Microbial Degradation of Tar Oil Compounds under Different Redox Conditions

The microbial transformation of typical tar oil compounds such as acridine, benzo(b)thiophene, dibenzofuran, indane, and indene under different redox conditions was investigated in microcosm studies. Under aerobic conditions the inherent contamination in polluted soil as well as the added N‐, S‐, O‐ heterocyclic and homocyclic compounds were transformed predominantly apart from thiophene. 1‐Indanone was detected by RP‐HPLC‐DAD and GC‐MS as an intermediate metabolite from indane and indene. Under nitrate and sulfate reducing conditions indane, benzo(b)thiophene, and dibenzofuran were transformed in assays with the polluted soil samples from well B 65 and B 66 within 426 days, whereas they were persistent in assays with the highly polluted soil B 67. All heterocyclic and homocyclic compounds added to the non‐contaminated soil from well B 85 were not degraded under nitrate and sulfate reducing conditions, too. The results indicate that for the decision, wether natural attenuation can be implemented in the remediation of contaminated site, in addition to BTEX and PAHs especially the fate of further tar oil compounds in anoxic aquifers has to be considered.     

Optimization of the Sampling Technique for the Determination of Dissolved Hydrogen in Groundwater

In this study a field‐sampling technique for dissolved hydrogen (H₂) in groundwater will be presented which allows the transport of gaseous samples into the laboratory for further analysis. The method consists of transferring the headspace trapped in a gas‐sampling bulb which is continuously purged by groundwater into previously evacuated vials using a gas‐tight syringe. Three transfer steps with preceding evacuation of the vial led to a H₂‐recovery of 100 % in laboratory experiments. The method has been applied to determine H₂ concentrations in an aquifer contaminated with chlorinated solvents. Tests concerning the effect of different pumping techniques on H₂ concentrations revealed that most reliable values were obtained with a bladder pump, while an electrically driven submersible pump generated considerable amounts of hydrogen due to electrochemical interactions with the sampled water. Concentrations of dissolved hydrogen in field and laboratory samples were about two orders of magnitude higher when sampling was performed with the electrically driven submersible pump compared to sampling with the bladder pump and a peristaltic pump. Lab experiments with a Plexiglas reservoir to produce H₂‐enriched water were used to study the effect of two tubing materials (PVC, polyamide) on H₂ losses. PVC tubing turned out to allow transfer of H₂‐enriched water over 25 m without significant losses, while PA‐tubing was not suitable for sampling of H₂.     

新技术在北极星天文方位角测量中的应用

使用GPS接收机的UTC作为北极星天文方位角测量的时间比对的标准时间，利用推估UTl与UTC的差值，将时间归算到UTl的方法，可满足各等级天文方位角测量的要求，现场计算零点恒星时和北极星坐标的精度满足北极星天文方位角测量的要求，实现了现场评估测量精度。     

自适应GM(1,1)模型进行地表沉降预报

提出采用自适应GM( 1 ,1 )模型进行地表沉降预报 ,并用于兖州某矿形变控制点的沉降预报 ,效果令人满意。说明此模型具有实用价值。     

Determination of silica sand stiffness

Site investigation and evaluation of properties of soil or rock are important aspects of geotechnical design. Determination of the ground stiffness is one of the important parameters in geotechnical engineering. Since the measurement of shear modulus is very sensitive to soil disturbance, especially for sand, determination of the stiffness of soil in the field is more reliable than in laboratory tests on sampled specimens. Measurement of shear modulus is one of the most common applications of self-boring pressuremeter testing. As an in situ device, the pressuremeter provides a unique method for assessing directly the in situ shear modulus of a soil. This paper describes a laboratory study of silica sand stiffness, which varies with stress level and strain amplitude. The results show that the elastic shear modulus value is mainly dependent on the value of the mean effective stress and relative density.     

An experimental investigation of LNAPL migration in an unsaturated/saturated sand

Accidental spills of hydrocarbons, such as Light Non-Aqueous Phase Liquids (LNAPLs), are one of the most common sources of subsurface contamination. Migration of LNAPL in a porous medium is influenced by various factors such as the number of fluids present in the unsaturated/saturated zones and the proportion of pores occupied by each fluid. The results for relationship between matric suction and degree of saturation are presented in this paper for water–air, water–LNAPL and LNAPL–air systems in a sand. A simple and reliable setup using Buchner funnel was designed to obtain these relations. It was found that the relationship between matric suction head and degree of saturation is hysteretic for all the fluid systems (water–air, water–LNAPL and LNAPL–air). Furthermore, the amount of hysteresis depended upon the fluid system, with the maximum hysteresis occurring for water–air system. The results suggest that the amount of trapped air depends upon the reversal degree of saturation from drying to wetting.     

