南黄海沉积物中活性铁氧化物对有机碳的保存作用

土壤和沉积物中活性铁对有机质的吸附对有机质具有长期稳定和保存作用,从而在地质时间尺度上缓冲大气CO₂浓度。本文利用连二亚硫酸钠还原性溶解提取活性铁氧化物（FeR）及与之结合的有机碳（Fe-OC）,定量研究了南黄海沉积物中FeR与OC之间的结合方式以及FeR对OC的保存作用,讨论了深度增加对二者相互作用的影响。结果表明,南黄海沉积物中Fe-OC占沉积物总有机碳的份数（f_Fe-OC）为（13.2±7.47）%,即活性铁对OC的年吸附量为0.72 Mt,占全球边缘海沉积物TOC年埋藏通量的0.44%。Fe-OC的平均OC:Fe为4.50±2.61,表明共沉淀作用对有机质的保存起重要作用,且其比值随海源有机质含量增加而增加。Fe-OC稳定碳同位素（δ13C_Fe-OC）结果表明,FeR优先保存活性有机质,但这种选择性随OC:Fe增大而减弱。随深度增加,f_Fe-OC和δ13C_Fe-OC均未表现出显著变化,这与该海域沉积物中有机质活性较低、铁还原作用较弱有关。     

Two New Hydrothermal Fields at the Mid-Atlantic Ridge

Two new major hydrothermal fields have been discovered in the rift valley of the MAR at 13°N (Ashadze) and l6°38′N (Krasnov). The Ashadze field consists of a cluster of active hydrothermal sites associated with ultramafic rocks and located at the greatest depth in the ocean (4,200 m). By contrast, the Krasnov field consists of inactive sulfide mounds hosted in basalts. The Krasnov is the largest hydrothermal deposit on the MAR (17.4 Mt) so far discovered with iron sulfide as the principal mineral type. By contrast, Cu-Zn sulfides are the major minerals in the Ashadze deposits, which are also enriched in gold and several other metals.     

Rare earth elements and yttrium in ferromanganese deposits from the South China Sea: distribution, composition and resource considerations

Ferromanganese nodules and crusts contain relatively high concentration of rare earth elements(REE) and yttrium(REY),with a growing interest in exploitation as an alternative to land-based REY resources.On the basis of comprehensive geochemical approach,the abundance and distribution of REY in the ferromanganese nodules from the South China Sea are analyzed.The results indicate that the REY contents in ferromanganese deposits show a clear geographic regularity.Total REY contents range from 69.1×10~(–6) to 2 919.4×10~(–6),with an average value of 1 459.5×10~(–6).Especially,the enrichment rate of Ce content is high,accounting for almost 60% of the total REY.This REE enrichment is controlled mainly by the sorption of ferromanganese oxides and clay minerals in the nodules and crusts.Moreover,the total REY are higher in ferromanganese deposits of hydrogenous origin than of diagenetic origin.Finally,Light REE(LREE) and heavy REE(HREE) oxides of the ferromanganese deposits in the study area can be classified into four grades: non-enriched type,weakly enriched type,enriched type,and extremely enriched type.According to the classification criteria of rare earth resources,the Xisha and Zhongsha platform-central deep basin areas show a great potential for these rare earth metals.     

Comparison of Strain-rate Dependent Stress-Strain Behavior from Ko-consolidated Compression and Extension Tests on Natural Hong Kong Marine Deposits

This article presents results from a series of K_o-consolidated compression and extension triaxial tests on specimens from undisturbed samples of Hong Kong Marine Deposits (HKMD). To investigate the strain-rate effects, a total of seven K_o-consolidated triaxial tests were conducted including four compression tests and three extension tests. After K_o-consolidation, the triaxial test specimens were sheared at step-changed axial strain rates under three different confining pressures of 50 kPa, 150 kPa, and 400 kPa, respectively. The step-changed strain rates were applied in the following order: +2%/h, +0.2%/h, +20%/h, -2%/h (unloading) and +2%/h (reloading) for the four compression tests and -2%/h, -0.2%/h, -20%/h, +2%/h (unloading) and -2%/h (reloading) for the three extension tests. The results are reported and analyzed in the paper. The results show that the strain rate effects, the stress-strain characteristics, and the effective stress paths of the specimens for tests in a compression state are different from those for tests in an extension stage. One order of magnitude increase in axial strain rate causes an average 8.6% increase in undrained shear strength for compression tests and a 12.1% increase for extension tests. It is also found that the failure mode of the specimens in compression is different from that in extension. The stress-strain behavior of specimens shows strain-softening and a clear shear band in compression tests, but strain-hardening without any clear shear band in extension tests for the same absolute value of axial strain.     

