长白山天池火山的岩石矿物学特征——对结晶分异过程和岩浆混合作用的启示

本文对天池火山玄武岩盾,粗面质-碱流质层状锥体以及顶部的粗面质-碱流质碎屑岩类及熔岩的岩石矿物成分做了系统分析,发现在玄武岩类中的主要矿物组合为斜长石、富钙辉石以及富镁橄榄石,而粗面岩-碱流岩类的主要矿物组合为碱性长石、富铁的辉石及橄榄石,并开始出现石英、独居石以及大量的铁钛氧化物,符合结晶分异的演化趋势。同时在玄武岩类及粗面-碱流岩类中均存在不平衡矿物,再结合矿物环带的成分变化、矿物的熔蚀现象及不同特征的岩石条带等,认为天池火山在黑石沟玄武岩、第一、三造锥阶段粗面岩以及千年大喷发的浮岩中均存在岩浆混合作用。根据岩石学及年代学等特征,认为不同时期的玄武质岩浆来自同一地幔源区,经不同程度的结晶分异作用形成,前造锥阶段及造锥阶段的岩石由不同阶段的玄武岩演化而来,全新世的碱流岩类则由造锥阶段粗面岩类演化而来。     

热硫化条件下温度对黄铁矿结晶生长的影响

模拟天然黄铁矿形成条件和基本过程,利用真空管式炉实验设备,通过热硫化法在250～410℃反应,实验考察不同温度条件下黄铁矿的结晶生长情况。运用扫描电镜、X射线粉晶衍射分析等手段,对实验产物形貌、物相结构特点等进行测试分析。结果表明：250～410℃时均可形成黄铁矿,但250～280℃时黄铁矿结晶程度较差;310～340℃时,可生长出部分晶面;360℃时黄铁矿生长成较为完好的晶体;380℃时黄铁矿结晶成立方体、八面体等自形晶;410℃时可形成结晶好、成分单一的黄铁矿。     

动态高压下陨石矿物的冲击熔融和分离结晶及其地球化学意义

应用近代微束矿物学分析测试技术,对在中国陨落的随州、寺巷口和岩庄等三块球粒陨石中矿物的冲击熔融和分离结晶作用进行了较系统的研究。查明存在有硅酸盐单矿物熔体、硅酸盐矿物混合熔体和全岩熔体三种组成不同的冲击熔体。研究结果显示:(1)三种熔融相与未熔相之间在主成分和微量元素组成上没有明显差别,说明它们是原地熔融的产物,但在较大的冲击熔块中,也发现冲击熔融作用引发了一部分元素,如亲铁元素、硒元素和轻重稀土元素的分异现象;(2)查明Al2O3、Cr2O3、Na2O和CaO等优先进入从冲击熔体结晶的辉石常压相或辉石的高压相——镁铁榴石(属地幔过渡带矿物)中;(3)Al元素能进入阿基莫石(即辉石的钛铁矿结构相,属下地幔矿物)中,以固熔体形式稳定下来。ELNES的测定查明,其氧化铁组分中Fe3+/∑Fe的比值高达0.67(3);(4)陨石全岩熔体中硅酸盐相与金属-硫化物相之间为完全不混熔,后者以孤立的共结体团块产于硅酸盐熔体之中,除Zn、Na、Cr、Co和Cu在硫化物相中和Na在金属相中有明显富集外,其他元素的浓度则无明显变化;(5)在寺巷口陨石熔脉的金属-硫化物共结团块内发现了FeNi金属-硫化铁-磁铁矿组合,进一步证实了S和O等轻元素可以加入到以Fe-Ni金属为主要组成的地核成分中去;(6)在岩庄陨石的FeNi金属-硫化铁共结体团块的硫化铁内发现了Na、Mn和Fe的磷酸盐矿物小球体,说明P和Na、Mn等元素也能成为地核的组成元素。以上研究在行星演化、地幔矿物学和地球化学,以及陨石学研究上均有着重要的科学意义。     

