流动注射-光度法测定地质样品中痕量碘

利用I~-对4,4′-四甲基二氨基二苯甲烷(4,4′-TMB-DPM)与氯胺T反应的催化作用,建立了流动注射-分光光度测定地质样品中痕量碘的方法。采用不等流速合并带法,分析速度快、节省试剂、灵敏度高。与高温水解法释放I~-相结合,使样品处理简单、干扰离子少。对于含I~-10μg/L的水样,其RSD(n=19)为1.1％,检出限为0.3ng/ml。用于水系沉积物、土壤分析时,含碘1.6×10~(-6)的样品RSD(n=10)为6.1％,检出限为0.08×10~(-6)。测量速度50N/h。     

南海东北部洋陆过渡区域地震折射波衰减特征

地震波衰减研究是了解岩石圈构造特征的有效方法.本文基于OBS2016-2测线的海底地震仪(OBS)数据, 首次对南海东北部洋陆过渡区域地震波衰减特征进行研究, 通过正演模拟获得该区域二维纵波衰减(Q_P)结构.结果表明, 下陆坡的上地壳存在一个宽约40 km, 厚度约为4~5 km的高衰减区, 其特征为低纵波和横波速度(V_P为5.5~6.3 km·s^-1和V_S为3.1~3.6 km·s^-1)以及较低的波速比(V_P/V_S为1.72~1.80), 对应较低的Q_P(280~410), 推测与断裂发育有关, 且受到火山活动的影响.洋陆过渡及洋壳区域的上地壳高衰减区具有低Q_P(300~400)和高V_P/V_S(1.90~1.96)特征, 可能对应较多的断裂发育及流体运移.洋陆过渡区域下地壳高速异常体表现为相对低的Q_P(550~600), 对应较高的V_P(7.0~7.8 km·s^-1)和V_S(3.5~3.8 km·s^-1)以及较高的V_P/V_S(1.85~1.96), 推测与蛇纹石化作用有关.蛇纹石化可能进一步增加岩石的孔隙度并导致更多的流体运移, 使得洋陆过渡及洋壳区域存在较高的地震波衰减.Q_P结构有助于我们分析南海大陆边缘的地震波衰减特征, 结合V_P、V_S以及V_P/V_S, 可以更好地了解该区域地质结构和岩石属性, 对进一步挖掘OBS数据信息有重要参考价值.

     

Whether human-induced activities could change the gradient pattern of coastal land use along the sea-land direction: a case study in Manila Bay,Philippines

Increasing intense human activities have largely changed the coastal landscape and caused many environmental issues. However, whether human-induced activities could change the coastal land use gradient pattern, an important coastal zonal characteristic along the sea–land direction, remains unclear. Manila Bay was selected as the study area in this work. According to the distance of the land use and land cover(LULC) to the coastline, we clustered the typical coastal land use sequence patterns(CLU...     

基于潜标观测的黑潮-亲潮混合区近惯性能量季节变化特征研究

近惯性内波广泛存在于全球海洋,是维持深层海洋跨等密度面湍流混合及海洋层结的重要能量来源。基于黑潮-亲潮混合区的多年深海潜标数据,分析了:(1)该海域近惯性内波及其能量的季节变化特征与影响因素,(2)上层和深层近惯性运动的频率、波数谱及垂向分布等特征。结果表明,该海域存在丰富的近惯性动能,无论海洋上层还是深层均呈现显著的冬季强、夏季弱的季节变化特征,冬季(12～2月)上层的近惯性能量可占全年能量的41%,深层近惯性信号同样显著,同潮汐信号相当。平板模型分析表明,该区域近惯性动能的季节循环特征主要受风场的季节变化所主导,同时受到黑潮延伸体流轴的摆动调制。     

A probability distribution for depth-limited extreme wave heights in a sea state

A model for the depth-limited distribution of the highest wave in a sea state is presented. The distribution for the extreme wave height is based on a probability density function (pdf) for depth-limited wave height distribution for individual waves [Méndez, F.J., Losada, I.J., Medina, R. 2004. Transformation model of wave height distribution. Coastal Eng, Vol. 50, 97:115.] and considers the correlation between consecutive waves. The model is validated using field data showing a good representation of the extreme wave heights in the surf zone. Some important statistical wave heights are parameterized obtaining useful expressions that can be used in further calculations.     

