Microbial activity promotes the enrichment of cobalt over nickel on hydrogenetic ferromanganese crusts

The different mineral phases of the ferromanganese (Fe–Mn) crusts stem from the interaction of biotic and abiotic components. It is therefore vital to study the activity of these components to decipher their contribution to the enrichment/depletion of metals in the crust. Thus, the present study examined sorption and release of Co and Ni by Fe-Mn crusts with associated microbial communities in the presence and absence of the metabolic poison sodium azide (15?mM). The study was conducted in the presence (G⁺) and absence (G^?) of added glucose (0.1%) at temperatures of 4?±?1°C and 28?±?2°C. Results showed that the microbial community had maximal sorption of Co of 66.12?µg?g^?1 at 4?±?1°C in the absence of added glucose and 479.75?µg?g^?1 at 28?±?2°C in the presence of added glucose. Maximum sorption of Ni in the absence of added glucose was 1.89?µg?g^?1 at 4?±?1°C and release of Ni was 51.28?µg?g^?1 in the presence of added glucose. Under abiotic conditions with 15?mM sodium azide as a metabolic inhibitor, significant amounts of Co and Ni were released in the G⁺ medium. Total cell counts on the Fe-Mn crust in the presence of added glucose increased by an order of magnitude from 10⁶ to 10⁷ cells g^?1 and in the absence of added glucose remained within the order of 10⁶ cells?g^?1 irrespective of temperature of incubation. Microscopic observation of the samples from biotic incubations showed numerous bacterial cells, exopolysaccharides, and structures resembling secondary minerals formed by bacteria. The results indicate that bacteria promote the enrichment of Co and Ni on the hydrogenetic Fe-Mn crusts by sorption processes and release of Ni by reductive dissolution of the oxides. The higher enrichment of Co than Ni is attributed to the way in which microbes interact with the metals.     

Zircon U–Pb and pyrite Re–Os age constraints on pyrite mineralization in the Yinjiagou deposit,China

We report new zircon U–Pb and pyrite Re–Os geochronological studies of the Yinjiagou poly-metallic deposit, sited along the southern margin of the North China Craton (SMNCC). In this deposit, pyrite, the most important economic mineral, is intergrown/associated with Mo, Cu, Au, Pb, Zn, and Ag. Prior to our new work, the age of chalcopyrite–pyrite mineralization was known only from its spatial relationship with molybdenite mineralization and with intrusions of known ages. The U–Pb and Re–Os isotope systems provide an excellent means of dating the mineralization itself and additionally place constraints on the ore genesis and metal source. Zircons separated from the quartz–chalcopyrite–pyrite veins include both detrital and magmatic groups. The magmatic zircons confine the maximum age of chalcopyrite–pyrite mineralization to 142.0 ± 1.5 Ma. The Re–Os results yield an age of 141.1 ± 1.1 Ma, which represents the age of the chalcopyrite–pyrite mineralization quite well. The common Os contents are notably low (0.5–20.1 ppt) in all samples. In contrast, the Re contents vary considerably (3.0–199.2 ppb), most likely depending on intensive boiling, which resulted in an increase of Re within the pyrite. This study demonstrates that the main chalcopyrite–pyrite mineralization occurred late in the magmatic history and was linked to a deeper intrusion involving dominant mantle-derived materials. This mineralization event might be related to the Early Cretaceous lithospheric destruction and thinning of the SMNCC.     

Whether human-induced activities could change the gradient pattern of coastal land use along the sea-land direction: a case study in Manila Bay,Philippines

Increasing intense human activities have largely changed the coastal landscape and caused many environmental issues. However, whether human-induced activities could change the coastal land use gradient pattern, an important coastal zonal characteristic along the sea–land direction, remains unclear. Manila Bay was selected as the study area in this work. According to the distance of the land use and land cover(LULC) to the coastline, we clustered the typical coastal land use sequence patterns(CLU...     

New interpretation on the provenance changes of the upper Pinghu–lower Huagang Formation within Xihu Depression,East China Sea Shelf Basin

Both Pinghu and Huagang formations are important hydrocarbon reservoirs of the Xihu Depression in the East China Sea Shelf Basin. Clarifying the source suppliers and restoring source-to-sink transport routes are of great significance to the future petroleum and gas undertakings. Previous researchers were largely confined by either limitation of geological records, highly dependence on a singular method or low-precision dating techniques. Our study integrated heavy mineral assemblages, geochemica...     

