Lithium isotope fractionation in the southern Cascadia subduction zone

We present lithium (Li) abundances and isotope compositions for a suite of anhydrous olivine tholeiites (HAOTs) and hydrous basalt-andesitic (BA) lavas from the Mt. Shasta and Medicine Lake regions, California. The values of δ⁷Li vary from + 0.9‰ to + 6.4‰ and correlate inversely with distance from the trench. These data are consistent with continuous isotope fractionation of Li during dehydration of the subducted oceanic lithosphere, an interpretation corroborated by uniformly high pre-eruptive H₂O contents in basaltic andesites accompanied by high Li, Rb, Sr, Ba and Pb abundances. The subduction-derived component that was added to these hydrous magmas is shown to be very similar beneath both Mt. Shasta and Medicine Lake volcanoes despite characteristically distinct Li isotope compositions in the magmas themselves. More evolved andesites and dacites from Mt. Shasta have δ⁷Li from + 2.8 to + 6.9‰ which is identical with the range obtained for HAOTs and BA lavas from Mt. Shasta. Therefore, Li isotopes do not provide evidence for any other crustal component admixed to Mt. Shasta andesites or dacites during magmatic differentiation and magma mixing in the crust.     

High precision locations of LP events on Mt. Etna: Reconstruction of the fluid-filled volume

During 1991–93 at Mount Etna, long-period (LP) events occurring in swarms characterized the evolution of the eruption. The presence of multiplets i.e. groups of events with similar waveform signatures, has been recognized within this activity. Traditional techniques for locating LP events do not allow obtaining reliable hypocenters, which have only succeeded in placing earthquakes in a roughly 1 km² area slightly east of the Mt. Etna Northeast Crater. Hypocenters have been relocated in two steps: the absolute location has been improved using Thurber’s code and a complex 3D velocity model; a highly precise relative location has been applied on multiplets to define the source geometry. 3D locations and high precision analysis suggest that during the 1991–93 eruption the resonator producing LP events was a part of the uppermost Northeast Crater conduit, measuring 210 meters in height and 45–50 meters in diameter.     

Geology, mineralogy, and PGE mineralization of the copper-nickel occurrences of the Kvinum ore field, Sredinny Range, Kamchatka

The geology and mineralogy of host metamorphic rocks, the mineralogy of sulfide ores, and the distribution of PGE mineralization were studied in detail for the Kvinum-1 and Kvinum-2 copper-nickel occurrences of the Kvinum ore field, which are the most promising targets for the copper-nickel-PGE mineralization of the Sredinny Range of Kamchatka. It was established that stringer-disseminated and massive copper-nickel ores are localized in amphibole peridotites, cortlandites, and form ore bodies varying from tens of centimeters to 5–20 m thick among the layered cortlandite-gabbroid massifs. The massive sulfide ores were found only at the bottom of cortlandite bodies and upsection grade into stringer-disseminated and disseminated ores. Pyrrhotite, chalcopyrite, and pentlandite are the major ore minerals with a sharply subordinate amount of pyrite, sphalerite, galena, arsenopyrite, and löllingite. Besides pentlandite, the Ni-bearing minerals include sulforasenides (gersdorffite), arsenides (nickeline), and tellurides (melonite) of nickel. It was found that PGE mineralization represented by antimonides (sudburyite) and tellurobismuthides (michenerite) of Pd with sharply subordinate platinum arsenide (sperrylite) is confined to the apical parts of massive sulfide zones and the transition zone to the stringer-disseminated ores. Ore intervals enriched in arsenides and tellurides of Ni, Pd, and Bi contain high-purity gold. In the central parts of the orebodies, the contents of PGE and native gold are insignificant. It is suggested that the contents of major sulfide minerals and the productivity of PGE mineralization in the cortlandites are defined by combined differentiation and sulfurization of ultramafic derivatives under the effect of fluids, which are accumulated at the crystallization front and cause layering of parental magmas with different sulfur contents. The fluid-assisted layering of mafic-ultramafic massifs resulted in the contrasting distribution of PGM in response to uneven distribution of sulfur (as well as As, Te, and Bi) during liquid immiscibility. The productivity of PGE mineralization significantly increases with increasing contents of S, As, Te, and Bi (elements to which Pt and, especially, Pd have high affinity) in fluids.     

