ENHANCING THE DECONVOLUTION OF NOISY CHROMATOGRAPHIC DATA BY JANSSON''S METHOD

In previous papers Jansson's method was found to be successful at deconvolving severely overlapped gaschromatographic peaks.In the most recent paper the method was evaluated with respect to quantitativeaceuracy,peak area and retention time repeatability.The problems associated with deconvolving noisydata and some alternatives which can improve the ability of Jansson's method to deconvolve noisy dataare discussed.These alternatives include presmoothing the data with a nine-point,third-order polynomialfilter and data reblurring.This paper will test these methods on peaks with various degrees of resolutionand signal-to-noise ratios.     

Calc-silicate reactions and bedding-controlled isotopic exchange in the Notch Peak aureole, Utah: implications for differential fluid fluxes with metamorphic grade

Fluid compositions and bedding‐scale patterns of fluid flow during contact metamorphism of the Weeks Formation in the Notch Peak aureole, Utah, were determined from mineralogy and stable isotope compositions. The Weeks Formation contains calc‐silicate and nearly pure carbonate layers that are interbedded on centimetre to decimetre scales. The prograde metamorphic sequence is characterized by the appearance of phlogopite, diopside, and wollastonite. By accounting for the solution properties of Fe, it is shown that the tremolite stability field was very narrow and perhaps absent in the prograde sequence. Unshifted oxygen and carbon isotopic ratios in calcite and silicate minerals at all grades, except above the wollastonite isograd, show that there was little to no infiltration of disequilibrium fluids. The fluid composition is poorly constrained, but X(CO₂)_fluid must have been >0.1, as indicated by the absence of talc, and has probably increased with progress of decarbonation reactions. The occurrence of scapolite and oxidation of graphite in calc‐silicate beds of the upper diopside zone provide the first evidence for limited infiltration of external aqueous fluids. Significantly larger amounts of aqueous fluid infiltrated the wollastonite zone. The aqueous fluids are recorded by the presence of vesuvianite, large decreases in δ¹⁸O values of silicate minerals from c. 16‰ in the diopside zone to c. 10‰ in the wollastonite zone, and extensive oxidation of graphite. The carbonate beds interacted with the fluids only along margins where graphite was destroyed, calcite coarsened, and isotopic ratios shifted. The wollastonite isograd represents a boundary between a high aqueous fluid‐flux region on its higher‐grade side and a low fluid‐flux region on its lower‐grade side. Preferential flow of aqueous fluids within the wollastonite zone was promoted by permeability created by the wollastonite‐forming reaction and the natural tendency of fluids to flow upward and down‐temperature near the intrusion‐wall rock contact.     

等厚薄互层时频特征的正演模拟

本文基于波动理论,利用深度域相移法对不同互层数、不同单层厚度的等厚薄互层进行正演模拟.采用广义S变换分析零偏移距地震道反射复合波的瞬时频谱.研究发现当单层厚度大于3/16波长时,等厚薄互层时域特征为中、高频等幅振荡,瞬时频谱为与单层厚度成反比的单一峰值梳状函数;当单层厚度小于3/16波长时,震源子波的有限带宽对瞬时频谱的高频频率峰有压制作用,导致等厚薄互层中部的时域振幅和频域最大幅度均为低值,薄互层的结构特征不易分辨,说明宽高频的震源子波是提高薄互层分辨能力的关键.此外,理论推导和实验分析均证明:当地层厚度大于1/8波长时,其峰值频率与薄互层单层厚度存在定量解析关系,这为等厚薄互层单层厚度定量预测提供了重要的技术手段.     

