碳棒涂膜式PVC膜铯离子选择电极的研制和应用

本文作者研制成功以四苯硼铯为活性物质的碳棒涂膜式PVC膜铯离子选择性电极。电极最佳膜组成:四苯硼铯5mg,邻苯二甲酸二丁酯0.4ml,硝基苯0.2ml,PVC粉0.2g。电极性能优良,制作简单,操作方便。结合大粒度磷钼酸铵和结晶形锑酸分离K~+,Na~+,巳将此电极用于卤水样中铯的测定,结果令人满意。     

金在表生条件下溶解,迁移和沉淀的探讨

金矿物在表生条件下溶解为离子金.离子金与表生络合剂结合成金络离子团迁移.在物化条件改变时,由于有机炭、粘土矿物及带异性电荷胶体吸附,使金络离子团分解成原子金沉淀.     

离子色谱—双电导法同时测定水样中多种阴离子的研究

本文在Dionex2020i离子色谱仪上,选用0.61×10~(-3)mol/L NaHCO_3-1.61×10~(-3)mol/LNa_2CO_3水溶液作淋洗液,在HPIC-AS4A阴离子分离柱上分离痕量F~-、NO_2~-、Br~-和较高浓度的Cl~-、NO_3~-、SO_4~(2-);选用2.0×10~(-3)mol/L TBAOH-6％CH_3CN水溶液作淋洗液,在MPIC-NS1分离柱上分离痕量F~-、Br~-和较高浓度的Cl~-,然后用串联双电导检测器的不同输出范围分别同时定量测定。本法特别适用于相邻两种离子浓度相差较大,前面高含量的离子对后面痕量离子测定有干扰的样品。用本文拟定的HPIC方法测定除铬后的地下水样中多种阴离子的结果与文献值吻合。     

固态萃取光度法测定痕量钛

本文采用熔融联苯萃取8-羟基喹啉钛,继后溶固相于N,N-二甲基甲酰胺中,在390nm处测量吸光度。实验确定了各参数的最佳值,其摩尔吸光系数为7.9×10~3L·mol~(-1)·cm~(-1),一些干扰元素可以掩蔽。方法迅速、简便,用于测定铍铜合金中的痕量Ti,所得结果令人满意.     

Circulation and water masses of the Arabian Sea

The dynamics and thermodynamics of the surface layer of the Arabian Sea, north of about 10N, are dominated by the monsoon-related annual cycle of air-sea fluxes of momentum and heat. The currents in open-sea regime of this layer can be largely accounted for by Ekman drift and the thermal field is dominated by local heat fluxes. The geostrophic currents in open-sea subsurface regime also show a seasonal cycle and there is some evidence that signatures of this cycle appear as deep as 1000 m. The forcing due to Ekman suction is an important mechanism for the geostrophic currents in the central and western parts of the Sea. Recent studies suggest that the eastern part is strongly influenced by the Rossby waves radiated by the Kelvin waves propagating along the west coast of India. The circulation in the coastal region off Oman is driven mainly by local winds and there is no remotely driven western boundary current. Local wind-driving is also important to the coastal circulation off western India during the southwest monsoon but not during the northeast monsoon when a strong (approximately 7 × 10⁶m³/sec) current moves poleward against weak winds. This current is driven by a pressure gradient which forms along this coast during the northeast monsoon due to either thermohaline-forcing or due to the arrival of Kelvin waves from the Bay of Bengal. The present speculation about flow of bottom water (deeper than about 3500 m) in the Arabian Sea is that it moves northward and upwells into the layer of North Indian Deep Water (approximately 1500–3500m). It is further speculated that the flow in this layer consists of a poleward western boundary current and a weak equatorward flow in the interior. It is not known if there is an annual cycle associated with the deep and the bottom water circulation.     

人工合成硅灰石的发光性质与发光机理的初步研究

在２５４ｎｍ紫外光照激发条件下，对人工合成掺入不同激活离子的低温ＴＣ型和高温型假硅灰石的发光性质进行了实验测定，从微观原子能量谱项讨论了在全的硅灰石基质中Ｅｕ＾３＋和Ｇｄ＾３＋的发光机理，分析了Ｂｉ＾３＋对Ｅｕ＾３＋与Ｐｂ＾２＋对Ｍｎ＾２＋的敏化发光条件，初步探讨了掺放Ｅｕ＾３＋的高温型假硅灰石发光强度减弱的原因。     

离子交换与吸附研究方法

综合文献资料，结合本人研究实践，对离子交换与吸附研究的一些方法做专门介绍．     

线性规划在徐州地下水资源开发中的应用

本文从地下水系统的观点出发,对徐州地区中寒武统—中奥陶统碳酸盐岩地下水系统进行了分析。并应用线性规划的原理和方法对徐州市西郊四个水源地地下水进行了水文地质计算。在规定水位允许降深的约束条件下,求得至2000年,该区地下水最大开采量为14万米~3/天及各水源地相应取水量的最佳分配。文中采用特定条件图解法计算多边界、多主井抽水干扰影响的方法,具有通用意义。     

Aspects of the cycle of inorganic nitrogen compounds in the tropical rain forest of the Ivory Coast

A partial balance of mineral N is given for the basins of two coastal rivers in a forest zone in the Ivory Coast. The dry and wet depositions on the basin surfaces is given for particulate matter (NO₃ ^–, NH₄ ⁺). The quantity of mineral N washed away in the rivers is evaluated. The losses from leaching of the soils by rainwater are about 0.33 to 1.0% of the atmospheric depositions for NH₄ ⁺–N and 2.2 to 5.8% for NO₃ ^––N. The yearly atmospheric input of N compounds to the ecosystem, about 1.4 g N m^–2 y^–1, is at least 14% of mineral N formed in the soils and is therefore quite significant.     

离子刻蚀全息光栅的研究

利用国产的光刻胶和国产离子刻蚀机在蒸镀的铝基衬底上进行刻蚀全息光栅,在国内是一项较新的技术。本文介绍和论述了该试验工作的工艺过程、参数计算和测试方法,得出了试验结果和参数计算值基本吻合的结论,并指出了进一步改善质量的方向。