Incorporating accumulated temperature and algorithm of snow cover calculation into the snowmelt runoff model

An accurate simulation of snowmelt runoff is of much importance in arid alpine regions. Data availability is usually an obstacle to use energy‐based snowmelt models for the snowmelt runoff simulation, and temperature‐based snowmelt models are more appealing in these regions. The snow runoff model is very popular nowadays, especially in the data sparse regions, because only temperature, precipitation and snow cover data are required for inputs to the model. However, this model uses average temperature as index, which cannot reflect the snowmelt simulation in the high altitude band. In this study, the snow runoff model is modified on the basis of accumulated active temperature. Snow cover calculation algorithm is added and is no longer needed as input but output. This makes the model able to simulate long‐time runoff and long‐time snow cover variation in every band. An examination of the improved model in the Manas River basin showed that the model is effective. It can reproduce the behaviour of the hydrology and can reflect the actual snow cover fluctuation. Copyright © 2012 John Wiley & Sons, Ltd.     

气侯变化背景下黑河上游春季融雪洪水预估研究

气候变暖将导致高山区冰冻圈加剧融化,一方面融水资源时空分布的不确定性增大;另一方面,融水洪水灾害发生的频度和强度也将发生改变。基于气象、水文数据和MODIS积雪覆盖数据,利用融雪径流模型(SRM),对1990—2012年共23年祁连山黑河札马什克控制区融雪期径流进行模拟与验证。结果表明：SRM在该流域具有较高的模拟精度（纳什系数为0.91),可用于分析和预估控制区径流强度变化。为此,采用黑河流域气温、降水降尺度数据,预估了未来气候变化背景下积雪范围变化及不同重现期洪水变化趋势。结果显示,与基准期相比,在RCP2.6、RCP4.5和RCP8.5情景下,最大积雪范围可减小3%~7%,且随着海拔升高,变化愈剧烈。RCP2.6情景下因气温和降水变化幅度较小,到21世纪末各重现期洪水强度保持在10%以内波动;RCP4.5情景下,各重现期洪水强度最高增大约20%;在RCP8.5情景下,各重现期洪水强度最高可增大超30%。相关分析结果显示,不同重现期洪水径流与气温和降水均具有较强相关性：重现期越长,洪峰与气温的相关性越大;重现期越短,洪峰与降水的相关性越大。通过预估气候变化背景下的融雪性洪水事件强度及重现期变化,有助于有效开展区域洪水风险管理、提高洪水资源的利用价值。     

Refinement of Phosphorus Determination in Quartz by LA‐ICP‐MS through Defining New Reference Material Values

The aim of this study was to improve the quality of laser ablation inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) determination of phosphorus in crystalline quartz. Over the last decade, the Geological Survey of Norway has routinely performed trace element determinations on quartz from both operating and potential quartz deposits by LA‐ICP‐MS. The determined phosphorus concentrations were, with but few exceptions, consistently within the range of 10 to 30 μg g^?1, results that seemed to be both too high and too consistent. The multi‐material calibration curve obtained from a suite of reference materials (NIST SRM 610, 612, 614, 1830, BAM No. 1 amorphous SiO₂ glass) did not define a precise regression line. Published phosphorus concentrations for the reference materials are poorly constrained and the observed dispersions along the multi‐material calibration curve suggest that some of the reference values may be inaccurate. Furthermore, the calibration curve did not pass through the origin of the [(cps ³¹P/cps ³⁰Si) · cone. Si] vs. P concentration diagram; thus, in addition to the uncertainties of the literature values of phosphorus, it is difficult to define the calibration curve. Three reference materials (NIST SRM 614, 1830, synthetic quartz KORTH) were sent for phosphorus accelerator implantation, providing an independent and accurate (± 3%) approach for determining phosphorus concentrations in crystalline quartz. The intrinsic phosphorus concentrations of the three implanted samples plus those for NIST SRM 610 and 612 were determined by secondary ion mass spectrometry (SIMS), yielding new phosphorus values for NIST SRM 610, 612, 614 and 1830. Using these new values resulted in a better defined LA‐ICP‐MS calibration curve. However, the source of the ICP‐MS related background could not be defined, such that it must still be empirically corrected for.     

Calcium Isotopic Composition of Various Reference Materials and Seawater

A compilation of δ^44/40Ca (δ^44/40Ca) data sets of different calcium reference materials is presented, based on measurements in three different laboratories (Institute of Geological Sciences, Bern; Centre de Géochimie de la Surface, Strasbourg; GEOMAR, Kiel) to support the establishment of a calcium isotope reference standard. Samples include a series of international and internal Ca reference materials, including NIST SRM 915a, seawater, two calcium carbonates and a CaF₂ reference sample. The deviations in δ^44/40Ca for selected pairs of reference samples have been defined and are consistent within statistical uncertainties in all three laboratories. Emphasis has been placed on characterising both NIST SRM 915a as an internationally available high purity Ca reference sample and seawater as representative of an important and widely available geological reservoir. The difference between δ^44/40Ca of NIST SRM 915a and seawater is defined as -1.88 O.O4%o (δ^44/42Ca_{NISTSRM915a/Sw}= -0.94 0.07%o). The conversion of values referenced to NIST SRM 915a to seawater can be described by the simplified equation δ^44/40Ca_Sa/Sw=δ^44/40Ca_{Sa/NIST SRM 915a} - 1.88 (δ^44/42Ca_Sa/Sw=δ^44/42Ca_{Sa/NIST SRM 915a} - 0.94). We propose the use of NIST SRM 915a as general Ca isotope reference standard, with seawater being defined as the major reservoir with respect to oceanographic studies.     