Geology of the Acropolis prospect,South Australia,constrained by high-precision CA-TIMS ages

Abstract

Acropolis is an Fe-oxide–copper–gold prospect ～20?km from Olympic Dam, South Australia, and marked by near-coincident gravity and magnetic anomalies. Prospective Fe-oxide–apatite?±?sulfide veins occur in Mesoproterozoic and Paleoproterozoic volcanic and granitoid host units beneath unmineralised sedimentary formations. We have produced a geological map and history of the prospect using data from 16 diamond drill holes, including LA-ICPMS and high-precision CA-TIMS ages. The oldest unit is megacrystic granite of the Donington Suite (ca 1850?Ma). A non-conformity spanning ca 250 My separates the Donington Suite and felsic lavas and ignimbrites of the Gawler Range Volcanics (GRV; 1594.03?±?0.68?Ma). The GRV were intruded by granite of the Hiltaba Suite (1594.88?±?0.50?Ma) and felsic dykes (1593.88?±?0.56?Ma; same age as the Roxby Downs Granite at Olympic Dam). The felsic dykes are weakly altered and lack Fe-oxide–apatite–sulfide veins, suggesting that they post-date the main hydrothermal event. If correct, this relationship implies that the main hydrothermal event at Acropolis was ca 1594?Ma and pre-dated the main hydrothermal event at Olympic Dam. The GRV at Acropolis are the same age as the GRV at Olympic Dam and ca 3–7 My older than the GRV exposed in the Gawler Ranges. The gravity and magnetic anomalies coincide with sections through the GRV, Hiltaba Suite and Donington Suite that contain abundant, wide, Fe-oxide veins. The GRV, Hiltaba Suite and Donington Suite are unconformably overlain by the Mesoproterozoic Pandurra Formation or Neoproterozoic Stuart Shelf sedimentary formations. The Pandurra Formation shows marked lateral variations in thickness related to paleotopography on the underlying units and post-Pandurra Formation pre-Neoproterozoic faults. The Stuart Shelf sedimentary formations have uniform thicknesses.

1. KEY POINTS

2. Fe-oxide–apatite?±?sulfide veins are hosted by the Gawler Range Volcanics (1594.03?±?0.68?Ma), the Hiltaba Suite granite (1594.88?±?0.50?Ma) and Donington Suite granite (ca 1850?Ma).

3. The age of felsic dykes (1593.88?±?0.56?Ma) interpreted to be post-mineralisation implies that the main hydrothermal event at Acropolis was ca 1594?Ma.

4. The Gawler Range Volcanics at Acropolis are the same age as the Gawler Range Volcanics at Olympic Dam and ca 3 to 7 My older than the Gawler Range Volcanics exposed in the Gawler Ranges.

     

Footwall dip of a core complex detachment fault: thermobarometric constraints from the northern Snake Range (Basin and Range,USA)

