Dissolved chromium in the St. Lawrence estuary

A study of dissolved chromium in the St. Lawrence estuary and Gulf of St. Lawrence has been carried out. A chromium concentration of 0·7 μg l^?1 was found in the St. Lawrence River. In the turbidity maximum of the upper estuary, chromium is removed from solution onto fine-grained resuspended sediments and internally produced organic-rich floccules. A simple flux calculation shows that these processes remove ～50% of the total dissolved chromium input of the river. At salinities greater than 5‰ dissolved chromium mixes conservatively.     

The 1999 and 2000 eruptions of Mount Cameroon: eruption behaviour and petrochemistry of lava

Mount Cameroon (4,095 m high and with a volume of ~1,200 km³) is one of the most active volcanoes in Africa, having erupted seven times in the last 100 years. This stratovolcano of basanite and hawaiite lavas has an elliptical shape, with over a hundred cones around its flanks and summit region aligned parallel to its NE--SW-trending long axis. The 1999 (28 March–22 April) eruption was restricted to two sites: ~2,650 m (site 1) and ~1,500 m (site 2). Similarly, in the eruption in 2000 (28 May–19 June), activity occurred at two sites: ~4,095 m (site 1) and ~3,300 m (site 2). During both eruptions, the higher vents were more explosive, with strombolian activity, while the lower vents were more effusive. Accordingly, most of the lava (~8×10⁷ m³ in 1999 and ~6×10⁶ m³ in 2000) was emitted from the lower sites. The 1999–2000 lavas are predominantly basanites with low Ni (5–79 ppm), Cr (40–161 ppm) and mg numbers (34–40). Olivine (Fo_77–85, phenocrysts and Fo_68–72, microlites), clinopyroxene (Wo₄₇En₄₁Fs₁₀ to Wo₅₁En₃₄Fs₁₅), plagioclase (An_49–67) and titanomagnetite are the principal phenocryst and groundmass phases. The lavas contain xenocrysts of olivine and clinopyroxene, which are interpreted as fragments of intrusive rocks disrupted by magma ascent. Major and trace element characteristics point to early fractionation of olivine. The clinopyroxenes (Al₂O₃ 1.36–7.83 wt%) have high Al^iv/Al^vi ratios (1.3–1.8) and are rich in TiO₂, characteristics typical of low pressure clinopyroxenes. Geochemical differences between the 1999–2000 lavas and those from previous eruptions, such as higher Nb/Zr of the former, suggest that different eruptions discharged magmas that evolved differently in space and time. Geophysical and petrological data indicate that these fractionated magmas originated just below the geophysical Moho (at 20–22 km) in the lithospheric mantle. During ascent, the magmas disrupted intrusions and earlier magma pockets. The main ascent path is below the summit, where newly arrived magma degasses. Degassed magma simultaneously intrudes the flank rift zones where most lava is extruded.An erratum to this article can be found at     

Was a dacite dome implicated in the 9,500 <Emphasis Type="SmallCaps">b.p.</Emphasis> collapse of Mt Ruapehu? A palaeomagnetic investigation

Constraining the process by which volcanoes become unstable is difficult. Several models have been proposed to explain the driving forces which cause volcanic edifices to catastrophically collapse. These include models for destabilisation of volcanic flanks by wedging due to dyke intrusion and the weakening of mechanical properties by pressurisation of pore fluids. It is not known which, if any, of the models are relevant to particular sector collapse events. Recent developments in the palaeomagnetic estimation of emplacement temperatures of volcaniclastic rocks have shown that even relatively low emplacement temperatures can be recorded by volcaniclastics with high fidelity. We have carried out a palaeomagnetic study of emplacement temperatures to investigate the role of igneous activity in the initiation of the 9,500 b.p. Murimotu sector collapse of Mt Ruapehu, New Zealand. This debris avalanche deposit has three fades which are stratigraphically superimposed, and the lowermost fades contains three lithological assemblages representing different segments of the edifice which were transported with little internal mixing within the flow. We have determined that some of the dacite-bearing assemblage 1, fades 1 was hot (∼350 °C) during transport and emplacement, whereas none of the other lithological assemblages of fades contained hot material. Our interpretation is that a dacite dome was active on the ancient Ruapehu edifice immediately prior to the Murimotu sector collapse. The partially cooled carapace of the dome and material shed from this part was incorporated into the avalanche deposit, along with cold lavas and volcaniclastics. We have not found evidence for incorporation of material at or close to magmatic temperatures, at least in the sampled locations. Our palaeomagnetic work allows us to develop a comprehensive, new palaeomagnetic classification of volcaniclastics. Published online: 25 January 2003 Editorial responsibility: D. Dingwell     