激光剥蚀-电感耦合等离子体质谱准确测定锆石中钛的含量

外标物质及内标元素的选择是激光剥蚀-电感耦合等离子体质谱(LA-ICP-MS)准确测定元素含量的关键因素之一。文章选用玻璃标准参考物质NIST 610、GSE-1G、BHVO-2G、BCR-2G、ATHO-G、KL2-G和T1-G作为外标,Si或Zr作为内标,对锆石M257中的Ti进行LA-ICP-MS微区原位测定。结果显示,选择Si或Zr作内标,采用BCR-2G、ATHO-G、KL2-G和T1-G作外标时,Ti含量测定值与参考值之间差异均较大,因此它们不适合作外标物质。采用BHVO-2G作外标和Si作内标,NIST 610作外标和Zr作内标,Ti含量测定值与参考值之间的差异均小于4%,因此BHVO-2G和NIST 610可有条件地作为外标物质。选择Si还是Zr作内标,GSE-1G作外标时,Ti含量的测定值与参考值之间的差异均小于3%,说明GSE-1G是较为合适的外标物质。选用GSE-1G作为外标,Si作内标,对5个标准锆石中的Ti含量进行了测定,结果显示,Ti元素在锆石91500中分布不均匀,而在锆石GJ-1、M257、PENGLAI和MUDTANK中分布均匀。在Ti元素分布均匀的GJ-1、M257、PENGLAI和MUDTANK等4个锆石中,由于Ti的含量均小于5μg/g,不适合作为锆石中Ti元素测定用的外标物质,但可作为测定时的质量监控样品。     

A Rapid Method for Determining Boron Concentration (ID‐ICP‐MS) and δ11B (MC‐ICP‐MS) in Vegetation Samples after Microwave Digestion and Cation Exchange Chemical Purification

We present in this article a rapid method for B extraction, purification and accurate B concentration and δ¹¹B measurements by ID‐ICP‐MS and MC‐ICP‐MS, respectively, in different vegetation samples (bark, wood and tree leaves). We developed a rapid three‐step procedure including (1) microwave digestion, (2) cation exchange chromatography and (3) microsublimation. The entire procedure can be performed in a single working day and has shown to allow full B recovery yield and a measurement repeatability as low as 0.36‰ (± 2s) for isotope ratios. Uncertainties mostly originate from the cation exchange step but are independent of the nature of the vegetation sample. For δ¹¹B determination by MC‐ICP‐MS, the effect of chemical impurities in the loading sample solution has shown to be critical if the dissolved load exceeds 5 μg g^?1 of total salts or 25 μg g^?1 of DOC. Our results also demonstrate that the acid concentration in the sample loading solution can also induce critical isotopic bias by MC‐ICP‐MS if chemistry of the rinsing‐, bracketing calibrator‐ and sample solutions is not thoroughly adjusted. We applied this method to provide a series of δ¹¹B values of vegetal reference materials (NIST SRM 1570a = 25.74 ± 0.21‰; NIST 1547 = 40.12 ± 0.21‰; B2273 = 4.56 ± 0.15‰; BCR 060 = ?8.72 ± 0.16‰; NCS DC73349 = 16.43 ± 0.12‰).     

超导岩样磁力仪的研制

超导岩样磁力仪是以超导量子干涉器（SQUID）为磁传感器用来测量岩样剩磁的仪器,是研究岩石磁学和古地磁学的重要手段。它比常规的古地磁仪器--无定向磁力仪、旋转磁力仪具有灵敏度高、响应时间短、动态范围大、又可三分量同时测量等优点,满足了弱磁岩样测量的要求。本文叙述了超导测磁的理论基础,仪器的组成,原理,研制情况及实测结果。     

Boron Isotopic Analysis of Proposed Borosilicate Mineral Reference Samples

This brief contribution presents new boron isotopic data for a set of proposed borosilicate reference minerals, most of which are described in the companion paper by Dyar et al.²⁰⁰¹. The results for a variety of minerals (tourmalines, danburite, prismatine, serendibite, ferroaxinite and a Li mica) show that it is generally possible to reproduce the ¹¹ B/¹⁰ B ratio within ± 0.5 per mil with replicate chemistry and mass spectrometry over long time spans. Because the accuracy of boron isotopic analysis is commonly determined by reference to secondary standards, it is suggested that some of the samples used in this study be adopted for interlaboratory comparisons and for quality control on boron isotopic analyses produced by a variety of analytical methods.     

Proposal for International Agreement on Ca Notation Resulting from Discussions at Workshops on Stable Isotope Measurements Held in Davos (Goldschmidt 2002) and Nice (EGS-AGU-EUG 2003)

A proposal is made to standardise the reporting of Ca isotope data to the δ⁴⁴Ca/⁴⁰Ca notation (or δ⁴⁴Ca/42Ca) and to adopt NIST SRM 915a as the reference standard.     

虎跳峡龙蟠右岸土石混合体粒度分形特征研究

应用分维理论对虎跳峡龙蟠右岸分布的土石混合体粒度分布的分维规律进行了研究分析,建立了平均粒径与相应的分维数之间的定量关系模型。通过研究表明,土石混合体具有良好的统计自相似性,由于其本身为级配不良土,在分维曲线上表现为双重分形分布,这种特殊的分维分布与土石混合体的成因及形成过程有关。