海岛旅游效率空间格局演变及影响因素研究 ——以中国12个海岛县(区)为例

旅游产业是海岛地区的重要产业之一，借助 DEA 模型测度 12 个海岛县 （区） 的旅游效率，采用组合方法对海岛旅游效率的空间特征演变进行刻画，并通过 EVIEWS 软件分析海岛旅游效率的影响因素。 （1） 海岛旅游综合效率总体不高，技术效率是海岛旅游效率发展的主要驱动力，规模效率水平较低，海岛旅游发展能力未得到全面发挥。 （2） 海岛县 （区） 之间旅游效率总体差异不大，相对差异明显。海岛旅游效率空间状态演变由不稳定趋向于稳定，可能存在“贫困陷阱”和“俱乐部趋同”现象。 （3） 经济发展水平、生态环境、科技信息对海岛旅游效率的发展起到积极的推动作用，产业结构、交通条件、城镇化是海岛旅游效率发展的约束性因素。     

Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile

The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu²⁺ concentrations in excess of 10^− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu²⁺ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems.     

拉拉铜矿黄铁矿微量元素地球化学特征及其成因意义

四川会理拉拉铜矿床是我国著名大型富铜矿床,针对该矿床中黄铁矿的微量元素、稀土元素地球化学分析表明:拉拉铜矿经历了早期火山喷发成岩成矿和晚期变质成岩成矿作用.条带状矿石中的黄铁矿Co/Ni比值集中于4.92～79.2之间,落入火山成因黄铁矿区,稀土元素分布具有Eu正异常和轻稀土富集的特征,反映矿床具有伴随河口群火山喷流沉积成岩过程的同生沉积成矿作用.脉状矿石中的黄铁矿Co/Ni比值集中于1.10～3.45,落在热液成因黄铁矿区,稀土元素较河口群岩石及其他典型块状硫化物矿床矿石稀土元素更加富集轻稀土元素,稀土含量变化范围更大,显著的负Eu异常,则又说明,矿床形成的主要成矿作用是伴随新元古代晋宁运动而发生的大规模的变质作用.     

商城县汤家坪钼矿地球化学特征及找矿远景

矿区地质、地球化学特征研究入手,总结了综合找矿标志,指出了进一步找矿方向。研究表明该矿床成矿组分单一,异常元素组合主要为Mo、Bi、Ag,次为W、Sn、Zn、Cu、Pb,仅有钼能形成较大规模的异常;矿床元素水平分带序列为(Mo-Bi-Ag)-(W-Sn)-(Pb-Zn-Cu),垂向分带序列为(Mo-Ag-Pb-Zn)-Cu-(Bi-W-Sn),并以w(Mo)/[w(Bi)×100]≥65,[w(Pb)×w(Zn)/w(W)×w(Sn)]≥25为判别标志,来预测深部盲矿体的存在。     

Interaction of copper with fatty acids in Soxhlet extraction and its influence

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.     

舒兰市福安堡钼矿床地质特征及找矿意义

本文较详细地介绍了福安堡中型斑岩钼矿床的地质特征、找矿标志及找矿方法,对在吉林地区北部舒兰—蛟河一带分布的印支—燕山期花岗岩区寻找大、中型斑岩型钼矿床具有重要的指导意义。     

四川稻城竹鸡顶铜矿地质特征及成矿特点

竹鸡顶斑岩型铜矿位于西南三江成矿带内,热液蚀变以青磐岩化、泥化为特征。区内现已圈出1个矿带和2个矿化带,并有幅频激电异常、土壤铜异常与之套合。该区具有较好的找矿前景。     

云南东川因民铜矿金矿化特征及成因初探

因民铜矿发育两种金矿化类型:一是铜矿的伴生金;二是热液构造蚀变岩型。化探样品分析结果显示,金矿化主要赋存于金箔箐断层上、下盘的角砾状蚀变岩内,空间上受岩性和断裂构造的双重控制。邻区拖布卡金矿的成矿地质背景与本区相似,在成矿地质年代上作以类比推测,认为喜马拉雅期是主成矿期。另外通过对光片镜下和化探原生晕样聚类分析研究,发现构造蚀变岩型金矿化具明显的多期多阶段性及热液特征。     

河南黄淮平原土壤中Cu的生态安全评价

在分析河南黄淮平原土壤和小麦籽实中Cu含量分布特征的基础上,利用单项污染指数法对研究区小麦籽实中Cu的污染状况进行评价。其结果为：研究区小麦籽实中Cu的单项污染指数Pi的平均值为0．473,说明研究区小麦籽实未受Cu的污染。Cu的状况良好。进一步讨论了土壤中Cu的含量与小麦籽实中Cu含量间的关系。认为小麦籽实中Cu的积累与土壤中的总Cu无明显的相关关系,而与土壤中的有效态Cu含量具有明显的相关性。据此,将土壤有效态Cu作为土壤Cu生态安全评价的指标。并建立了小麦籽实Cu与土壤有效Cu的响应关系模型,确定了土壤中有效Cu的安全界限值。     

内蒙古阿鲁科尔沁旗好力宝铜钼矿床地质特征及找矿方向

好力宝铜钼矿床属与燕山期隐伏的隐爆角砾状斜长花岗斑岩和碎裂次石英斑岩有关的热液脉状和斑岩型矿床.铜钼矿体受隐爆角砾岩筒和岩体控制,矿化产在蚀变隐爆角砾岩和硅化带中.今后的找矿方向应侧重于对斜长花岗斑岩与围岩接触带和碎裂次石英斑岩中化探异常和低阻高极化异常地段的探索.