Characterization of volcanic thermal anomalies by means of sub-pixel temperature distribution analysis

The simultaneous solution of the Planck equation (involving the widely used “dual-band” technique) using two shortwave infrared (SWIR) bands allows for an estimate of the fractional area of the hottest part of an active lava flow (f _h) and the background temperature of the cooler crust (T _c). The use of a high spectral and spatial resolution imaging spectrometer with a wide dynamic range of 15 bits (DAIS 7915) in the wavelength range from 0.501 to 12.67 μm resulted in the identification of crustal temperature and fractional areas for an intra-crater hot spot at Mount Etna, Italy. This study indicates the existence of a relationship between these T _c and f _h extracted from DAIS and Landsat TM data. When the dual band equation system is performed on a lava flow, a logarithmic distribution is obtained from a plot of the fractional area of the hottest temperature vs. the temperature of the cooler crust. An entirely different distribution is obtained over active degassing vents, where increases in T _c occur without any increase in f _h. This result indicates that we can use scatter plots of T _c vs. fh to discriminate between different types of volcanic activity, in this case between degassing vents and lava flows, using satellite thermal data.     

Carbonatites in a subduction system: The Pleistocene alvikites from Mt. Vulture (southern Italy)

We report here, for the first time, on the new finding of extrusive calciocarbonatite (alvikite) rocks from the Pleistocene Mt. Vulture volcano (southern Italy). These volcanic rocks, which represent an outstanding occurrence in the wider scenario of the Italian potassic magmatism, form lavas, pyroclastic deposits, and feeder dikes exposed on the northern slope of the volcano. The petrography, mineralogy and whole-rock chemistry attest the genuine carbonatitic nature of these rocks, that are characterized by high to very high contents of Sr, Ba, U, LREE, Nb, P, F, Th, high Nb/Ta and LREE/HREE ratios, and low contents of Ti, Zr, K, Rb, Na and Cs. The O–C isotope compositions are close to the “primary igneous carbonatite” field and, thus, are compatible with an ultimate mantle origin for these rocks. The Sr–Nd–Pb–B isotope compositions, measured both in the alvikites and in the silicate volcanic rocks, indicate a close genetic relationship between the alvikites and the associated melilitite/nephelinite rocks. Furthermore, these latter products are geochemically distinct from the main foiditic-phonolitic association of Mt. Vulture. We propose a petrogenetic/geodynamic interpretation which has important implications for understanding the relationships between carbonatites and orogenic activity. In particular, we propose that the studied alvikites are generated through liquid unmixing at crustal levels, starting from nephelinitic or melilititic parent liquids. These latter were produced in a hybrid mantle resulting from the interaction through a vertical slab window, between a metasomatized mantle wedge, moving eastward from the Tyrrhenian/Campanian region, and the local Adriatic mantle. The occurrence of carbonatite rocks at Mt. Vulture, that lies on the leading edge of the Southern Apennines accretionary prism, is taken as an evidence for the carbonatation of the mantle sources of this volcano. We speculate that mantle carbonatation is related to the introduction of sedimentary carbon from the Adriatic lithosphere during Tertiary subduction.     

Deciphering the Holocene evolution of the St. Lawrence River drainage system using luminescence and radiocarbon dating

The St. Lawrence River is an important drainage route for eastern North American fresh waters. Following Late Pleistocene deglaciation, several fluctuations in base level have fine-tuned the evolution of the ancestral St. Lawrence. These fluctuations are hereby dated using K-feldspar infrared stimulated luminescence (IRSL) and radiocarbon. The accuracy of the individual IRSL dates was achieved by properly correcting for thermal transfer and anomalous fading. For each site investigated, widely used statistical approaches in equivalent dose data have been used to establish which age model, the central or the minimum model, would be appropriate to define the “true” depositional age. The chronology of the succession of regional lake levels is based on careful mapping and dating of the regional dunes, beaches and deltaic sediments. A relative time-space evolution history could be drawn, from ca. 8000 years BP to the present time period. Three major fluctuations are documented for the middle to late Holocene. An unexpected finding, from the ages cluster diagram, is that there have been times in the recent past (ca. 1000–4000 years BP) when the river level was lower or at the same elevation as today. The potential for K-feldspar IRSL to accurately date the Holocene lacustrine evolution is critical in the St. Lawrence River modern drainage basin, an environment that might be negatively impacted over the next century.     

