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971.
A novel method has been examined for monitoring tropospheric hydroxyl radicals (OH), the most important oxidant in tropospheric chemistry. Aqueous phase salicylic acid reacts with atmospheric OH to produce 2,5-dihydroxy benzoic acid (2,5-DHBA) and other products. High Performance Liquid Chromatography (HPLC) is used to separate the post-reaction solution and the products are quantified using fluorescence detection. Unlike other methods, it has been reported to be inexpensive, portable and relatively simple. Although the sensitivity was sufficient to measure typical daytime OH concentrations of 0.04–0.4 ppt., the method was hindered by numerous interferences. Successive identification and elimination of these still resulted in a signal that was much larger than expected. Tests showed that this was not likely to be due to ozone, HO2, NOx, H2O2, aerosols, light or bacteria. Experimental and numerical studies suggest that the interference could be due to methyl peroxy radicals. The effect of many other components in the atmosphere, both individual and combined, must also be tested before the method can be used reliably in the field. The validity of previous reports of ambient hydroxyl measurements using this technique is therefore brought into question. 相似文献
972.
Z. X. Zhang T. Naarttij rvi 《Fragblast: International Journal for Blasting and Fragmentation》2005,9(2):61-78
Due to the large-scale sub-level caving in Malmberget mine and the short distance between the mine and Malmberget town, the ground vibrations in the town have reached a high level since the year 2001 when large scale caving mining started. In order to control and reduce the high vibrations, LKAB launched a research project on active reduction of vibrations in Malmberget by using the wave interference or wave superposition method with electronic detonators. By means of this method, the vertical vibrations were reduced by 10% and the total vibration time for a ring blast was reduced by 80% according to five ring tests in the mine. For a further reduction of the vibrations, a second method, named changing initiation sequence in ring blasts, was developed on the basis of stress wave theory and the geographic conditions of the town and the mine. The second method has so far been applied in all of the drifts near the town, and the vibrations measured at the town show that the vertical vibrations caused by production blasts in the mine have been reduced by more than 31% on average. In addition, a third method, dividing a ring into two parts during blasting, was developed and used to reduce the ground vibrations from a number of very large rings in the mine. The results indicate that the vibrations have been reduced by more than 33%, and a more interesting and surprising result is that ore extraction has been increased by the third method. 相似文献
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Measurements of the response of the ¼‐scale reinforced concrete Hualien (Taiwan) containment model obtained during forced vibration tests are used to identify some of the characteristics of the superstructure and the soil. In particular, attempts are made to determine the fixed‐base modal frequencies, modal damping ratios, modal masses and participation factors associated with translation and rocking of the base. The shell superstructure appears to be softer than could have been predicted on the basis of the given geometry and of test data for the properties of concrete. Estimates of the shear‐wave velocity and damping ratio in the top layer of soil are obtained by matching the observed and theoretical system frequency and peak amplitude of the response at the top of the structure. The resulting models for the superstructure and the soil lead to theoretical results for the displacement and rotations at the base and top of the structure which closely match the observed response. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
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高阶单步法控制MR智能隔震系统的试验研究 总被引:1,自引:0,他引:1
高阶单步法已成功地应用于结构非线性分析及考虑时滞的主动控制等,显示了它的稳定、精度高和计算迅速等特点。磁流变阻尼器是一种性能优良的智能阻尼器,它具有阻尼力可调范围宽、响应迅速且所需能量很少的特点。本文将磁流变(MR)阻尼器与普通橡胶隔震支座相结合,采用高阶单步算法和两种控制策略对结构进行振动控制。数值模拟分析与振动台试验结果表明:由MR阻尼器提供可调阻尼力的智能隔震控制系统能有效克服被动隔震最优控制频带窄的缺点,对较宽频域范围不同大小的地震激励均能提供最优控制。同时也表明该控制算法是一种能用于结构实际控制的变阻尼有效算法。 相似文献
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瞬态振动法瑞雷面波采集质量的探讨与分析 总被引:1,自引:5,他引:1
结合实例,对瞬态振动法瑞雷面波资料采集技术进行深入研究,分析了影响瞬态瑞雷面波勘探的各种因素以及应采取的数据采集技术,从而达到提高资料采集质量的目的。 相似文献
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建筑物抗震安全性评估专家系统 总被引:2,自引:0,他引:2
本文从振动测量角度识别建筑物的模态参数,利用模态参数结合抗震规范对现存莪抗震安全进行评估。用LIPS语言完成专家系统的实现,据此可进行多类建筑物的抗震安全性评估,最后用一个房屋结构的数值模拟例子说明评估过程。 相似文献