Coastal ridge constructive processes at a multi-decadal scale in Barreta Island (southern Portugal)

Multiple ridges across prograding coasts may display variable geometries, commonly expressed through varying elevations. Changes in ridge elevation have been traditionally related to the occurrence of fluctuating progradation rates, which might, in turn, be driven by shifting environmental conditions. Here, we explore the geometry and growth mechanisms of multiple ridges, generated at Barreta Island (Ria Formosa, southern Portugal), as a consequence of the rapid progradation of the island over the last 70 years, following the artificial fixation of the downdrift Faro-Olhão inlet with jetties in 1955. The variability in the morphology of these features was analysed in combination with available wind and wave data, in order to better distinguish growth mechanisms and understand the main parameters determining the final geometry of the observed ridges. The results suggest that (1) most of the identified ridges fall in the beach ridge classification, as they have been mostly built by marine processes, and (2) the parameters derived from, or closely related to wave climate variability (e.g. progradation rates, storm occurrence) can jointly explain most of the observed morphological changes, while aeolian processes played a secondary role. Indeed, ridge geometry appears mainly controlled by progradation rates, with higher ridges associated with lower progradation rates. Progradation rate, in turn, is mostly related to longshore wave power, storminess, and the occurrence storm groups. Yet, the final configuration of ridges can also be affected by runup levels and onshore winds. Therefore, establishing the relation between ridge geometry and wave climate is not a straightforward task, because of the complex processes and interactions that control coastal morphodynamics. © 2019 John Wiley & Sons, Ltd.     

Age and significance of voluminous mafic–ultramafic magmatic events in the Murchison Domain,Yilgarn Craton

Mafic–ultramafic rocks in structurally dismembered layered intrusions comprise approximately 40% by volume of greenstones in the Murchison Domain of the Youanmi Terrane, Yilgarn Craton. Mafic–ultramafic rocks in the Murchison Domain may be divided into five components: (i) the ～2810 Ma Meeline Suite, which includes the large Windimurra Igneous Complex; (ii) the 2800 ± 6 Ma Boodanoo Suite, which includes the Narndee Igneous Complex; (iii) the 2792 ± 5 Ma Little Gap Suite; (iv) the ～2750 Ma Gnanagooragoo Igneous Complex; and (v) the 2735–2710 Ma Yalgowra Suite of layered gabbroic sills. The intrusions are typically layered, tabular bodies of gabbroic rock with ultramafic basal units which, in places, are more than 6 km thick and up to 2500 km² in areal extent. However, these are minimum dimensions as the intrusions have been dismembered by younger deformation. In the Windimurra and Narndee Igneous Complexes, discordant features and geochemical fractionation trends indicate multiple pulses of magma. These pulses produced several megacyclic units, each ～200 m thick. The suites are anhydrous except for the Boodanoo Suite, which contains a large volume of hornblende gabbro. They also host significant vanadium mineralisation, and at least minor Ni–Cu–PGE mineralisation. Collectively, the areal distribution, thickness and volume of mafic–ultramafic magma in these complexes is similar to that in the 2.06 Ga Bushveld Igneous Complex, and represents a major addition of mantle-derived magma to Murchison Domain crust over a 100 Ma period. All suites are demonstrably contemporaneous with packages of high-Mg tholeiitic lavas and/or felsic volcanic rocks in greenstone belts. The distribution, ages and compositions of the earlier mafic–ultramafic rocks are most consistent with genesis in a mantle plume setting.     

Microchemical Characterization of Natural Gold and Copper Alloys from the Ancient Um Shashoba Gold Mine,South Egypt

The SEM-EDX technique was applied to investigate Au, and Cu＋Sn alloyed grains in the mineralization of the Um Shashoba mine for achieving further understanding of occurrences, internal structures and microchemistry of Au and Cu alloys and associated minerals, and mineralization type. This study is aiming at the genetic history of ore-bearing fluid events, geochemical evaluation and exploration significance. The results showed that the mineralization could be considered as a single major episode generated by metamorphic mesothermal solution rich in sulfides and unsaturated respect to Au. It was differentiated into many stages; started with formation of auriferous pyrite that was pseudomorphed by secondary hematite, limonite and goethite. Three phases of Au alloy were precipitated, and Cu＋Sn and Ag-rich alloys were produced respectively and followed by deposition of two generations of barren pyrite. Calcite and ankerite were crystalized, surrounded and partially replaced some of early formed minerals. Finally, barren muscovite recrystallized around and inside both later formed carbonate minerals that were free of any sign of Au in their structures. The processes of deformation, recrystallization, annealing, dissolution, remobilization and re-precipitation played the most important roles in the genetic history of the mineralization.     