大兴安岭北段诺敏大山地区早白垩世侵入岩地球化学特征及其构造意义

本文选择大兴安岭北段诺敏大山地区早白垩世侵入岩进行了锆石U-Pb年代学和地球化学研究,探讨该区域侵入岩成因类型、岩浆来源及构造环境。该区侵入岩岩性主要为正长花岗岩、正长花岗斑岩和似斑状正长花岗岩,对其中正长花岗岩样品进行LA-ICP-MS锆石U-Pb测年表明,正长花岗岩侵位年龄为129.5±0.4 Ma,应为早白垩世岩浆活动的产物,结合区内侵入岩与地层相互接触关系,本区侵入岩形成时代为早白垩世。区内侵入岩具有富硅（SiO2= 67.36%~74.09%）、富碱（K2O+Na2O= 8.88%~9.34%）、高铝（Al2O3= 12.56%~16.15%）,低MgO、TiO2、CaO的特点,属于高钾钙碱性岩石系列;铝饱和指数（A/CNK）为0.94~1.31,为准铝质—过铝质岩石。微量元素富集Rb、U、Th、K等大离子亲石元素,强烈亏损Ti、Nb、Sr、P等高场强元素,具有明显的Eu负异常,属于高分异I型花岗岩。岩石Rb/Sr为0.9~2.0,Sr/Y为4.2~7.2,显示出高Sr、低Y的特点,指示岩浆源区为地壳物质的部分熔融。结合区域研究成果,蒙古—鄂霍茨克构造域在早白垩世之前已结束碰撞,诺敏大山地区早白垩世岩浆活动可能发生在蒙古—鄂霍茨克造山后的伸展环境。     

Acidification of Lower St. Lawrence Estuary Bottom Waters

Accumulation of metabolic CO₂ can acidify marine waters above and beyond the ongoing acidification of the ocean by anthropogenic CO₂. The impact of respiration on carbonate chemistry and pH is most acute in hypoxic and anoxic basins, where metabolic CO₂ accumulates to high concentrations. The bottom waters of the Lower St. Lawrence Estuary (LSLE), where persistently severe hypoxia has developed over the last 80 years, is one such case. We have reconstructed the evolution of pH in the bottom waters from historical and recent data, and from first principles relating the stoichiometry of CO₂ produced to oxygen consumed during microbial degradation of organic matter. Based on the value of the atmospheric partial pressure of CO₂ that best reproduces the preformed dissolved inorganic carbon concentration in the bottom waters, we estimate the average ventilation age of the bottom waters to be 16?±?3 years. The pH of the bottom waters has decreased by 0.2 to 0.3 over the last 75 years, which is four to six times greater than can be attributed to the uptake of anthropogenic CO₂. The pH decrease is accompanied by a decline in the saturation state with respect to both calcite and aragonite. As of 2007, bottom waters in the LSLE are slightly supersaturated with respect to calcite (Ω_c?≈?1.06?±?0.04) but are strongly undersaturated with respect to aragonite (Ω_a?≈?0.67?±?0.03).

     

Dynamics of co-ignimbrite plumes generated from pyroclastic flows of Mount St. Helens (7 August 1980)

 Four co-ignimbrite plumes were generated along the flow path of the pyroclastic flow of 7 August 1980 at Mount St. Helens. Three of the plumes were generated in discrete pulses which can be linked to changes in slope along the channel. One plume was generated at the mouth of the channel where the flow decelerated markedly as it moved onto the lower slopes of the pumice plain. Plume generation here may be triggered by enhanced mixing due to a hydraulic jump associated with an abrupt slope change. Measurements of plume ascent velocity and width show that the co-ignimbrite plumes increased in velocity with height. The plumes have initial velocities of 1–2 m/s. Two of the plumes reached a velocity maximum (4.6 and 8.8 m/s, respectively, at heights of 270 and 315 m above the flow) and thereafter decelerated. The other plumes reached velocities of 6.2 and 13 m/s. The four plumes become systematically less energetic downstream as measured by their ascent rates, which can be interpreted as a consequence of decreasing interaction of the pyroclastic flow front with the atmosphere. Theoretical models of both co-ignimbrite plumes and discrete co-ignimbrite clouds assume that there is no initial momentum, and both are able to predict the observed acceleration stage. The rising plumes mix with and heat air and sediment out particles causing their buoyancy to increase. Theoretical models agree well with observations and suggest that the initial motion of the ascending material is best described as a discrete thermal cloud which expands as it entrains air, whereas the subsequent motion of the head may become influenced by material supplied from the following plume. The models agree well with observations for an initial temperature of the ash and air mixture in the range of 500–600 K, which is in turn consistent with the measured initial ash temperature of around 920 K. Ash masses of 3.4×10⁵ to 1.8×10⁶ kg are estimated. Received: 11 January 1996 / Accepted: 7 October 1996