Testing and modeling of the state-dependent behaviors of rockfill material

Dense Tacheng rockfill material (TRM) exhibits strain softening and dilation during drained triaxial tests, and therefore, an adapted Rowe’s stress–dilatancy equation was proposed for TRM. This equation incorporates an internal state index related to the density and pressure, as well as the coefficient of particle breakage and rotation. The adapted Rowe’s stress–dilatancy equation indicates that the relationship between stress and dilatancy is not constant, but varies with density and pressure. This result is in agreement with TRM test data. A state-dependent model was established for TRM using generalized plasticity theory combined with the adapted Rowe’s stress–dilatancy equation. The model includes twelve constants calibrated using TRM test data from Group A, and this model was used to predict the strain softening and dilatancy behaviors of dense TRM. Furthermore, the model predictions were validated using test data from Group B. In summary, the model accurately represented the stress–strain and dilatancy behaviors of TRM over a wide range of densities and pressures.     

Coupling of two methods,waveform superposition and numerical,to model blast vibration effect on slope stability in jointed rock masses

Drilling and blasting is a major technology in mining since it is necessary for the initial breakage of rock masses in mining. Only a fraction of the explosive energy is efficiently consumed in the actual breakage and displacement of the rock mass, and the rest of the energy is spent in undesirable effects, such as ground vibrations. The prediction of induced ground vibrations across a fractured rock mass is of great concern to rock engineers in assessing the stability of rock slopes in open pit mines. The waveform superposition method was used in the Gol-E-Gohar iron mine to simulate the production blast seismograms based upon the single-hole shot vibration measurements carried out at a distance of 39 m from the blast. The simulated production blast seismograms were then used as input to predict particle velocity time histories of blast vibrations in the mine wall using the universal distinct element code (UDEC). Simulated time histories of particle velocity showed a good agreement with the measured production blast time histories. Displacements and peak particle velocities were determined at various points of the engineered slope. The maximum displacement at the crest of the nearest bench in the X and Y directions was 26 mm, which is acceptable in regard to open pit slope stability.     

南北地震带南段水平向地震动衰减特征

地震动衰减关系作为抗震救灾的重要依据,一直都是现代地震学研究的重点之一.本研究使用南北地震带南段区域2009—2016年共217个地震事件获得随震中距变化的水平向地震动峰值速度(PGV)和地震动峰值加速度(PGA)经验衰减关系,并计算场地响应.研究结果显示PGV衰减关系的拟合效果较PGA更好,两者的距离衰减系数会随事件矩震级增大呈线性减小;相较于大矩震级事件,中矩震级事件在近场可能产生较衰减关系理论值更大的PGV和PGA,同时衰减关系的拟合标准差会随事件矩震级的增大而减小.进行场地响应校正后的PGV和PGA更加符合经验衰减关系,PGA的场地响应影响较PGV更强但两者的趋势一致,并与该区域前人计算得到的地壳Qs值分布对应,表明地壳介质放大或压制地震波振幅和其传递地震波能量的能力是相关联的.本文结果一定程度上揭示了南北地震带南段的地震动强度衰减特征,为未来中国西南部的抗震减灾工作提供了重要的参考.     

Eminescu impact structure: Insight into the transition from complex crater to peak-ring basin on Mercury

Peak-ring basins represent an impact-crater morphology that is transitional between complex craters with central peaks and large multi-ring basins. Therefore, they can provide insight into the scale dependence of the impact process. Here the transition with increasing crater diameter from complex craters to peak-ring basins on Mercury is assessed through a detailed analysis of Eminescu, a geologically recent and well-preserved peak-ring basin. Eminescu has a diameter (∼125 km) close to the minimum for such crater forms and is thus representative of the transition. Impact crater size-frequency distributions and faint rays indicate that Eminescu is Kuiperian in age, geologically younger than most other basins on Mercury. Geologic mapping of basin interior units indicates a distinction between smooth plains and peak-ring units. Our mapping and crater retention ages favor plains formation by impact melt rather than post-impact volcanism, but a volcanic origin for the plains cannot be excluded if the time interval between basin formation and volcanic emplacement was less than the uncertainty in relative ages. The high-albedo peak ring of Eminescu is composed of bright crater-floor deposits (BCFDs, a distinct crustal unit seen elsewhere on Mercury) exposed by the impact. We use our observations to assess predictions of peak-ring formation models. We interpret the characteristics of Eminescu as consistent with basin formation models in which a melt cavity forms during the impact formation of craters at the transition to peak ring morphologies. We suggest that the smooth plains were emplaced via impact melt expulsion from the central melt cavity during uplift of a peak ring composed of BCFD-type material. In this scenario the ringed cluster of peaks resulted from the early development of the melt cavity, which modified the central uplift zone.     