Low‐angle detachment faults are common features in areas of large‐scale continental extension and are typically associated with metamorphic core complexes, where they separate upper plate brittle extension from lower plate ductile stretching and metamorphism. In many core complexes, the footwall rocks have been exhumed from middle to lower crustal depths, leading to considerable debate about the relationship between hangingwall and footwall rocks, and the role that detachment faults play in footwall exhumation. Here, garnet–biotite thermometry and garnet–muscovite–biotite–plagioclase barometry results are presented, together with garnet and zircon geochronology data, from seven locations within metapelitic rocks in the footwall of the northern Snake Range décollement (NSRD). These locations lie both parallel and normal to the direction of footwall transport to constrain the pre‐exhumation geometry of the footwall. To determine P–T gradients precisely within the footwall, the ΔPT method of Worley & Powell (2000) has been employed, which minimizes the contribution of systematic uncertainties to thermobarometric calculations. The results show that footwall rocks reached pressures of 6–8 kbar and temperatures of 500–650 °C, equivalent to burial depths of 23–30 km. Burial depth remains constant in the WNW–ESE direction of footwall transport, but increases from south to north. The lack of a burial gradient in the direction of footwall transport implies that the footwall rocks, which today define a sub‐horizontal datum in the direction of fault transport, also defined a sub‐horizontal datum at depth in Late Cretaceous time. This suggests that the footwall was not tilted about the normal to the fault transport direction during exhumation, and hence that the NSRD did not form as a low‐angle normal fault cutting down through the lower crust. Instead, the following evolution for the northern Snake Range footwall is proposed. (i) Mesozoic contraction caused substantial crustal thickening by duplication and folding of the miogeoclinal sequence, accompanied by upper greenschist to amphibolite facies metamorphism. (ii) About half of the total exhumation was accomplished by roughly coaxial stretching and thinning in Late Cretaceous to Early Tertiary time, accompanied by retrogression and mylonitic deformation. (iii) The footwall rocks were then ‘captured’ from the middle crust along a moderately dipping NSRD that soled into the middle crust with a rolling‐hinge geometry at both upper and lower terminations.     

黄山不同高度雨滴谱的演变特征

选取2011年6月黄山地区一次降水过程,利用测得的雨滴谱资料对不同高度上降水微物理量及雨滴谱分布特征进行分析,并讨论其中的差异。结果表明:此次降水较强,各直径微物理量在山腰最大、山底次之、山顶最小;山腰的雨强最大,而山顶数浓度最大。在雨滴谱分布中,小于1mm的雨滴数密度是山顶大于山腰大于山底,这与小雨滴的蒸发和碰并有关;大于1.5 mm的雨滴数密度则是山腰大于山顶和山底,这可能与地形抬升使得云系加强有关。由各微物理量的时间序列可将降水过程分为两个阶段,第一阶段各微物理量值明显大于第二阶段,其中第一阶段的降水量约为第二阶段的3倍。雨强与雷达反射率、数浓度、最大直径近似成幂函数关系,其中雨强与雷达反射率相关性最好。     

小兴安岭东南部伊春中生代花岗岩的锆石U-Pb测年及其地质意义

本文首次报道了小兴安岭南部伊春地区的五三零、南岔三林场及寒月林场岩体高精度锆石LA-ICP-MS U-Pb年龄。三个岩体均形成于早侏罗世,侵位年龄分别为175±3 Ma,180±2 Ma和195±2 Ma。岩石学和地球化学特征显示,这些岩体为高硅富碱性的钙碱性系列的二长花岗岩.花岗闪长岩组合,形成于造山后的伸展构造环境中,其大地构造背景与早侏罗世佳木斯板块和松嫩.张广才岭板块碰撞拼合后伸展作用有关。     

210Pb and 7Be as Tracers for Aerosol Transfers at Center Guizhou，China：Ⅰ．The Explanation by Weekly Interval

