Sm–Nd and Ar–Ar Isotopic Dating of the Nuri Cu–W–Mo Deposit in the Southern Gangdese,Tibet: Implications for the Porphyry‐Skarn Metallogenic System and Metallogenetic Epochs of the Eastern Gangdese

The Nuri Cu–W–Mo deposit is a large newly explored deposit located at the southern margin of the Gangdese metallogenic belt. There are skarn and porphyry mineralizations in the deposit, but the formation age of the skarn and the relationship between the skarn and porphyry mineralizations are controversial. Constraints on the precise chronology are of fundamental importance for understanding the ore genesis of the Nuri deposit. To determine the formation age of the skarn, we chose garnets and whole rock skarn samples for Sm–Nd dating. We also selected biotite associated with potassic alteration for Ar–Ar dating to confirm the ore formation age of the porphyry mineralizations. The Sm–Nd ages of the skarn are 25.73 ± 0.92 – 25.2 ± 3.9 Ma, and the age of the potassic alteration is 24.37 ± 0.32 Ma. The results indicate that the skarn and porphyry mineralization are coeval and belong to a unified magmatic hydrothermal system. Combined with a previous molybdenite Re–Os age, we think that the hydrothermal activity of the Nuri deposit lasted for 1.2 – 2.1 Myr, which indicates that the mineralization formed rapidly. The chronologic results indicate that the Nuri deposit formed in the period of transformation from compression to extension in the late collisional stage of the collision between the Indian and Eurasian continents.     

基于加权距离成本的最优学区划分算法

学区划分的科学性与合理性始终是我国教育领域的一个热点课题。最优学区划分算法研究具有重要的现实意义。本文以就近入学为基本原则,以区域学生总体上学距离成本最小化为核心目标,提出了一种基于学生数量加权距离成本的最优学区划分算法,通过FME软件平台设计程序加以实现,利用模拟数据试验验证了算法和程序的可行性与有效性。     

2006-2015年上海嘉定区气温和降水非均匀分布特征分析

利用上海嘉定区2006-2015年9个自动气象观测站的逐小时观测资料,通过对气温和降水日变化差异、年变化特征、空间分布状况的分析,研究了该地区气温和降水时空非均匀性分布特征。研究结果表明：嘉定区气温和降水日变化存在局地差异和季节差异,日最高气温出现时间在四季中最为集中,而日最低气温出现时间则比较分散;年平均气温呈走低趋势,而年降水量从整体上来说却呈增加趋势;上海嘉定区东南角为气温高值区且降水量相对偏大,中部地区为降水量高值区且气温也相对偏高,而北部降水量偏少且气温偏低,表明嘉定区东南部和中部相对暖湿,而北部偏干冷;气温和降水的标准差空间分布差异大,表明上海嘉定区气温和降水的空间非均匀性特征显著。通过嘉定气温和降水的时空演变规律的揭示,有助于更好地认识小尺度局部区域气候特征,也能为准确认识该地区的极端事件、精细化天气预报及区域气象灾害风险评估提供更加科学的气候变化背景。     

浮游植物生物法测定海水铜络合容量

采用牟氏角毛藻通过生物法测定青岛多处近岸水的铜络合容量CC_(cu)。此法测定的CC_(cu)值范围在1.6×10~(-7)～6.7×10~(-7)mol/dm~3之间。测定了4个经紫外线消解的海水中不同含量EDTA,结果表明,此法可较好反映水体中配位体的含量。使用1.5次微分ASV法也测定了这些样品的CC_(cu),两种方法测定结果比较,表明生物法测得的CC_(cu)值大于ASV法。这样差异可能与两种方法测定铜的形态不同有关。     

Sea water environment copper requirement of egg hatching and naupliar metamorphosis of Peaneus chinensis

ＳｅａｗａｔｅｒｅｎｖｉｒｏｎｍｅｎｔｃｏｐｐｅｒｒｅｑｕｉｒｅｍｅｎｔｏｆｅｇｇｈａｔｃｈｉｎｇａｎｄｎａｕｐｌｉａｒｍｅｔａｍｏｒｐｈｏｓｉｓｏｆＰｅａｎｅｕｓｃｈｉｎｅｎｓｉｓ￥ＹｕａｎＹｏｕｘｉａｎ；ＱｕＫｅｍｉｎｇ；ＬｉｕＬｉｂｏ；ＧａｏＣ...     

