Multi-proxy Reconstruction of Trophic State,Hypolimnetic Anoxia and Phototrophic Sulphur Bacteria Abundance in a Dimictic Lake in Northern Germany over the past 80 Years

During monthly investigations from 1996 to 2000, a hypolimnetic layer of phototrophic sulphur bacteria (Chromatium spp.) were observed in Lake Dudinghausen, a small dimictic lake in northern Germany. This paleolimnological study was initiated to detect if the occurrence of sulphur bacteria was related to cultural eutrophication or reflected natural conditions. Therefore, diatoms, algal pigments, okenone, geochemical proxies, and ²¹⁰Pb and ¹³⁷Cs were used in four sediment cores to investigate historical changes in trophic development, hypolimnetic redox conditions, anoxia and phototrophic sulphur bacteria abundances. Fossil diatoms, pigments, the ratio of chlorophyll derivatives to total carotenoids and the ratio of chlorophyll a to its derivatives suggest two phases of eutrophication coupled with hypolimnetic anoxia over the last ~80 years: a first phase from about 1923–1932 and a second from 1952 to 1982. In the first phase the ratios of Fe–Mn as well as Fe–Ca increased, suggesting seasonal anoxia. However, hypolimnetic anoxia was only weak because low levels of okenone suggest no mass development of sulphur bacteria. In contrast, sulphur bacteria increased during the early stages of the second eutrophication phase, suggesting increased temporal and spatial hypolimnetic anoxia. Surprisingly, the ratios of Fe–Mn as well as Fe–Ca decreased during this time. Possibly Fe, Mn and Ca were equally reduced through the intense anoxia. In the final stage, sulphur bacteria decreased again. As these bacteria need both anoxic conditions and a certain amount of light, the increased nutrient load probably led to low Secchi depth and therefore insufficient light conditions. In more recent years, diatoms and pigments suggest a decrease in nutrient levels. A second mass development of sulphur bacteria occurred, probably due to improved light conditions and continued anoxia in the upper hypolimnion. We conclude that the recent development of phototrophic sulphur bacteria do not represent natural conditions in Lake Dudinghausen. Furthermore, the upper sediments contain a completely new diatom flora that never occurred in older sediments of Lake Dudinghausen. Therefore, nutrient levels may eventually reach natural conditions, however they may not represent biological background reference conditions.     

塔里木盆地柯克亚地区天然气和凝析油的地球化学特征与成区

柯克亚气田的油气成因复杂，对原油和可能烃源岩的分子标志物特征进行了剖析，在凝析油中检测到3-甲基甾烷，不含4-甲基甾烷，富含重排藿烷和C30^-未知萜烷．表明油源主要来自于二叠系源岩。柯克亚的天然气重烃含量高，属湿气，乙烷碳同位素偏重；天然气氩同位素和成熟度特征均指示混源气特征，通过气源判识天然气主要来源于石炭系一二叠系源岩，部分来源于侏罗系源岩。天然气的乙烷δ^13C值明显重于凝析油全油δ^13C值，揭示柯克亚地区凝析油和天然气分属不同来源。     

Levels and distributions of organic source tracers in air and roadside dust particles of Kuala Lumpur,Malaysia

The concentrations of n-alkanes, unresolved complex mixture (UCM), petroleum molecular markers, other tracers of cooking and burning emissions, and natural background in atmospheric particles and roadside dust particles were measured at eight locations in the city center and the suburbs of Kuala Lumpur, Malaysia. Atmospheric particles were collected using high-volume filtration (PM-10, GFF) over 24 h average periods. Road dusts were swept up, dried and sieved. Both types of samples were extracted with dichloromethane/methanol mixture (3:1 v/v) by ultrasonic agitation. The extracts were then fractionated by column chromatography and the alkanes subjected to gas chromatography–mass spectrometry (GC–MS). Total extracts were also analyzed directly by GC–MS after silylation. The molecular distributions of compounds as well as diagnostic geochemical ratios were determined in order to identify the sources of the organic compounds. Samples collected from a rural area and lubricating oils were also analyzed for comparisons. Anthropogenic and biogenic sources such as vehicular emissions, waxes of higher plants, food cooking operations, and biomass and domestic refuse burning processes contributed to the organic matter content of atmospheric and to lesser extent, roadside dust particles.     