It′s essential to measure air concentrations and depositional fluxes of environmental radionuclides in different regions for modeling global contamination transfer and validation, tracing deposition process and dating, referencing watershed erosion trace and assessing natural radiation of ecosystem. This study introduces the research background and methods and explains weekly variations of ²¹⁰Pb and ⁷Be concentrations in surface air and precipitation at Mt. Guanfeng/Guiyang since 2001. The results indicate that ²¹⁰Pb and ⁷Be concentrations in surface air fluctuate periodically at 2~6 week interval because of the meteorological condition changes. The annual trend in ²¹⁰Pb air concentration is overall influenced by air temperature variation and periodical rainfall. ⁷Be air concentration varies up and down regualarly. The synchronization of low concentrations for both ²¹⁰Pb and ⁷Be in surface air and high ratio (²¹⁰Pb/⁷Be ≥ 0.8) indicate oceanic poor ²¹⁰Pb-⁷Be air mass invasion. The synchronization of high concentrations of ²¹⁰Pb and ⁷Be in surface air and low ratio (²¹⁰Pb/⁷Be ≤ 0.7) implies rich ⁷Be air mass invasion from altostratus atmosphere. Weekly concentrations of ²¹⁰Pb and ⁷Be in precipitation and the K_d coefficients are high in late Autumn to Spring, and low in late Spring to Autumn. Although ²¹⁰Pb and ⁷Be concentrations vary seasonally, their weekly concentrations in precipitation increase with that of air concentration. The ²¹⁰Pb and ⁷Be weekly concentrations for seasonal division is about 0.2 Bq/L and 1 Bq/L, respectively. However, the K_d coefficient decreases when ²¹⁰Pb and ⁷Be air concentrations increase. Deposition of ²¹⁰Pb and ⁷Be with precipitation mainly take place in Spring and Summer; The weekly fallout of ²¹⁰Pb and ⁷Be increases with increasing precipitation; the increase of ⁷Be is triple of that of ²¹⁰Pb and 2.5 when precipitation nears to zero. The weekly-high fallout of ²¹⁰Pb and ⁷Be with precipitation corresponds with the dramatic decrease of their air concentrations within or vicinal weeks. The ratio of ²¹⁰Pb to ⁷Be in rainfall is overall ≤ 0.5 and varies synchronously with the ratio in surface air, indicating that the two radionuclides are cleaned by precipitation from air at close speed. In the extreme freezing disaster in 2008, both ²¹⁰Pb and ⁷Be air concentrations were low and coupling with coexist of low concentration of aerosol and high nuclides activities. Weekly concentration of ⁷Be in surface air at Mt. Guanfeng demonstrates the anticipated concentration level in the low-latitude and high-elevation region; the short-term fluctuations of ⁷Be concentration indicated the hysteresis was influcenced by the strong air current submersion and the low-elevation air mass rising differently at Mt. Guanfeng and Mt. Waliguan.      

新疆哈尔里克山后碰撞期构造-岩浆活动特征及年代学证据

新疆地区后碰撞期构造-岩浆活动非常活跃,其同位素年龄集中在290～270Ma。天山东段的后碰撞期构造-岩浆活动研究相对薄弱,高质量的定年数据较少。在野外地质调查的基础上,笔者选择东天山哈尔里克地区的小堡花岗岩体进行了锆石的LA-ICP-MSU-Pb定年,获得两组谐和年龄,分别为297±2Ma和295±2Ma,代表哈尔里克地区后碰撞早期岩浆作用的形成时代。小堡岩体矿物组合以斜长石、石英、钾长石、角闪石和黑云母为主,副矿物有锆石、磷灰石和磁铁矿,与I型高钾钙碱性花岗岩矿物组合基本一致。与小堡花岗岩体同时发育、空间并存的还有基性岩墙群和碱性花岗岩,构成后碰撞初始阶段三组合地质标志。结合区域地质资料,认为小堡早二叠世花岗岩体是后碰撞初期碰撞造山、地壳增厚引发下地壳物质部分熔融的产物,其构造属性为板内岩浆活动。     

Pediment response to drainage basin evolution in south-central Arizona

The Sonoran Desert portion of the Basin and Range physiographic province contains a number of streams that now flow across once-closed basins. We explore here the research questions of if and how granitic rock pediments respond to the transition from rimming endorheic basins to bordering through-flowing streams. Granitic rock pediments of the northern Usery and eastern McDowell Mountains once graded to the closed Miocene–Pliocene Pemberton basin that occupied the present-day location of the confluence of the Salt and Verde Rivers. The process of lake overflow, which integrated these rivers, first aggraded fill terraces that, in turn, caused aggradation of a mantle of transported grus on bedrock pediments. Subsequent episodic incision of the Salt and Verde rivers lowered the base level; this led to the development of erosional features such as rolling topography of a degrading pediment mantle; exposure of the former piedmont angle and its associated zones of enhanced bedrock decay and regolith carbonate; and exposure of spheroidally weathered bedrock and emerging tors, some of which experienced 20^th century erosion. The granitic pediments of the former Pemberton Basin, which now transport grus to the Salt and Verde rivers, have actively adjusted to aggradational and degradational events associated with drainage integration and do not appear to be inherited from an ancient wet climatic interval.