碳酸盐型盐湖卤水的模拟太阳池结晶试验

在碳酸盐型盐湖提锂工艺中, 太阳池是一个重要组成部分, 目的是储存太阳能能量以结晶析出碳酸锂。文章利用加热方法首次在实验室条件下进行模拟太阳池结晶试验, 试验的蒸发量随着温度的升高而加大, 但蒸发量的不同对析盐结晶影响不大。在不同时间段模拟试验中, 24 h时间段的Mg2+析盐浓度较Li+大, 且随着时间的延长逐渐降低, 而Li+则相反;Mg2+析出速率随着时间的增加而逐渐降低, 而Li+析出速率基 本保持一致。在不同温度模拟试验中, 卤水主要组分总析出率与温度的升高呈正相关, 卤水中CO32?和Li+的浓度降低速度大于其他组分, CO32?和Li+的析出率远大于其他组分, 析出主要矿物鉴定结果均为扎布耶石     

Permian High Ba-Sr Granitoids: Geochemistry, Age and Tectonic Implications of Erlangshan Pluton, Urad Zhongqi, Inner Mongolia

Abstract: Erlangshan Pluton from Urad Zhongqi, central Inner Mongolia, is located in the middle segment of the northern margin of the North China Plate. The rocks consist mainly of diorites with gneissic structure. Petrochemical characteristics reveal that the diorites belong to metaluminous, high-potassium calc-alkaline series, with chemical signatures of I-type granites. They are characterized by low SiO2 contents (56.63%–58.53%) and A/CNK (0.90–0.96), high Al2O3 contents (17.30%–17.96%) and Na2O/K2O ratios (1.20–1.70), enrichment in large ion lithophile elements (LILE, e.g., Ba=556–915 ppm, Sr=463–595 ppm), and relative depletion in high field strength elements (HFSE, e.g., Nb, Ta, Ti) in primitive mantle-normalized spidergram, and right-declined rare earth element patterns with slightly negative Eu anomalies (d?Eu=0.72–0.90). They have Sr/Y ratios (20–25) evidently less than Kebu Pluton (49–75) to its east. Sensitive high resolution ion micro-probe U-Pb zircon dating of the diorites has yielded an intrusive age of 270±8?Ma. This leads us to conclude that Erlangshan diorites were formed by mixing between the middle or lower crustal-derived magma and minor mantle-derived mafic magma, followed by fractional crystallization, which was trigged by crustal extension and fault activity in post-collisional setting.     

青藏高原东缘休瓦促钨钼矿区复式岩体时空分布及演化意义

休瓦促钨钼矿区位于义敦地体南段,是该区域唯一存在晚三叠世、晚白垩世和新生代酸性侵入体直接接触形成复式岩体的矿区.目前尚未对该复式岩体的岩浆演化过程开展过系统深入研究,限制了对该矿区及区域构造事件和岩浆演化的认识.本文通过系统梳理前人研究成果,开展东矿段黑云母花岗岩,西矿段二长花岗岩、花岗斑岩地质年代学和地球化学分析,探...     

西藏驱龙斑岩铜矿床岩浆演化过程中的Cu同位素分馏

随着同位素测试技术的发展,高温下重同位素分馏逐渐运用到地球化学领域.为了探索岩浆演化过程中是否会发生Cu同位素分馏,文章对西藏驱龙斑岩铜矿床同来源、不同演化阶段的两套岩浆岩(闪长岩包体和花岗闪长岩)进行了Cu同位素测试.测试结果显示,闪长岩包体的δ65Cu值集中在+0.08‰-+0.35‰之间,平均值为+0.25‰,花岗闪长岩的δ65Cu值为+0.42‰～+0.87‰,平均值为+0.60‰.△65Cu花岗闪长岩-闪长岩包体≈+0.4‰,并且δ65Cu值与样品w(SiO)变化存在一定的正相关性.结合地质学及同位素方面考虑,花岗闪长岩和闪长岩包体的Cu同位素组成差异可能是岩浆演化过程中发生了Cu同位素分馏所致.在驱龙矿区中新世岩浆演化过程中,随着岩浆去气作用,63Cu随HS-、Cl-等挥发分优先进入气相,导致残留岩浆熔体相对富集65Cu.此外,两者的Cu同位素组成差异也可能与岩浆演化过程中斜长石、角闪石、黑云母等矿物的不断结晶分离有关,矿物结晶分离时,基性矿物富集63Cu,而残余熔体则富集65Cu.     