浙江古田山自然保护区常绿阔叶林群落特征

在对古田山自然保护区森林植被广泛调查的基础上，详细分析了常绿阔叶林群落特征，从该区森林植被的外貌特征、群落结构和种类组成上看，均具有我国典型亚热带常绿阔叶林的基本性质。     

Russian behaviour in the market for permits under the Kyoto Protocol

After the US withdrawal from the Kyoto Protocol and the extension of national quotas in the Bonn and Marrakesh agreements, meagre environmental effects and a low price of emission permits are likely to be the outcome of implementation. This paper attempts to analyze this scenario, mainly in relation to the Russian case. I discuss on the basis of certain key assumptions the strategic options open to the supply side of the permit market and Russia’s potentially incompatible interests as a producer of oil and gas on the one hand and a dominating seller of emission permits under the Kyoto Protocol on the other. The analysis shows that Russian oil and gas interests are likely to boost Russia’s inclination to sell permits, ultimately resulting in lower permit prices.     

天然沸石在环保中的应用

天然沸石具有良好的离子交换性，吸附性及较好的催化性等性能，且资源丰富、价格低廉，在水处理、空气净化、放射性废物处理和抗菌剂的制备等环境保护与污染治理方面得到了广泛的应用。但目前我国天然沸石的开发利用总体水平还比较低，应加强各种天然沸石的成分，结构和性能研究，大力加强天然沸石的改型改性工艺技术研究，扩大天然沸石在环保中的应用范围。     

广西资源红辉沸石水热制备纳米微孔材料--沸石分子筛

利用广西红辉沸石资源水热制备纳米微孔材料——沸石分子筛，其工艺流程为“红辉沸石”(预处理) 氢氧化钠 铝酸钠 水→水热反应→晶化合成→过滤、洗涤、烘干→沸石分子筛产品。基于大量实验研究，确定了水热制备A型、P型和X型沸石的最佳工艺技术参数，制备出了质量较高的沸石分子筛产品，并综合分析了红辉沸石粒度、石英杂晶、晶化时间以及反应混合物组成对沸石分子筛水热制备的影响，指明了今后研究工作的努力方向。     

含水层地下储气库参数优化问题分析

讨论了灰色物元法在含水层储气库参数优化问题中的应用。天然气地下储气库的建造是一项大型、复杂、具有多目标性的工程项目,包括固定资产投资、钻井、修井、注采气工艺完善、地面建设等,需要上亿元的投资,因此其方案的确定,事关重大,必须在建设前期进行充分的技术和工程论证。地下储气库设计方案的优选需要考虑使用功能、技术性、经济性、安全性、环境影响等诸方面的效果进行综合论证,来确定最优方案。由于确定地下储气库优化设计指标类型的多样性,不相容性,且其量纲也不尽相同,甚至有些指标只能是定性描述的非量化灰数,这就导致地下储气库建造设计方案的优选是属灰色系统问题。利用灰色物元分析法优选储气库参数,可以使储气库的参数设计达到最佳。     

Insolation weathering and hygric dilatation: two competitive factors in stone degradation

In the natural environment, temperature and moisture are very important parameters in stone degradation. Therefore, on 28 samples from different lithologies (magmatic, metamorphic and sedimentary rocks) thermal and hygric expansion measurements were performed in order to constrain their behaviour related to environmental changes. It was shown that marbles, even those that are dolomitic, are sensitive to temperature impacts. For rocks with clay minerals the effect of temperature may be responsible for shrinking. Finally the amount of residual strain, i.e. the formation of microcracks due to temperature action controls the rate of stone degradation. For most sedimentary rocks no residual strain after heating was observed. In contrast to most magmatic and metamorphic low-porosity rocks, sedimentary rocks contain swelling minerals (like smectite and even phyllosilicates), which are very sensitive to hygric attacks. The cycles of wetting and drying, i.e. the natural environmental effects, may significantly control the deterioration velocity caused by hygric expansion.     

石漠化的成因机理与防治对策

从石漠化的研究现状出发，依据我国西南岩溶石山地区石漠化特征，着重分析其主要控制介质为岩性、构造、地貌、气候、岩溶、地下水、植被等自然介质因子与森林砍伐、高坡开垦等人为介质因子．石漠化是以岩溶山区脆弱的岩溶生态环境为基础，以内、外地质作用和人类恶性生态地质作用为驱动力，以资源退化和恶化为本质，基岩不断裸露，生态环境不断恶化，周而复始的恶性循环过程．提出对石漠化的研究重点是成固机理研究，对石漠化的防治应着重于对石漠化的驱动力及其主异因子的防治，阐述了治山必须先治水等防治对策与建议．