混合了壳源物质。     

Hydrochemical and isotopic characteristics of groundwater in the Souss Upstream Basin, southwestern Morocco

Heterogeneous shallow Plio-Quaternary formations of the Souss Plain represent the most important aquifer in southern High Atlas Mountains in Morocco. The present work was conducted in the Souss Upstream Basin to identify the chemical characteristics and the origin of groundwater in an aquifer under semi-arid climate. Isotopic and hydrochemical compositions combined with geological and hydrogeological data were used for this purpose. The total dissolved solids vary from 239 to 997 mg l⁻¹, and the following groundwater types are recognized: Ca²⁺–Mg²⁺–HCO₃⁻, Ca²⁺–Mg²⁺–SO₄²⁻ and Ca²⁺–Mg²⁺–Cl⁻. The groundwater is saturated and slightly supersaturated with respect to carbonate minerals and undersaturated with respect to evaporite minerals, which means that the groundwater composition is largely controlled by the dissolution of carbonate rocks known in the basin. The isotopic contents of groundwaters ranged from −8‰ to −5.2‰ for δ¹⁸O, from −52‰ to −34‰ for δD, and from 0 to 5.5 TU for tritium. The hydrogen (δD) and oxygen (δ¹⁸O) isotope signatures reveal a significant infiltration before evaporation takes place, indicating a major recharge directly from fractures in the crystalline and limestone formations of Atlas Mountains (above 800 m a.s.l.) and infiltration of surface water in the alluvial cones at the border of the Atlas basins. The very low tritium values suggest that the groundwater recharge follows a long flow path and a mixing between old and modern water is shown. However, a slight evaporation effect is noted in the southern part of the basin close to the Anti-Atlas Mountains.     

滇黔桂微细浸染型金矿铅同位素组成及应用

滇黔桂微细浸染型金矿铅同位素组成及应用＊刘显凡刘家军朱赖民（中国科学院地球化学研究所，贵阳５５０００２）卢秋霞（成都理工学院，成都６１００５９）关键词微细浸染型金矿铅同位素组成矿质来源上地幔分异混染滇黔桂１矿床地质背景研究区位于扬子地台西南缘与华南加...     

地质学家重视研究深部（变质）CO_2对古气候的影响

地质学家重视研究深部（变质）ＣＯ２对古气候的影响贾跃明（中国地质矿产信息研究院，北京，１０００３７）近几年来，随着过去全球变化研究的兴起，地质学家越来越重视地质历史时期影响大气ＣＯ２浓度的因素的调查。不少人认为，变质作用和火山活动可能是过去大气中ＣＯ...     

塔中石炭系碎屑岩深埋藏优质储层成因探讨

塔中地区石炭系碎屑岩为一套次生－原生孔隙型深埋藏优质储层。储集岩为中细粒－细粒石英砂岩，储层形成于古地温梯度低、沉积物浅埋时间长、深埋时间短、孔隙水矿化度高及较早被油气占居的条件下，致使原生孔隙保存较好。同时，塔中地区石炭系目前刚进入８０℃－１２０℃的强溶成岩阶段，次生孔隙正在发育，距离碳酸盐岩沉淀带和后期石英次生加大带尚有较大深度，因而储层的孔渗性维持在最佳状态。     

华南下二叠统层状硅岩的形成及意义

华南地区下二叠统的层状硅岩分布较稳定，厚度一般为几十米，含有数量不等的放射虫和海绵骨针等，并据此可分为放射虫硅岩、海绵骨针硅岩和贫化石硅岩。化学成分特点和硅氧同位素值，具有生物化学成因硅岩的特征，与火山成因和热水成因的硅岩也有一定联系。层状硅岩的形成明显受断裂控制，硅质生物、上升洋流和水平洋流则是硅质富集、保存和沉淀的主要因素，而海底火山和热水活动的参与也起到一定促进。层状硅岩中有机碳含量丰富，平均０．６９％，是潜在的有利烃源岩。     

Predisposition to Induced Seismicity in Some Czech Coal Mines

—Mining-induced seismicity associated with longwall face operations in the Ostrava- Karviná coal mines, Czech Republic, has been investigated in order to establish the conditions leading to a focal zone generation. The study, based on macroseismic and instrumental observations, proved that seismicity is influenced by natural as well as mining conditions. The first group includes the influence of faults, washouts and red beds, while the second one is represented by shaft and/or crosscut safety pillars and various types of remnant pillars. All the cases discussed show that many focal zones are generated in overstressed strata as a consequence of interaction of natural conditions and/or old workings with the active coal face. Received June 18, 1996, accepted March 10, 1997     

华北南部地区——古生界构造演化及其油气远景

华北南部地区的地质演化与华北其他地区一样，经历了结晶基底形成，中一晚元古代台内裂谷发育、古生代稳定地台沉积和中一新生代活化等发展过程。但本区受秦岭褶皱带构造活动的强列影响。因而具有相对独特的构造演化特征和油气控制条件。早寒武世中期，古秦岭海槽伸展扩张，沉积了一套全区广泛分布的以碳酸盐岩为主夹泥页岩的地层；晚寒武世开始，古秦岭海槽向北俯冲挤压，在本区南部出现一个平行于海槽的大陆边缘隆起；中奥陶世发生     

未定名矿物(Bi38CrO60)的矿物学研究

人工合成立方晶体Bi38CrO60在自然界首次发现于中国陕西省洛南县驾鹿金矿床中,暂称之为未定名矿物.其共生和伴生矿物有黄铁矿、自然金、碲金矿、含氧金矿物等.常呈不规则粒状集合体,偶见立方体微晶(粒径小于0.05 mm),棕黑色,金属光泽;HV=232.78 kg/mm2 ,HM=4.15;D=14.10(3)g/cm3,Dx=14.08(2)g/cm3,n=3.14(3).EPM8100探针分析Bi2O3为98.854%、CrO3为1.111%,合计99.965%,化学式为Bi38.009Cr0.995O60;CAMEBAX-SX51探针分析Bi2O3为98.862%,CrO3为1.112%,合计99.974%,化学式为Bi38.008Cr0.996O60.均可写为Bi38CrO60.X射线粉晶分析主要强度线d(I)(hkl)分别为0.321 5(100),(310);0.272 11(72),(321);0.171 45(40),(530);0.169 6(30),(600);0.165 1(30),(611);0.160 8(30),(620);0.294 11(25),(222);0.359 6(22),(220);0.217 1(20),(332);0.150 3(20),(631),等轴晶系,可能的空间群为Im3m;a=1.018 1(1)nm,c/a=1,晶胞体积v=1.055 29(1)nm3,z=1.1-Kp/Kc=0.019.Cr6 ,Bi3 ,O2-.未定名矿物和人工晶体的化学成分与X射线粉晶数据基本一致.