微波消解-电感耦合等离子体质谱法测定铁矿石中15个稀土元素

分析地质样品中稀土元素的含量,现有的方法都受到基体干扰和共存元素干扰,电感耦合等离子体质谱(ICP-MS)已在痕量元素分析中得到广泛应用,通过条件优化可准确测定稀土元素。本文建立了ICP-MS同时测定铁矿石中钇镧铈镨钕钐铕钆铽镝钬铒铥镱镥15个稀土元素的方法,样品用盐酸、硝酸和氢氟酸高温密闭消解,消解完全后转移定容,在线加入¹⁰³Rh、¹¹⁵In、¹⁸⁵Re内标液进行测定,方法回收率为95%~104%,精密度(RSD)≤3.5%。对12个国家24个代表性主产区进口的铁矿石样品进行检测,分析其稀土元素的配分模式特征为右倾型轻稀土富集,现阶段的进口铁矿粉多为多产区复合配矿。本方法较其他传统方法大幅降低能耗,提高了分析效率,初步探讨的稀土元素丰度特征可为研究主产区铁矿石的矿床成因、提高我国烧结球团矿的加工工艺提供依据。     

风化作用对铁陨石矿物学特征影响的探讨

本文对南丹IIICD铁陨石的矿物学特征进行了研究,并与同为铁陨石但化学分类不同的阿根廷IAB铁陨石和西伯利亚IIB铁陨石进行了对比,重点探讨了风化作用对铁陨石矿物学特征的影响.首先用偏光显微镜、静水称重、扫描电镜观察了样品的基本矿物学特征和微形貌特征,然后用振动式样品磁强计、X射线衍射与电子探针能谱半定量测试研究了样品的磁学性质、物相和化学组成.研究结果表明,南丹铁陨石在较强的自然风化作用下,光泽变弱为土状光泽,相对密度降低;风化产生的反铁磁性物质会使陨石的磁性下降;另外,样品表面物相组成也发生较大变化,以针铁矿(FeOOH)和磁铁矿(Fe₃O₄)等铁的次生矿物为主;但风化壳以下的矿物物相及化学成分均未发生明显变化,以Fe、Ni为主的铁纹石、镍纹石物相存在.     

长江中下游成矿带庐枞盆地小包庄铁矿床地质特征研究

罗河铁矿床位于长江中下游成矿带内庐枞火山岩盆地的西北部,是成矿带内已发现规模最大的铁矿床。2013年在罗河铁矿床深部又勘探新发现了小包庄大型铁矿床,这是长江中下游成矿带内近年来重大找矿突破之一,具有重要的理论研究意义和勘探应用价值。本文在前人工作基础上,基于详细的钻孔观察和系统的岩相学、矿相学工作并结合电子探针测试分析,研究了小包庄铁矿床的矿化蚀变特征,厘定了矿床的成矿阶段,分析了成矿作用过程,并初步探讨了矿床成因。研究表明,罗河铁矿床和小包庄铁矿床为同一成矿系统在不同深度成矿作用的产物。小包庄铁矿床主矿体矿呈厚大的透镜状、似层状产于砖桥组地层中,位于罗河铁矿床主矿体之下约800~1000m,主要由浸染状矿体组成。矿床中金属矿物主要为磁铁矿和黄铁矿,非金属矿物主要为硬石膏、透辉石和碳酸盐,矿石的代表性矿物组合为磁铁矿-硬石膏-透辉石。矿石的结构构造主要有浸染状构造、脉状构造、块状构造、自形-半自形粒状结构、他形粒状结构和筛状结构等。矿床围岩蚀变强烈,主要蚀变类型有碱性长石化、透辉石化、绿泥石化、绿帘石化、碳酸盐化和硬石膏化。小包庄铁矿床形成经历了热液期的四个阶段,即碱性长石阶段、透辉石-硬石膏-磁铁矿阶段、绿泥石-绿帘石-碳酸盐阶段和硬石膏-黄铁矿-碳酸盐-石英阶段,其中,铁矿化主要发育于透辉石-硬石膏-磁铁矿阶段。通过矿床地质特征的分析以及与宁芜地区铁矿床的对比研究,本文认为小包庄铁矿床成矿物质和成矿流体来源于深部的闪长质侵入岩(?),而矿化发育在远离侵入岩或次火山岩之上的火山岩中,明显有别于宁芜地区玢岩铁矿床,类似于智利安第斯成矿带中部分产于安山质火山岩中的磁铁矿-磷灰石型矿床,是长江中下游成矿带中产于火山岩中的一类特殊类型的玢岩型铁矿。     

