陕西彬县大佛寺D4钻孔勘察地球化学研究

运用烃类勘察地球化学方法，对鄂尔多斯盆地南部彬县大佛寺井田钻遇中休罗统煤层的耽钻孔，进行了垂向剖面多指标的综合地球化学研究。结果表明：剖面中所有岩样中的烃类物质均为热解烃生成初期演化阶段的煤成烃产物，具明显的同一性；由煤层至地表黄土，所有岩样中的烃类呈明显的、规律性垂直向上运移。这证实地下煤层烃类在近地表具有很好的地球化学信息显示，利用勘察地球化学方法找煤／煤层气是可行的。     

地球化学样品分析质量管理系统

利用VFP6．0强大的数据计算和管理功能，设计了对地质调查样品分析数据的实验室质量管理系统。该系统不仅可以同时管理多个图幅样品的数据，还可以自动实现样品编码、内检样品按指定比例随机生成、一级和二级标样质量汇总、内检合格率和报出率计算、二级标样质量监控图绘制以及按选定格式进行分析数据和内检数据的导入和导出，可以根据用户的需要输出美观的表格。该系统适用于不同比例尺化探数据的实验室质量管理。     

呼和浩特市环境地球化学特征初探

介绍了呼和浩特市环境地球化学特征,对该区土壤次生环境进行了质量分区划分,探讨该区土壤环境地球化学元素迁移概略,提出了土壤环境地球化学治理的具体意见.     

云南保山卧牛寺组玄武岩成因：地幔柱活动的产物？

保山卧牛寺组玄武岩为低钛拉斑玄武岩，具有大陆板内玄武岩的特征，总体与蛾眉山玄武岩中的低钛玄武岩相似。其分异程度较高，富集大离子亲石元素和高场强元素，有明显的Nb、Ta负异常，Zr和Hf正异常，Eu无异常或弱负异常。该玄武岩由3个大喷发旋回形成3个岩石单元，其中下部早期第1单元由致密块状玄武岩、斜斑玄武岩、杏仁玄武岩和凝灰岩组成，第2和第3单元中见少量橄榄玄武岩和粒玄岩以及辉绿岩脉。有较高的^86Sr／^87Sr值(0．705966—0．706657)、较低的^143Nd／^144Nd值(0．512212—0．512283)，εNd(t)多为负值，源区为介于EMI和EMⅡ端员之间的富集岩石圈地幔。上述地球化学和同位素特征均可与蛾眉山玄武岩下部低钛拉斑玄武岩对比，表明该期岩浆作用可能同为地幔柱活动的产物，并暗示蛾眉山大火成岩省向西有很大的延伸。     

新疆东天山地区土屋、延东铜矿地球化学特征与异常查证方法

对土屋地区干旱荒漠景观地球化学条件和勘查地球化学方法进行了分析，对比研究了不同比例尺地球化学异常特征及对矿床的反映能力，指出了该区铜元素是预测铜矿的最重要的指示元素，论证了在区域铜高背景区和异常区开展1：5万化探是进一步定性、定位预测矿区、矿床的重要环节，提出了东天山地区经济、有效的地球化学勘查和异常查证方法技术组合。     

易门式大型铜矿床构造成矿动力学模型

针对金属矿床隐伏矿定位预测的关键问题,在提出构造成矿动力学的分支学术方向的基础上,以易门式大型铜矿床为例,从成矿地质背景、矿田构造、构造地球化学和成矿构造应力场等方面进行构造成矿动力学研究,阐述在构造应力场控制下成矿流体运移和聚集的规律。构造地球化学研究认为,构造地球化学异常反映矿体的原生晕;构造地球化学异常受构造控制,其分带特征可指示成矿流体的流向,并提供矿床成因和隐伏矿(化)体相对埋深的信息。构造应力场的控矿特征主要表现在:构造应力场导致控矿构造的形成,并驱动成矿流体的运移;构造应力场控制了成矿能量场;应力和能量的高值集中区分布特点可反映某些构造型式。在此基础上建立构造成矿动力学模型,概括隐伏矿成矿预测准则,据此提出若干重点找矿靶区和靶位,其中部分靶区得到工程验证,表明构造成矿动力学方法对隐伏矿定位预测和评价具有重要的指导意义。     

Weathering control over geomorphology of supermature Proterozoic Delhi quartzites of India