渤海湾北部海域表层海水的表观铜络合容量

为给渤海湾北部海域重金属铜环境容量研究提供科学依据，采用阳极溶出伏安法对该海域12个站位表层海水样品的表观铜络合容量(ACuCC)和条件稳定常数(K)以及络合容量指数(CCI)进行了测定和计钟：。得到该海区表层海水的表观铜络合容量在228．0～673．4nmol／L之间，平均值为437．5nmol／L，条件稳定常数对数值(IgK)变化范围在7．41～8．84之间，平均值为7．89，络合容量指数在72．69％～92、92％之间，平均值为82．93％。表明该海域表层海水对重金属铜具有较强的络合能力。     

闽江口溶解态镉、铜、铅的行为及其与营养盐的关系

研究了１９９０年６月和１０月闽江口溶解态镉、铜、铅的行为及其与营养盐的关系。结果表明，在６月和１０月镉呈添加行为，铜呈保守行为，而铅呈除去行为、镉的添加主要源自浮游生物碎屑的再矿化作用，而铅的去除受非生物无机过程控制。     

含羟基西佛碱型大环冠醚铜(Ⅱ)、锌(Ⅱ)配合物的合成与表征

利用模板法合成 1种新的含醇羟基西佛碱型大环冠醚 L (7,11-二氮杂 - 3,15 -二氧杂 - 4 ,5 ;8,10 ;13,14-三苯并环十六 - 6 ,11-二烯 - 1-醇 )的铜、锌配合物。经元素分析 ,IR、MS分析确定配合物的组成 M(L2 ) (NO3 ) 2 及其配位情况 ,由模板反应得到 [1+ 1]型西佛碱大环化合物。 DMF溶液中的电导数据证实它们均属非电离型 ,并运用 TG- DTA分析比较铜、锌配合物的热稳定性。     

Porphyry fertility in the Northparkes district: indicators from whole-rock geochemistry

Abstract

Four economic porphyry Cu–Au deposits and several prospects have been investigated in the Northparkes district, part of the Ordovician to early Silurian Junee–Narromine Belt of the Macquarie Arc, New whole-rock geochemical data from the Northparkes porphyry Cu–Au district, NSW, indicate that the mineralising intrusive complexes exhibit distinct arc signatures that are transitional from high-K calc-alkaline to silica-saturated alkalic. Based on ratios of Sr/Y vs Y (e.g. Sr/Y > ～20 and Y < ～17?ppm) the mineralising intrusions are interpreted to have crystallised from fractionated hydrous melts indicating the suppression of plagioclase crystallisation in favour of hydrous mineral phases. This interpretation is supported by listric-shaped rare earth element curves and the presence of primary hornblende phenocrysts indicating elevated magmatic water contents. There is an association of mineralising intrusions with a low Zr trend both in the mineralised Northparkes district intrusive rocks and in mineralised porphyry-related intrusive rocks globally. A newly developed fertility indicator ratio Zr/Y ～10% is more accurate at identifying the mineralised rocks at Northparkes than the conventional Sr/Y vs Y fertility indicator diagram, successfully identifying 92% of the mineralising intrusions, mainly owing to the fact that it is less affected by hydrothermal alteration. The insensitivity of Zr–Y to alteration makes this indicator a useful new tool that may lead to enhanced probabilities for future discoveries in the Northparkes district, broader Macquarie Arc and altered rocks globally.

1. KEY POINTS

2. Mineralising intrusions in the Northparkes district have distinct Zr vs Y concentrations.

3. The Zr vs Y indicator of magmatic fertility is less sensitive to alteration than Sr-based indicators.

4. The Zr vs Y magmatic fertility indicator identified at Northparkes is not unique and identifies mineralising intrusions in other porphyry fields.