湖泊沉积物-水界面营养元素的生物地球化学作用和环境效应 Ⅰ.界面氮循环及其环境效应

发生在沉积物-水界面的剧烈生物地球化学作用对沉积物和上覆水体具重要的环境效应，然而此方面研究很少。本文通过云贵高原四个湖泊湖水和孔隙水NH和NO剖面，沉积物柱芯不同结合态氮含量剖面分布，界面扩散通量，影响氮循环的因素及它们季节性变化规律等的对比研究，初步揭示了湖泊沉积物一水界面的氮循环及其环境效应。     

Dissolved carbon in pore waters from the carbonate barrier reef of Tahiti (French Polynesia) and its basalt basement

This paper deals with dissolved inorganic carbon (DIC) and organic carbon (DOC) in pore waters from a 150 m deep hole drilled through the carbonate barrier reef of Tahiti and its underlying basalt basement. Alkalinity-pH measurements were used to calculate the DIC species concentration, and DOC was analysed according to the high temperature catalytic oxidation technique. Salinity was used as a conservative tracer to help identify water origin and mixing within the hole. Water mixing, calcium carbonate dissolution and mineralization of organic carbon combined to form three distinct groups of pore water. In the deeper basalt layers, pore water with alkalinity of 1.4 meq kg^–1 pH of 7.6 and p(CO₂) of 1.2 mAtm was undersaturated with respect to both aragonite and calcite. In the intermediate carbonate layer, pore water with alkalinity of more than 2.0 meq kg^–1, pH of 7.70 and p(CO₂) of 1.4 mAtm was supersaturated with respect to both aragonite and calcite. The transition zone between those two groups extended between 80 and 100 m depth. The shift from aragonite undersaturation to supersaturation was mainly attributed to the mixing of undersaturated pore waters from the basalt basement with supersaturated pore waters from the overlaying limestone. In the top of the reef, inputs from a brackish water lens further increased p(CO₂) up to 5.6 times the atmospheric P(CO₂).     

Comparison of Cu and Zn cycling in eutrophic lakes with oxic and anoxic hypolimnion

Data on the cycling of Cu and Zn in two eutrophic lakes are presented: Lake Greifen that becomes seasonally anoxic in its hypolimnion and Lake Sempach that is aerated during winter and oxygenated during summer. They suggest that hypolimnetic oxygenation 1) enhances the release of copper from the sediment but 2) also accelerates the entrapment and deposition of Cu and Zn by freshly formed Mn- and Fe-oxides.     

The role of moisture cycling in the weathering of a quartz chlorite schist in a tropical environment: findings of a laboratory simulation

Long‐term weathering of a quartz chlorite schist via wetting and drying was studied under a simulated tropical climate. Cubic rock samples (15 mm × 15 mm × 15 mm) were cut from larger rocks and subjected to time‐compressed climatic conditions simulating the tropical wet season climate at the Ranger Uranium Mine in the Northern Territory, Australia. Fragmentation, moisture content and moisture uptake rate were monitored over 5000 cycles of wetting and drying. To determine the impact of climatic variables, five climatic regimes were simulated, varying water application, temperature and drying. One of the climatic regimes reproduced observed temperature and moisture variability at the Ranger Uranium Mine, but over a compressed time scale. It is shown that wetting and drying is capable of weathering quartz chlorite schist with changes expected over a real time period of decades. While wetting and drying alone does produce changes to rock morphology, the incorporation of temperature variation further enhances weathering rates. Although little fragmentation occurred in experiments, significant changes to internal pore structure were observed, which could potentially enhance other weathering mechanisms. Moisture variability is shown to lead to higher weathering rates than are observed when samples are subjected only to leaching. Finally, experiments were conducted on two rock samples from the same source having only subtle differences in mineralogy. The samples exhibited quite different weathering rates leading to the conclusion that our knowledge of the role of rock type and composition in weathering is insufficient for the accurate determination of weathering rates. Copyright © 2005 John Wiley & Sons, Ltd.     

Influences of wastewater discharges on the water quality of Mamasın dam watershed in Aksaray, Central Anatolian part of Turkey

Sustaining the human ecological benefits of surface water requires carefully planned strategies for reducing the cumulative risks posed by diverse human activities. Municipal governments in Aksaray City play a key role in developing solutions to surface water management and protection problems. The responsibility to provide drinking water and sewage works, regulate the use of private land, and protect public health provides the mandate and authority to take action. A large part of Aksaray City uses Mamasın dam water as its primary source for drinking water. Several point sources of contamination may result from direct wastewater discharges from Melendiz and Karasu rivers, which recharge the Mamasın dam watershed. Relevant studies were carried out for monitoring the eutrophication process, which usually occurs in the static water mass of the Mamasın dam lake. This process may be caused by the continual increase in nutrients and decrease of O₂ levels, causing anaerobic conditions. Stimulated algae growth in these water bodies consequently reduces water quality. Hydrochemical parameters were evaluated to estimate the types of pollution sources, the level of pollution, and its environmental impacts on the Mamasın dam drinking water reservoir.     

二价铁氧化对铁锰循环功能微生物活性的影响及机制

地质微生物是沉积环境中铁、锰氧化还原循环的主要驱动因子,铁锰共存环境中二价铁氧化对不同铁、锰循环功能微生物活性的影响差异和机制尚不清楚.以铁还原菌Shewanella oneidensis MR-1、铁氧化菌Pseudogulbenkiania sp.strain 2002、锰氧化菌Pseudomonas putida MnB1和Leptothrix discophora SS-1作为代表性的铁、锰循环功能微生物,利用平板计数、荧光显微镜等手段探究了Fe(II)氧化对功能微生物活性的影响差异及机制.结果表明0.05 mM Fe2+氧化60 min可使MR-1和MnB1的活菌数量降低4~5个数量级,SS-1及S.2002无显著失活.Fe(II)氧化产生的吸附态。OH和胞内。OH是细菌失活的主要原因,胞外H₂O₂、胞外游离态。OH和三价铁氧化物是细菌失活的次要原因,SS-1及S.2002产生了氧化应激反应,成功抵御了活性氧化物种.      