Quartz and quartzite are thought to be resistant as a mineral and a rock respectively; however, we have shown that the presence of small amounts of pyrite in the quartzites makes them vulnerable to weathering. We observe that weathering of Proterozoic quartzite in the semi‐arid conditions around Delhi proceeded from fractures towards the inside and produced weathering rinds. The chemical index of alteration (CIA), which is actually a measure of weathering of aluminosilicate minerals, increases from the core outwards, through the rinds. Although aluminosilicate minerals occur only as minor phases (<2 per cent), their weathering indicates a movement of the weathering front from the periphery towards the core. We have suggested a coupled mechanism in which the dissolution of pyrites by moving water produced a sulphate‐bearing acidic solution and ferrous iron, which reacted with aluminosilicate minerals and quartz, respectively. This initially makes the Delhi quartzite porous and subsequently friable. The total disintegration of grain to grain contacts imparted friability to this quartzite to produce silica sand. Subsequent physical erosion of loose sand, produced during rind development in the outermost zones, has given rise to features like tors, spheroids, gullies, cavities and small‐scale caves on these quartzites. Thus, the terrain has acquired ruggedness in semi‐arid conditions. Copyright © 2003 John Wiley & Sons, Ltd.     

Provenance analysis and tectonic setting of the Ordovician clastic deposits in the southern Puna Basin, NW Argentina

Provenance studies on Early to Middle Ordovician clastic formations of the southern Puna basin in north-western Argentina indicate that the sedimentary detritus is generally composed of reworked crustal material. Tremadoc quartz-rich turbidites (Tolar Chico Formation, mean composition Q_t89 F7 L4) are followed by volcaniclastic rocks and greywackes (Tolillar Formation, mean Q_t33 F42 L25). These are in turn overlain by volcaniclastic deposits (mean Q_t24 F30 L46) of the Diablo Formation (late Arenig–early Llanvirn) that are intercalated by lava flows. All units were deformed in the Oclóyic Orogeny during the Middle and Late Ordovician. Sandstones of the Tolar Chico Formation are characterized by Th/Sc ratios > 1, La/Sc ratios ≈ 10, whereas associated fine-grained wackes show slightly lower values for both ratios. LREE (light rare earth elements) enrichment of the arenites is ≈ 50× chondrite, Eu/Eu* values are between 0·72 and 0·92, and flat HREE (heavy rare earth elements) patterns indicate a derivation from mostly felsic rocks of typical upper crustal composition. The ε_{Nd(t = sed)} values scatter around −11 to −9. The calculated Nd-T_DM residence ages vary between 1·8 and 2·0 Ga indicating contribution by a Palaeoproterozoic crustal component. The Th/Sc and La/Sc ratios of the Tolillar Formation are lower than those of the Tolar Chico Formation. Normalized REE (rare earth elements) patterns display a similar shape to PAAS (post-Archaean average Australian shale) but with higher abundances of HREEs. Eu/Eu* values range between 0·44 and 1·17, where the higher values reflect the abundance of plagioclase and feldspar-bearing volcanic lithoclasts. Average ε_{Nd(t = sed)} values are less negative at −5·1, and Nd-T_DM are lower at 1·6 Ga. This is consistent with characteristics of regional rocks of upper continental crust composition, which most probably represent the sources of the studied detritus. The rocks of the Diablo Formation have the lowest Th/Sc and La/Sc ratios, lower LREE abundances than the average continental crust and are slightly enriched in HREEs. Eu/Eu* values are between 0·63 and 1·17. The Nd isotopes (ε_{Nd(t = sed)} = −3 to −1; T_DM = 1·2 Ga) indicate that one source component was less fractionated than both the underlying Early Ordovician and the overlying Middle Ordovician units. Synsedimentary vulcanites in the Diablo Formation show the same isotopic composition. Our data indicate that the sedimentary detritus is generally composed of reworked crustal material, but that the Diablo Formation appears to contain ≈ 80% of a less fractionated component, derived from a contemporaneous continental volcanic arc. There are no data indicating an exotic detrital source or the accretion of an exotic block at this part of the Gondwana margin during the Ordovician.     

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).     

壳幔混染作用——下扬子区早中生代玄武岩同位素地质特征

下扬子区中生代（231Ma）玄武质火山岩全岩εNd（t）值-8.62～1.92,87Sr/86Sr 值0.7074～0.7179，206Pb/204Pb值为17.786～18.323。岩石中含有前寒武纪捕虏晶锆石。研究表明玄武质岩石可能是由亏损地幔与元古宙地壳岩石混染作用的结果。