非金属矿物在抗菌材料制备中的应用

介绍了几种非金属矿物(沸石、海泡石等)的结构特点,并简要阐述了以沸石、海泡石和累托石等为载体的金属离子型无机抗菌剂的制备方法及其对各种菌类的抑制情况;天然非金属矿物结构独特,价格低,资源广,作为抗菌剂载体具有很高的应用价值。     

萤石夜明珠有关问题探讨

近年来，中国的各种传媒上不断出现有关夜明珠的报道。引起了广泛的注意，当前市场上出现的夜明珠主要是荧石夜明珠，笔者对荧石夜明珠作了一些初步研究和探讨。发光的原因主要是含稀土元素（rare earth elements)所致，含量可以低至万分数。本文的资料希望能促进对夜明珠问题的深入认识。     

Natural attenuation of TCE, As, Hg linked to the heterogeneous oxidation of Fe(II): an AFM study

Hydrous ferric oxide (HFO) colloids formed, in strictly anoxic conditions upon oxidation of Fe²⁺ ions adsorbed on mineral surface, were investigated under in situ conditions by contact mode atomic force microscopy (AFM). Freshly cleaved and acid-etched large single crystals of near endmember phlogopite were pre-equilibrated with dissolved Fe(II) and then reacted with Hg(II), As(V) and trichlorethene (TCE)-bearing solutions at 25 °C and 1 atm. HFO structures are found to be of nanometer scale. The As(V)–Fe(II) and Hg(II)–Fe(II) reaction products are round (25 nm) microcrystallites located predominantly on the layer edges and are indicative of an accelerated Fe(II) oxidation rate upon formation of Fe(II) inner sphere surface complexes with the phyllosilicate edge surface sites. On the other hand, TCE–Fe(II)–phlogopite reaction products are needle-shaped (45 nm long) particles located on the basal plane along the Periodic Bond Chains (PCBs) directions. Experiments with additions of sodium chloride confirm the importance of the Fe(II) adsorption step in the control of the overall heterogeneous Fe(II)–TCE electron transfer reaction.

Kinetic measurements at the nanomolar level of Hg° formed upon reduction of Hg(II) by Fe(II) in presence of phlogopite particles provide further convincing evidence for reduction of Hg(II)_aq coupled to the oxidation of Fe(II) adsorbed at the phlogopite–fluid interface, and indicate that sorption of Fe(II) to mineral surfaces enhances the reduction rate of Hg(II) species. The Hg(II) reduction reaction follows a first-order kinetic law. Under our experimental conditions, which were representative of many natural systems, 80% of the mercury is transferred to the atmosphere as Hg° in less than 2 h.

The reduction of a heavy metal (Hg), a toxic oxyanion (arsenate ion) and a chlorinated solvent (TCE) thus appear to be driven by the high reactivity of adsorbed Fe(II). This is of environmental relevance since these three priority pollutants are that way reductively transformed to a volatile, an immobilizable and a biodegradable species, respectively. Such kinetic data and reaction pathways are important in the evaluation of natural evaluation scenarios, in the optimization of Fe(II)/mineral mixtures as reductants in technical systems, and in general, in predicting the fate and transport of pollutants in natural systems.     

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in sediments from Hong Kong

Concentrations of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in 14 sediment samples collected from four sites in the Mai Po Marshes Nature Reserve (within a RAMSAR Site) and from another six sites in Victoria Harbour and along the Hong Kong coastline. Elevated levels of PCDDs, and particularly OCDD, were detectable in all samples collected from the Mai Po Marshes and five of the six sites. In contrast to PCDDs, PCDFs were mainly found in sediment samples collected from industrial areas (Kwun Tong and To Kwa Wan) in Victoria Harbour. PCDD/F levels and congener profiles in the samples from the Mai Po Marshes Nature Reserve in particular show strong similarities to those reported in studies which have attributed similar elevated PCDD concentrations to nonanthropogenic PCDD sources.     

人类活动对北京东灵山山顶草甸植被的影响及草甸植被的保育对策

通过对北京东灵山海拔 1500 m以上草甸植被资源的调查，共获得41个面积为 4 m×4 m的样方资料。将不同草甸群落按照人类活动的影响作用进行归类，并对各个草甸群落的生境和群落特征进行分析，结果表明：①东灵山山顶草甸植被以人类活动影响下形成的次生草甸群落为主，原生性草甸仅分布在海拔 2000 m以上的山顶及其邻近地段；②种类组成最丰富的草甸群落位于海拔1510～1900m的地段，这是自然条件和人类活动共同作用的结果；③旅游活动的影响已经使山顶原生性草甸受到威胁，局部地段草甸植被退化严重；④限制马匹活动，适时、适度提高缆车票价，在草甸分布地段部分拆除并制止新建饭店、旅馆，实行旅游功能分区规划和管理，有针对性地开展草甸承载力研究等，是现阶段草甸植被保育的重要措施。     