地幔不均一性与地幔循环的多维表征和原因思考

地幔早先经核- 幔- 壳分异形成,后受不同尺度对流和循环的影响,因而具有不均一性特征。近三十年来,地幔化学通过研究大洋玄武岩发现了多样地幔端元和非放射性同位素证据并证明了地幔不均一性,逐渐建全了地幔地球化学体系。然而,地幔不均一性如何对应于时空尺度的地幔循环,以及地球演化如何影响地幔不均一性等,仍不清楚。此外,地球物理研究显示,岩石圈厚度差异、中下地幔的波速异常体以及俯冲板片形态的观测为纵横向对流系统提供了空间不均一性证据支持。联合地球化学和地球物理手段对研究地幔不均一性至关重要,用好透视地幔成分与结构的“双目镜”已成为共识。本文从地幔不均一性结合地球化学场、地球物理的不同表现形式,以及现今及历史时期的洋陆格局的对比,多维度联系地幔循环和演化,思考了超大陆旋回与地幔不均一化的内在逻辑。强调了从全球演化角度看地幔不均一性的重要性和提出多手段联合建立地幔循环驱动模型的展望。     

泉州湾赤潮藻类优势种演替影响因子探讨

于2006年5—11月对东海泉州湾赤潮监控区设定4个采样站位,进行赤潮常规监测。结果表明,泉州湾藻类优势种由中肋骨条藻(Skeletonema costatum)、太平洋海链藻(Thalassiosira pacifica)、微小原甲藻(Prorocentrum minimum)、尖刺拟菱形藻(Pseudo-nitzschia pungens)、丹麦细柱藻(Leptocylindrus danicus)及旋链角毛藻(Chaetoceros curvisetus)等赤潮生物组成,虽然中肋骨条藻为最主要的优势种,但有3个站位出现了上述优势种的演替。通过深入分析该海域水质营养盐含量及组成结构的动态变化对赤潮藻类优势种演替的影响,发现由于不同的赤潮藻类种群具有各自的生态习性及适应环境的生长增殖策略,海域水质营养盐含量和组成结构的变化,会引起赤潮藻类种群增殖竞争力间强弱的相对变化,而种群增殖竞争力强的种类有可能迅速增殖取代原有的优势种而演替为新的优势种,这是一个动态的过程。     

Global distribution of summer chlorophyll blooms in the oligotrophic gyres

Chlorophyll blooms consistently develop in the oligotrophic NE Pacific in late summer, isolated from land masses and sources of higher chlorophyll waters. These blooms are potentially driven by nitrogen fixation, or by vertically migrating phytoplankton, and a better understanding of their ubiquity could improve our estimate of the global nitrogen fixation rate. Here, global SeaWiFS chlorophyll data from 1997 to 2007 are examined to determine if similar blooms occur in other oligotrophic gyres. Our analysis revealed blooms in five other areas. Two of these are regions where blooms have been previously identified: the SW Pacific and off the southern tip of Madagascar. Previously, unnoticed summer blooms were also identified in the NE and SW Atlantic and in a band along 10°S in the Indian Ocean. There is considerable variation in the intensity and frequency of blooms in the different regions, occurring the least frequently in the Atlantic Ocean. The blooms that develop along 10°S in the Indian Ocean are unique in that they are clearly associated with a hydrographic feature, the 10°S thermocline ridge, which explains the bloom within a conventional upwelling scenario. The environment and timing of the blooms, developing in oligotrophic waters in late summer, are conducive to both nitrogen fixers and vertically migrating phytoplankton, which require a relatively stable water column. However, the specific locations of the chlorophyll blooms generally do not coincide with areas of maximum levels of nitrogen fixation or Trichodesmium. The NE Pacific chlorophyll blooms develop in a region with a very high SiO₄/NO₃ ratio, where silicate will not be a limiting nutrient for diatoms. The blooms often develop between eddies, wrapping around the periphery of anti-cyclonic features. However, none of the areas where the blooms develop have particularly high eddy kinetic energy, from either a basin-scale or a mesoscale perspective, suggesting that other factors, such as interactions with a front or dynamics associated with the critical latitude, operate in conjunction with the eddy field to produce the observed blooms.     

山东近岸海湾微型浮游植物分布及其丰度与营养盐相关性研究

2006年7月至2007年10月对山东近岸的威海湾、荣成湾、桑沟湾、靖海湾、五垒岛湾及乳山湾(37°28.7'-36°46.3'N,121°28.8'-122°39.6'E)的26个站位按季节进行了4个航次的现场调查,分析了6个海湾不同季节的微型藻类及营养盐情况,并进一步对几种主要微藻类群与各种营养盐之间的相关性进行了研究.结果表明,各海湾微型浮游植物的平均丰度在456.3×104-2332.2×104cell/L之间;夏季和春季的主要优势种为硅藻:冬季主要优势种为黄藻;秋季主要优势种为隐藻.不同微藻类群与不同营养盐的相关性差异显著,其中,与NH4-N的相关性依次为:绿藻＞黄藻＞隐藻＞甲藻＞硅藻＞金藻,相关系数依次分别为0.965、0.929、0.761、0.748、0.671和-0.304;与NO3-N的相关系数的绝对值为金藻＞隐藻＞甲藻＞硅藻＞黄藻＞绿藻;与PO4-P的相关系数的绝对值则为甲藻＞金藻＞绿藻＞黄藻＞隐藻＞硅藻.