安徽铜陵地区中生代侵入岩成因及成矿意义

安徽铜陵矿集区是我国最著名的铜、金、铁产地之一,成矿与岩浆作用关系密切.本次对铜陵地区中生代侵入岩进行了系统的矿物学、岩石学和元素地球化学研究.结果表明:①本区岩浆岩主要为辉石(二长)闪长岩( SiO2≤55％)、石英(二长)闪长岩(SiO255％～65％)和花岗闪长岩(SiO2≥65％)三种岩石组合,其矿物成分主要为...     

Geochronologic-petrochemical studies of the Hongshishan mafic–ultramafic intrusion,Beishan area,Xinjiang (NW China): petrogenesis and tectonic implications

The Hongshishan mafic–ultramafic intrusion (SIMS zircon U–Pb age 286.4 ± 2.8 Ma) consists of dunite, clinopyroxene peridotite, troctolite, and gabbro. Major elements display systematic correlations. Trace elements have identical distribution patterns, including flat rare-earth element (REE) patterns with positive Eu anomalies and enrichments in large ion lithophile elements (LILE) but depletions in Nb and Ta, indicating fractional crystallization as a key factor in magmatic evolution. Petrologic and geochemical variations in drill core samples demonstrate that minor assimilation and progressive magma injections were closely associated with Ni–Cu mineralization. Mass balance estimates and Sr–Nd isotopes reveal that the Hongshishan parental magmas were high-Mg and low-Ti tholeiitic basalts and were derived from a lithospheric mantle source that had been modified by subducted slab metasomatism before partial melting.

Southward subduction of the Palaeo-Tianshan–Junggar Ocean is further constrained by a compilation of inferred, subduction-induced modifications of mantle sources in mafic–ultramafic intrusions distributed in the eastern Tianshan–Beishan area. Integrating the regional positive ?_Nd(t) granites, high-Mg and low-Ti basaltic magmas (mafic–ultramafic intrusions), and slightly later high-Ti basalts in NW China suggests that their petrogenesis could be attributed to Permian mantle plume activities.     

Petrogenetic modeling of rock variety in the Khalkhab–Neshveh pluton,NW of Saveh,Iran

The Khalkhab–Neshveh (KN) pluton is a part of Urumieh–Dokhtar Magmatic Arc and was intruded into a covering of basalt and andesite of Eocene to early Miocene age. It is a medium to high‐K, metaluminous and I‐type pluton ranging in composition from quartz monzogabbro, through quartz monzodiorite, granodiorite, and granite. The KN rocks show subtle differentiation trends strongly controlled by clinopyroxene, plagioclase, hornblende, apatite, and titanite, where most major elements (except K₂O) are negatively correlated with SiO₂; and Al₂O₃, Na₂O, Sr, Eu, and Y define curvilinear trends. Considering three processes of magmatic differentiation including mixing and/or mingling between basaltic and dacitic magmas, gravitational fractional crystallization and in situ crystallization revealed that the latter is the most likely process for the evolution of KN magma. This is supported by the occurrence of all rock types at the same level, the lack of mafic enclaves in the granitoid rocks, the curvilinear trends of Na₂O, Sr, and Eu, and the constant ratios of (⁸⁷Sr/⁸⁶Sr)_i from quartz monzodiorite to granite (0.70475 and 0.70471, respectively). In situ crystallization took place via accumulation of plagioclase and clinopyroxene phenocrysts and concentration of these phases in the quartz monzogabbro and quartz monzodiorite at the margins of the intrusion at T ≥ 1050°C, and by filter pressing and fractionation of hornblende, plagioclase, and later biotite in the granitoids at T = ～880°C.