Ground response analysis of Kanpur soil along Indo-Gangetic Plains

The present work deals with 1D and 2D ground response analysis and liquefaction analysis of alluvial soil deposits from Kanpur region along Indo-Gangetic plains. Standard penetration tests and seismic down hole tests have been conducted at four locations namely IITK, Nankari village, Mandhana and Bithoor at 1.5 m interval up to a depth of 30 m below the ground surface to find the variation of penetration blows and the shear wave velocity along the depth. From the selected sites undisturbed as well as representative soil samples have been collected for detailed soil classification. The soil profiles from four sites have been considered for 1D and 2D ground response analysis by applying the free field motions of three Himalayan earthquakes namely Chamba earthquake (M_w—5.1), Chamoli earthquake (M_w—6.4) and Uttarkashi earthquake (M_w—6.5). An average value of Peak Ground Acceleration (PGA) obtained from 1D and 2D analysis is considered for liquefaction analysis and post-liquefaction settlement. The excess pore water pressure ratio is greater than 0.8 at a depth of 24 m from ground surface for IITK, Nankari village, Bithoor sites. More than 50% of post liquefaction settlement is contributed by layers from 21–30 m for all sites. In general, the soil deposits in Kanpur region have silty sand and sand deposits and are prone to liquefaction hazards due to drastic decrease of cyclic resistance ratio (CRR) at four chosen sites in Kanpur.     

唐山地区基岩地震动峰值衰减特征研究

基于搜集的唐山地区的强震记录数据,采用考虑地震动峰值加速度、近距离和震级的三种衰减模型,然后利用数理统计回归的方法对这些模型的结果进行了对比和分析,获得了唐山地区基岩场地峰值加速度衰减关系.并用2012年5月28日的唐山4.8级地震对此衰减关系进行了验证.     

On the genesis of granite pits on top of the Shigujian Peak of the Dayangshan Mountain in Jinyun County, Zhejiang Province

On top of Shigujian Peak (1477 m a.s.l.) of the Dayangshan Mountain in Jinyun County, Zhejiang Province, large amounts of granite pits with diameters ranging from several dozens of centimeters to around one meter and depth from 10 cm to 45 cm are found on rock surface. These pits mainly appear on the NE and SE sides, and their drainage mouths are in the same direction. The identification results through micropolariscope and X-ray fluorescence spectrometer reveal that bedrock of pits is from middle to fine-grained moyite being apt to be weathered and modified. In Dayangshan region the annual mean temperature is 9.2℃ and annual precipitation is over 1700 mm. On the one hand, there always experiences a period of periglacial action with temperature oscillating near 0℃ for 4 months, i.e., from December to March next year. As a consequence, the freezing-thawing cycles may be remarkable to disintegrate the bedrock. On the other hand, the windward slope of Shigujian Peak meets typhoon of over force 10 on the Beaufort scale in summer, therefore, the blowing makes suspending sands or pebbles grind in swirling form. Based on field investigation and periglacial geomorphic theory, the pits on top of Shigujian Peak are attributed to freezing- thawing of periglacial action. Meanwhile, storm and strong wind accelerate the process. Observation shows that both the actions are still undergoing and variant directions of wind are the main cause for making different shapes of the pits. Because the top of Shigujian is 1500 m lower than the present snow line, some scholars considered that “glacial pothole” formed in the Quaternary is hard to work, even though in the Last Glacial Maximum (LGM).