Seismic response of natural gas and water pipelines in the Ji-Ji earthquake

In order to study the damage patterns of natural gas and water pipelines in the Ji-Ji earthquake, a GIS database and analysis procedures were established. Repair statistics was obtained from major natural gas companies and the Taiwan Water Supply Corporation (TWSC), and entered into the system. Then, repair rates (RR) were calculated. Previously, damage was analyzed without considering the corresponding pipeline material and diameters. In this study, new attempts were made to collect more data including those related to the composition of pipelines to provide a more detailed analysis of the relationship between earthquake forces and the resulting damage. Statistical analysis was also conducted to understand the correlation between RR and seismic parameters such as the peak ground acceleration, peak ground velocity, and spectrum intensity.     

关于土卫八运动的轨道解

为了适应星际探测的需求,本文建立了在新的精度要求下土星卫星运动对应的力学模型,具体讨论了土卫八的运动,并针对主要摄动源土卫六的引力作用,建立了轨道变化的分析解,以此表明建立了土卫运动理论该采取的途径和精密定轨宜采用以轨道根数作为状态量的数值定轨方法。     

A framework for economic loss estimation due to seismic transportation network disruption: a spatial computable general equilibrium approach

This paper presents a framework for assessing the economic impact of disruption in transportation that can relate the physical damage to transportation networks to economic losses. A spatial computable general equilibrium (SCGE) model is formulated and then integrated with a transportation model that can estimate the traffic volumes of freight and passengers. Economic equilibrium under a disruption in the transportation network is computed subject to the condition that the adjustment of labor and capital inputs is restricted; the model reflects slow adjustment of these linked to the state of recovery. As a case study, the model reviews the large Niigata-Chuetsu earthquake of 2004. Considering the damage to the transportation infrastructure, the model indicates the extent of the economic losses arising from the earthquake distributed over regions as a consequence of the intra- and interregional trade in a regional economy. The results show that 20% of the indirect losses occur in the Niigata region directly affected by the earthquake, whereas 40% of the total losses are experienced in the Kanto region and non-negligible losses reach rather remote zones of the country such as Okinawa.     

A review of natural sinkhole phenomena in Italian plain areas

Italian sinkholes, which are mainly related to karst phenomena (i.e., solution sinkholes, collapse sinkholes, etc.), are widespread along the Apennine ridge and in pedemontane areas where there are carbonatic bedrock outcrops. However, other collapses, which seem unrelated to karst dissolution, have been identified in plain areas with a thick sedimentary cover over buried bedrock. The main goal of this work is to study the geological, geomorphological, and structural setting of these areas to identify the possible mechanism of the generation and evolution of these collapses. About 750 cases were identified by research based on historical archives, specific geological literature, and information from local administrations. Geological, geomorphological, and hydro-geochemical surveys were conducted in 300 cases, supported by literature, borehole, and seismic data. A few examples were discarded because they could be ascribed to karst dissolution, volcanic origin (i.e., maar), or anthropogenic causes. Field studies regarding the other 450 cases are in progress. These cases occur along the Tyrrhenian margin (Latium, Abruzzo, Campania, Tuscany) in tectonic, coastal, and alluvial plains close to carbonate ridges. These plains are characterized by the presence of pressurized aquifers in the buried bedrock, overlaid by unconsolidated sediments (i.e., clay, sands, pyroclastic deposits, etc.). The majority of these collapses are aligned along regional master and seismogenetic faults. About 50% of the studied cases host small lakes or ponds, often characterized by highly mineralized springs enriched with CO₂ and H₂S. The Periadriatic margin does not seem to be affected by these phenomena, and only a few cases have been found in Sicily, Sardinia, and Liguria. The obtained scenarios suggests that this type of collapse could be related to upward erosion through vertical conduits (i.e., deep faults) caused by deep piping processes whose erosive strength is increased by the presence of acidic fluids. In order to distinguish these collapses from typical karst dissolution phenomena, they are defined as deep piping sinkholes (DPS).     

莺歌海盆地泥-流体底辟树型输导系统及运移模式

莺歌海盆地发育多期泥.流体底辟.底辟活动的多期性造成底辟区断裂和裂隙不断开启,输导天然气从深部向浅部垂向运移,充注底辟两侧及周缘的砂体,在剖面上构成树形样式,称之为底辟树型输导系统.底辟树型输导系统连通了浅层和中一深层的构造和岩性圈闭,是莺歌海盆地中央凹陷带构造及岩性天然气藏成藏的主要输导通道和样式,其相应运移方式分为能量保持型和能量释放型两种.本文提出了莺歌海盆地中央凹陷带发育底辟树型输导系统及其运移的地质模型,泥-流体底辟活动控制下的底辟树型输导系统及其运移模型是对伸展-转换盆地油气成藏理论的发展和补充.