Wave-influenced deltas: geomorphological implications for facies reconstruction

ABSTRACT A process‐based facies model for asymmetric wave‐influenced deltas predicts significant river‐borne muds with potentially lower quality reservoir facies in prodelta and downdrift areas, and better quality sand in updrift areas. Many ancient barrier‐lagoon systems and ‘offshore bars’ may be better reinterpreted as components of large‐scale asymmetric wave‐influenced deltaic systems. The proposed model is based on a re‐evaluation of several modern examples. An asymmetry index A is defined as the ratio between the net longshore transport rate at the mouth (in m³ year^?1) and river discharge (in 10⁶ m³ month^?1). Symmetry is favoured in deltas with an index below ≈ 200 (e.g. Tiber, lobes of the Godavari delta, Rosetta lobe of the Nile, Ebro), whereas deltas with a higher index are asymmetric (e.g. Danube – Sf. Gheorghe lobe, Brazos, Damietta lobe of the Nile). Periodic deflection of the river mouth for significant distances in the downdrift direction occurs in extreme cases of littoral drift dominance (e.g. Mahanadi), resulting in a series of randomly distributed, quasi‐parallel series of sand spits and channel fills. Asymmetric deltas show variable proportions of river‐, wave‐ and tide‐dominated facies both among and within their lobes. Bayhead deltas, lagoons and barrier islands form naturally in prograding asymmetric deltas and are not necessarily associated with transgressive systems. This complexity underlines the necessity of interpreting ancient depositional systems in a larger palaeogeographic context.     

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).     

青藏高原1∶25万区域地质调查地貌年代学研究

高原隆升及剥蚀作用的复杂性与区域差异性以及高原恶劣的气候、地理条件,使得在青藏高原空白区1∶25万区域地质调查中进行地貌年代学研究具有很大的现实意义.由于地貌是高原隆升、环境演化、新构造运动等的信息载体,地貌年代有助于重塑这些地质作用的发生时间及发展过程,因此地貌年代学研究具有重要的技术意义.1∶25万银石山幅的工作表明,地貌年代学调查对高原隆升及环境演化过程研究具有良好效果.     

Diagenetic history and porosity evolution of Upper Carboniferous sandstones from the Spring Valley #1 well, Maritimes Basin, Canada–implications for reservoir development

Eighty-two core samples were collected from the Spring Valley #1 well which penetrates the Upper Carboniferous strata in the Late Devonian–Early Permian Maritimes Basin. The strata consist of alternating sandstones and mudstones deposited in a continental environment. The objective of this study is to characterize the relationship of sandstone porosity with depth, and to investigate the diagenetic processes related to the porosity evolution. Porosity values estimated from point counting range from 0% to 27.8%, but are mostly between 5% and 20%. Except samples that are significantly cemented by calcite, porosity values clearly decrease with depth. Two phases of calcite cement were distinguished based on Cathodoluminescence, with the early phase being largely dissolved and preserved as minor relicts in the later phase. Feldspar dissolution was extensive and contributed significantly to the development of secondary porosity. Quartz cementation was widespread and increased with depth. Fluid inclusions recorded in calcite and quartz cements indicate that interstitial fluids in the upper part of the stratigraphic column were dominated by waters with salinity lower than that of seawater, the middle part was first dominated by low-salinity waters, then invaded by brines, and the lower part was dominated by brines. Homogenization temperatures of fluid inclusions generally increase with depth and suggest a paleogeothermal gradient of 25 °C/km, which is broadly consistent with that indicated by vitrinite reflectance data. An erosion of 1.1–2.4 (mean 1.75) km of strata is inferred to have taken place above the stratigraphic column. δ¹⁸O values of calcite cements (mainly from the late phase) decrease with depth, implying increasing temperatures of formation, as also suggested by fluid-inclusion data. δ¹³C values of calcite cements range from −13.4‰ to −5.7‰, suggesting that organic matter was an important carbon source for calcite cements. A comparison of the porosity data with a theoretical compaction curve indicates that the upper and middle parts of the stratigraphic column show higher-than-normal porosity values, which are related to significant calcite and feldspar dissolution. Meteoric incursion and carboxylic acids generated from organic maturation were probably responsible for the abundant dissolution events.