Preliminary 3–D geological model of the Kalgoorlie region,Yilgarn Craton,Western Australia,based on deep seismic‐reflection and potential‐field data

The granite‐greenstone terranes of the Eastern Goldfields Province, Yilgarn Craton, Western Australia, are a major Australian and world gold and nickel source. The Kalgoorlie region, in particular, hosts several world‐class gold deposits. To attempt to understand why these deposits occur where they do, it is important to understand the crustal architecture in the region and how the major mineral systems operate in this architecture. One way to understand these relationships is to develop a detailed 3–D geological model for the region. The best method to map the 3–D geometry of major geological structures is by acquisition and interpretation of seismic‐reflection profiles. To contribute to this aim, a grid of deep seismic‐reflection traverses was acquired in 1999 to examine the 3–D geometry of the region in an area including the Kalgoorlie mineral region and mineral fields to the north and west. This grid was tied to the 1991 regional deep seismic traverse and 1997 high‐resolution seismic profiles in the same region. The grid covers an area measuring approximately 50 km wide by 50 km long and extended to a depth of approximately 50 km (below the base of the crust in this region). The resulting 3–D geological model was further constrained by both surface geological data and geophysical interpretations, with the seismic interpretations themselves also constrained by gravity and magnetic modelling. The 3–D model was used to investigate the geometric relationships between the major faults and shear zones in the area, the relationship between the granite‐greenstone succession and the basement, and the spatial relationships between the greenstones and the granites. Interpretation of the grid of seismic lines and construction of the 3–D geological model confirmed the existence of the detachment surface and led to the recognition that the granite‐greenstone contact usually occurs at a much shallower level than the detachment. Also, west‐dipping faults in the vicinity of the Golden Mile, including the Abattoir Shear through to Boulder‐Lefroy Fault, appear to be more important than previously thought in controlling the structure of that area. An antiformal thrust stack occurs beneath a triangle zone centred on the Golden Mile. The Black Flag Group was deposited in a probable extensional setting, and late extension was also probably more important than previously thought. The granite‐gneiss domes were uplifted by the formation of antiformal thrust stacks at depth beneath them.     

The magmatic history of the Vetas-California mining district,Santander Massif,Eastern Cordillera,Colombia

The Vetas-California Mining District (VCMD), located in the central part of the Santander Massif (Colombian Eastern Cordillera), based on U–Pb dating of zircons, records the following principal tectono-magmatic events: (1) the Grenville Orogenic event and high grade metamorphism and migmatitization between ∼1240 and 957 Ma; (2) early Ordovician calc–alkalic magmatism, which was synchronous with the Caparonensis–Famatinian Orogeny (∼477 Ma); (3) middle to late Ordovician post-collisional calc–alkalic magmatism (∼466–436 Ma); (4) late Triassic to early Jurassic magmatism between ∼204 and 196 Ma, characterized by both S- and I-type calc–alkalic intrusions and; (5) a late Miocene shallowly emplaced intermediate calc–alkaline intrusions (10.9 ± 0.2 and 8.4 ± 0.2 Ma). The presence of even younger igneous rocks is possible, given the widespread magmatic–hydrothermal alteration affecting all rock units in the area.The igneous rocks from the late Triassic–early Jurassic magmatic episodes are the volumetrically most important igneous rocks in the study area and in the Colombian Eastern Cordillera. They can be divided into three groups based on their field relationships, whole rock geochemistry and geochronology. These are early leucogranites herein termed Alaskites-I (204–199 Ma), Intermediate rocks (199–198 Ma), and late leucogranites, herein referred to as Alaskites-II (198–196 Ma). This Mesozoic magmatism is reflecting subtle changes in the crustal stress in a setting above an oblique subduction of the Panthalassa plate beneath Pangea.The lower Cretaceous siliciclastic Tambor Formation has detrital zircons of the same age populations as the metamorphic and igneous rocks present in the study area, suggesting that the provenance is related to the erosion of these local rocks during the late Jurassic or early Cretaceous, implying a local supply of sediments to the local depositional basins.