Sub-seismic scale fracture pattern and in situ permeability data in the chalk atop of the Krempe salt ridge at Lägerdorf, NW Germany: Inferences on synfolding stress field evolution and its impact on fracture connectivity

Chalk is exposed in the Heidestrasse quarry at Lägerdorf, at the top of the NE-SW trending Krempe salt ridge. Structural data indicate the presence of two joint sets, striking almost parallel and perpendicular to the salt ridge, respectively, and of a set of conjugate extensional faults and fault zones striking NW-SE, i.e. almost perpendicular to the salt ridge. Within the overall NW-SE trend of joints and faults, strike variations occur from the massive chalk exposed in the lower half of the quarry, to the overlying layered chalk. A large variability characterizes the normalized spacing of both joint sets, which does not show any clear trend with layer dip. In situ measurements indicate that the cross-sectional permeability of tight joints increases 1-2 orders of magnitude with respect to the undeformed chalk. We propose that joint and fault azimuthal variability resulted from changes through time of the stress ellipsoid at the top of the salt ridge, while joint spacing variability is associated with the weak mechanical influence of bedding in chalk. Azimuthal variability improves fracture connectivity and, hence, permeability and fluid flow.     

Heat flow pattern, base of methane hydrates stability zones and BSRs in Shenhu Area, northern South China Sea

Using the collected 433 heat flow values, we estimated the bases of methane hydrate stability zone (BHSZ), in northern South China Sea (NSCS). Through comparing BHSZs with the depths of bottom simulating reflectors (BSRs), in Shenhu Area (SA), we found that there are big differences between them. In the north of SA, where the water depth is shallow, many slumps developed and the sedimentation rate is high, it appears great negative difference (as large as -192%). However, to the southeast of SA, where the water depth is deeper, sedimentation rate is relatively low and uplift basement topography exists, it changes to positive difference (as large as +45%). The differences change so great, which haven’t been observed in other places of the world. After considering the errors from the process of heat flow measurement, the BSR depth, the relationship of thermal conductivity with the sediments depth, and the fluid flow activities, we conclude that the difference should be not caused by these errors. Such big disagreement may be due to the misunderstanding of BSR. The deviant “BSRs” could represent the paleo-BSRs or just gas-bearing sediment layers, such as unconformities or the specific strata where have different permeability, which are not hydraterelated BSRs.     

中国北方砂栖纤毛虫的空间分布及其驱动因素

为深入了解不同地理尺度因素对驱动微型生物群落空间结构的相对影响,本研究于2020年10月调查了中国北方14个砂质潮间带的砂栖纤毛虫群落。研究结果如下：（1）检获纤毛虫105种,隶属26目65属,按丰度优势依次为帆口目、小胸目和环毛目;（2）黄海、渤海两区域的环境因子存在显著差异,但纤毛虫群落组成趋于相似;（3）偏Mental分析显示,环境条件较空间距离在纤毛虫群落组成的驱动中更为重要,其中盐度、粒度和海滩坡度是解释纤毛虫空间分布的最优环境因子组合,而潮差和溶解无机氮含量是次要影响因子;（4）沿海区域微型生物的强扩散效应在一定程度上掩盖了环境异质性影响。综上,由于沿海生态系统中微型生物受到更少扩散限制,在空间分布格局的形成上,环境条件的影响比空间距离更重要。本研究为海洋微型生物地理学提供了基础数据,有助于在全球变化背景下制定沙滩管理和保护规划。     

正韵律厚油层剩余油的水平井开发技术研究

与直井相比,水平井开发具有缩短油井井距,扩大泄油面积,提高临界锥流量,更好地控制注入流体、改善波及效率等优势。在相同采液量的情况下,水平井可以降低采液强度,减缓含水上升速度。特高含水期河流相储集层的顶部是剩余油富集区,利用水平井技术挖掘正韵律厚油层顶部剩余油,取得了很好的开发效果,最终采收率较直井开发提高了14个百分点。