Importance of hydrogeological conditions during formation of the karstic bauxite deposits,Central Guizhou Province,Southwest China: A case study at Lindai deposit

Karstic bauxite deposits are widespread in Central Guizhou Province, SW China, and high-grade ores are frequently sandwiched with overlying coal and underlying iron-rich layers and form a special “coal–bauxite–iron” structure. The Lindai deposit, which is one of the most representative karstic bauxite deposits in Central Guizhou Province, was selected as a case study. Based on textural features and iron abundances, bauxite ores in the Lindai deposit are divided into three types of ores, i.e., clastic, compact, and high-iron. The bauxite ores primarily comprise diaspore, boehmite, kaolinite, illite, and hematite with minor quartz, smectite, pyrite, zircon, rutile, anatase, and feldspar. The Al₂O₃ (53–76.8 wt.%) is the main chemical contents of the bauxite ore samples in the Lindai district, followed by SiO₂, Fe₂O₃, TiO₂, CaO, MgO, S, and P etc. Our geological data on the Lindai deposit indicated that the ore-bearing rock series and its underlying stratum have similar rare earth elements distribution pattern and similar Y/Ho, Zr/Hf, and Eu/Eu¹ values; additionally, all ore-bearing rock samples are rich in MgO (range from 0.16 wt.% to 0.68 wt.%), and the plots of the dolomites and laterites lie almost on or close to the weathering line fit by the Al-bearing rocks in Zr vs. Hf and Nb vs. Ta diagrams; suggesting that the underlying Middle Cambrian Shilengshui Formation dolomite is the parent rock of bauxite resources in the Lindai district.Simulated weathering experiments on the modern laterite from the Shilengshui Formation dolomite in the Lindai bauxite deposit show that hydrogeological conditions are important for karstic bauxite formation: Si is most likely to migrate, its migration rate is several magnitudes higher than those of Al and Fe under natural conditions; the reducing inorganic acid condition is the most conducive to Al enrichment and Si removal; Fe does not migrate easily in groundwater, Al enrichment and Fe removal can occur only in acidic and reducing conditions with the presence of organic matter.The geological and experimental studies show that “coal–bauxite–iron” structure in Lindai deposit is formed under certain hydrogeological conditions, i.e., since lateritic bauxite or Al-rich laterite deposited upon the semi-closed karst depressions, Si can be continuously removed out under neutral/acidic groundwater conditions; the coal/carbonaceous rock overlying the bauxitic materials were easily oxidized to produce acidic (H₂S, H₂SO₄, etc.) and reductant groundwater with organic materials that percolated downward, resulting in enrichment of Al in underlying bauxite; it also reduced Fe³⁺ to its easily migrating form Fe²⁺, moving downward to near the basal carbonate culminated in precipitating of ferruginous (FeS₂, FeCO₃, etc.) strata of the “coal–bauxite–iron” structure. Thus, the bauxitic materials experienced Al enrichment and Si and Fe removal under above certain hydrogeological conditions forming the high-quality bauxite.     

辽宁省本溪县杨家堡子金矿地质特征及成因浅析

本溪县杨家堡子金矿赋存于早古生代奥陶系马家沟组及寒武系凤山组内,矿体主要围岩为变质程度轻微的碎屑沉积岩及碳酸盐岩,矿体受断裂构造控制,金矿物及载金矿物——黄(褐)铁矿均呈稀疏浸染状分布,金成矿与燕山期二长花岗岩关系密切,具有"卡林型"金矿床地质特征。认为杨家堡子金矿是与早古生代寒武系、奥陶系地层、岩性、岩相(变质相)、断裂构造及燕山期岩浆活动有成因联系的金矿床,对矿体的矿物组合进行分析,初步确定矿化成因应属低温热液型金矿床。     