曹妃甸浅滩表层砂体插桩深度研究

曾妃甸浅滩原为古滦河三角洲,三角洲废弃后,海底表层沉积物在波浪潮流的簸选及自重应力作用下,沉积物颗粒粗化,粒度单一,且堆积紧密,工程强度较高。平台在该海医插桩时往往难以贯穿该层,其实际插桩深度较预定深度存在较大偏差。本文对此类砂体的形成机制、插桩过程中土体的压实作用对砂体强度的影响进行了分析,在对砂体力学参数做出适当调整后,运用太沙基地基极限荷载公式进行计算,得到了与实际情况较为一致的结果。     

海南岛东南部潟湖台风事件沉积记录

研究海岸潟湖沉积记录可恢复器测记录之前和史前时期热带气旋活动的频率和强度信息。本文试图通过分析潟湖沉积揭示南海北部地区的古台风活动信息,以海南岛东南部两个潟湖的钻孔沉积物为研究对象,选取沉积物粒度、有机质和碳酸盐含量等参数建立台风事件的鉴别指标,同时借助²¹⁰Pb CRS计年模式确定了沉积物柱状样的沉积速率和年代序列,对海南岛东南部的古风暴活动进行了分析。结果显示,柱状岩心清晰地记录了海南省东南部过去350年期间的35次特大风暴潮事件。基于历史文献和沉积记录的风暴沉积事件恢复了近350年来的风暴活动历史,发现海南省东南部特大风暴事件频数与厄尔尼诺强度有显著关系,同时还可能受到太平洋涛动（PDO）、北大西洋涛动（NAO）和太阳黑子活动等多种气候因素的综合影响。本文研究表明,结合风暴沉积记录和历史文献资料可为恢复海岸带地区长时间尺度高分辨率的古风暴活动规律提供有效信息。     

The influence of increased iron concentration on survival and growth of seedlings and young plants of eelgrass Zostera marina

Iron (Fe) is an essential nutrient for plants but toxic at high concentrations. We subjected seedlings and young plants of eelgrass Zostera marina to different seawater iron concentrations (500, 600, 700, 800, 1,000 and 1,500 μg/L) for 30 days under controlled laboratory conditions. Natural seawater without added iron (500 μg/L) was used as reference seawater. No sediments were provided to avoid iron scavenging by particle surfaces in the sediment. We measured plant response in terms of survivorship, morphology, growth rate and productivity. Survival analysis combined with morphological, dynamic and productive assessment suggested that the optimum seawater iron concentration for the establishment of Z. marina seedlings and young plants is 700 μg/L. The no observed effect concentration, lowest observed effect concentration, lethal concentration that caused an increase in mortality to 10% of that of the control, and the effect concentration that caused a decrease in growth to 10% of that of the control values of young plants were significantly lower than those of seedlings, implying an increased sensitivity to high Fe concentrations (>1,000 μg/L). This study further develops our understanding of the physiological ecology of the early life stages of Z. marina and provides data that could prove helpful in the development of successful eelgrass restoration and conservation.     

海洋沉积地质过程模拟:性质与问题及前景

探讨了海洋沉积地质数值模拟的功能问题.地球科学研究以正演方法(以数值模拟为代表)和反演方法(以地层记录分析为代表)的结合为特征.数值模拟作为一种重要的研究工具,具有获得过程和机理分析结果、形成工作假说、指导现场观测和采样的作用.与此同时,在正反演交融中模型本身也得到了提高和完善.在海洋沉积地质领域,数值模拟在沉积物输运...     

A mineral equilibria study of the hydrothermal alteration in mafic greenschist facies rocks at Kalgoorlie, Western Australia

The influx of a H₂O–CO₂‐dominated fluid into actinolite‐bearing metabasic rocks during greenschist facies metamorphism in the Kalgoorlie area of Western Australia resulted in a zoned alteration halo around inferred fluid conduits that contain gold mineralisation. The alteration halo is divided into two outer zones, the chlorite zone and the carbonate zone, and an inner pyrite zone adjacent to the inferred fluid conduits. Reaction between the fluid and the protolith resulted in the breakdown of actinolite and the development of chlorite, dolomite, calcite and siderite. In addition, rocks in the pyrite zone developed muscovite‐bearing assemblages as a consequence of the introduction of potassium by the fluid. Mineral equilibria calculations undertaken using the computer software thermocalc in the model system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–CO₂ show that mineral assemblages in the outer zones of the alteration halo are consistent with equilibrium of the protoliths with a fluid of composition X_CO2 = CO₂/(CO₂ + H₂O) = 0.1–0.25 for temperatures of 315–320 °C. The inner zone of the alteration halo reflect equilibrium with a fluid of composition X_CO2≈ 0.25. Fluid‐rock buffering calculations show that the alteration halo is consistent with interaction with a single fluid composition and that the zoned structure of the halo reflects the volume of this fluid with which the rocks reacted. This fluid is likely to have also been the one responsible for the gold mineralisation at Kalgoorlie.     

西菲律宾海沉积物铁族元素地球化学

本文对取自西菲律宾海区的三个柱状沉积物岩芯的铁族元素地球化学行为进行了系统的研究。从元素的含量及剖面变化、元素的相关性及组合特征,铁族元素与主元素的关系以及元素的赋存状态等方面探讨了物质来源、沉积作用和古气候,并据此进行了地层划分。沉积物有4种来源:海底火山源、生物源、自生源和陆源。海底火山物质提供了较多的铁族元素,相形之下,自生沉积作用较弱。元素地层学研究表明,在全新世温暖期和晚更新世寒冷期铁族元素表现出不同的地球化学行为,尤以Mn和亲生物(Ca)元素对气候的反映灵敏。WP_2孔和WP_(40)孔铁族元素特征相似,与WP_1孔差别较大。