Mill-leach-waste cutoff grades for sulphidic copper ore

Summary Recent mining literature on cutoff grade theory has come to reflect some viewpoints and analyses expressed earlier in the economic literature. Agreement is best when the cutoff grade policy is established by analysis in stages, starting from the limits of the deposit, and using the maximum net present value objective. In the derivation of the optimal cutoff grade policy a dynamic programming approach is then applied to solve the overall problem as a series of linked, nonlinear, stage optimization problems. A wholly satisfactory use of a dynamic programming methodology requires that two conditions be satisfied: the separability and optimality conditions. The former is, strictly, violated by a heap-leaching or dump-leaching process, the latter by possible forms of resource rent taxation. This paper considers the problem of including such a leaching process in a cutoff grade policy analysis along aforementioned lines. It concludes that a workable method of doing so may be found which, in particular, may be quite satisfactory in arid climates where, in addition, some practical leaching experience already exists.     

早子沟金矿矿石质量特征、选矿试验研究及选别效果

本文依据早子沟金矿矿区勘查及选矿工艺矿物学研究资料,从金矿石的结构构造、矿石类型、矿物成分、金的赋存状态及其主要载体矿物的嵌布特征、共伴生组分等方面综述了矿石质量特征,重点分析了以上矿石质量特征要素对选矿的影响;简述了选矿试验研究的成果及选别效果。矿区矿石工艺类型属少硫化物微细粒浸染型含金矿石,金的赋存状态复杂,利用重选—浮选中矿再磨的重浮联合流程可获得较理想的选冶回收指标。     

巯基棉富集-光度法连续测定铬铁矿中的铂钯

在建立巯基棉富集-分光光度法联用系统的基础上,对螯合反应的pH、吸附酸度、显示剂用量、显色温度及体系稳定性等进行了优化选择,并将联用系统成功地应用于实际样品的富集分离分析。在盐酸介质中,α-呋喃二肟与钯得黄色络合物,于λmax=380nm处测定其吸光度,HSCT与铂反应生成2：1稳定络合物,于λmax=540nm处测定其吸光度,对Pt,Pd的检测限（3）分别为0．01μg／ml,0．005μg／ml,对国家一级标准物质进行验证,结果与标准值相符,加标回收率98．0％～102．5％,相对标准偏差为3．88％～8．97％。应用于实际样品的测定．结果满意。     

新疆塔什库尔干地区磁铁矿床地质特征与找矿方向

新疆塔什库尔干地区的磁铁矿床是河南省地质调查院2003年在实施1/25万克克吐鲁克幅、塔什库尔干幅、莎车幅区域地质调查过程中发现的,也是迄今为止新疆南部最大的磁铁矿床。该矿床产出的大地构造位置独特,成矿地质条件良好,找矿潜力很大。本文根据最新找矿勘查资料,通过对矿区地质、矿体及矿石组构特征等方面的综合分析研究,认为新疆塔什库尔干地区磁铁矿床是沉积变质型磁铁矿床,区内进一步的找矿方向为古元古界布伦阔勒群第二岩性段分布的向形(斜)核部。     

新疆大南湖北露天煤矿首采区Ⅲ火烧区地下水资源的数值模拟

大南湖北露天煤矿首采区东南部需要揭露Ⅲ火烧岩区一部分,这使得烧变岩水成为露天煤矿矿井充水的主要水源。资源勘探阶段的水文地质资料表明,烧变岩区赋水空间发育、透水能力强,储存量非常可观,但由于受资源勘探阶段水文地质勘探工程量制约,水文地质条件未能详细查明,现有水文地质成果尚不能满足首采区对烧变岩水疏排设计的要求。对烧变岩地下水资源进行模拟开采性抽水试验,获取Ⅲ火烧区的水文地质参数,利用数值模拟的方法,运用MODFLOW软件建立了III火烧区地下水数值模型,并模拟计算出了Ⅲ火烧区地下水储存量。经验证,本次模拟所取得成果与煤矿实际情况相符,能够作为首采区矿坑疏排水设计依据。