La3+ 离子掺杂钨酸铅单晶的微结构缺陷

钨酸铅晶体是一种非化学计量化合物,缺陷丰富,蕴含着利用掺杂产生新效应和开发新功能的广泛可能性。探讨了不同浓度La3 掺杂对于钨酸铅晶体发光性能的影响,如热释光、X射线激发发光、光致发光等。La3 掺杂有效地抑制了陷阱中心,使发光受到强烈的抑制,在高浓度掺杂的钨酸铅中,激发机制有所改变,通过XPS测试的结果分析了不同浓度La3 掺杂机制。低浓度掺杂中,La3 取代Pb2 ,形成缺陷复合体[2(La3Pb ).-(VPb)″];高浓度掺杂晶体中,La3 离子不但占据Pb2 位置,而且也会占据W6 位置(La3W ),产生La3 的自补偿机制,形成La3 的自补偿对[(La3W )-(La3Pb ).]-(VO)..或缺陷聚集体[3(LaP3b ).-(La3W )]。     

重金属铜污染植被光谱响应特征研究

重金属铜污染植被的反射光谱特性会发生明显改变。在本研究中,采用不同程度的铜污染土壤作为培养基质,选择春小麦、上海青两种农作物进行铜胁迫实验,获取了4个不同生育期、10个不同铜污染强度下的植被叶片的反射光谱,并采用铜污染叶片7个特征波段和光谱角的方法研究了铜污染叶片的光谱特征。结果表明,铜污染叶片光谱差异与作物时期和作物类型有关,可以采用叶片光谱角描述铜污染叶片与健康叶片的光谱差异。该方法只需与阈值做简单的比较,方法简便易行,而且对轻度及重度铜污染十分敏感。叶片光谱辐射传输模型反演结果表明铜污染叶片内部结构参数N明显变大,这也证明了铜污染使叶片内部结构更加散乱无序。在此基础上进一步建立了N与红肩处反射率值的线性关系,相关系数为0.978。本文为铜污染叶片光谱反射模型的建立提供了初步的数据基础与理论支持。     

Evaluation of ASCE 7 equations for designing acceleration‐sensitive nonstructural components using data from instrumented buildings

This study uses instrumented buildings and models of code‐based designed buildings to validate the results of previous studies that highlighted the need to revise the ASCE 7 F_p equation for designing nonstructural components (NSCs) through utilizing oversimplified linear and nonlinear models. The evaluation of floor response spectra of a large number of instrumented buildings illustrates that, unlike the ASCE 7 approach, the in‐structure and the component amplification factors are a function of the ratio of NSC period to the supporting building modal periods, the ground motion intensity, and the NSC location. It is also shown that the recorded ground motions at the base of instrumented buildings in most cases are significantly lower than design earthquake (DE) ground motions. Because ASCE 7 is meant to provide demands at a DE level, for a more reliable evaluation of the F_p equation, 2 representative archetype buildings are designed based on the ASCE 7‐16 seismic provisions and exposed to various ground motion intensity levels (including those consistent with the ones experienced by instrumented buildings and the DE). Simulation results of the archetype buildings, consistent with previous numerical studies, illustrate the tendency of the ASCE 7 in‐structure amplification factor, [1 + 2(z/h)] , to significantly overestimate demands at all floor levels and the ASCE 7 limit of to in many cases underestimate the calculated NSC amplification factors. Furthermore, the product of these 2 amplification factors (that represents the normalized peak NSC acceleration) in some cases exceeds the ASCE 7 equation by a factor up to 1.50.     

A Possible Mechanism of Ocean Finestructure Part Ⅰ: Energy and Coherence

依据在作者的前文（１９９８）中对于考虑旋转向量水平分量（ｆ～）的大洋内波方程求出的渐近解,文中对Ｓ场（考虑ｆ～条件下的总的内波场）,ＳＩ场（不计ｆ～影响的内波场）和ＳＦ场（Ｓ场中与ｆ～相关联的部分）导出了能量谱和相干谱。此理论谱与Ｍｕｌｅｒ等（１９７８）的ＩＷＥＸ实验的观测结果相比较表明,ＳＦ场的水平动能谱和铅直位移谱基本上与水平流细结构和铅直位移细结构的观测谱一致。作者推测ＳＦ场对应于中纬度大洋可逆细结构。但是对于相干谱的观测结果,在不考虑内波非线性相互作用和破碎过程的条件下,仅考虑ＳＦ场的影响还不能给予满意的解释。     

Computation of wind-wave spectra in coastal waters with SWAN on unstructured grids

An unstructured-grid procedure for SWAN is presented. It is a vertex-based, fully implicit, finite difference method which can accommodate unstructured meshes with a high variability in geographic resolution suitable for representing complicated bottom topography in shallow areas and irregular shoreline. The numerical solution is found by means of a point-to-point multi-directional Gauss–Seidel iteration method requiring a number of sweeps through the grid. The approach is stable for any time step while permitting local mesh refinements in areas of interest. A number of applications are shown to verify the correctness and numerical accuracy of the unstructured version of SWAN.     

Estimation of the Land Surface Emissivity in the Hinterland of Taklimakan Desert

An accurate accounting of land surface emissivity(ε) is important both for the retrieval of surface temperatures and the calculation of the longwave surface energy budgets.Since ε is one of the important parameterizations in land surface models(LSMs),accurate accounting also improves the accuracy of surface temperatures and sensible heat fluxes simulated by LSMs.In order to obtain an accurate emissivity,this paper focuses on estimating ε from data collected in the hinterland of Taklimakan Desert by two different methods.In the first method,ε was derived from the surface broadband emissivity in the 8–14 μm thermal infrared atmospheric window,which was determined from spectral radiances observed by field measurements using a portable Fourier transform infrared spectrometer,the mean ε being 0.9051.The second method compared the observed and calculated heat fluxes under nearneutral atmospheric stability and estimated ε indirectly by minimizing the root-mean-square difference between them.The result of the second method found a mean value of 0.9042,which is consistent with the result by the first method.Although the two methods recover ε from different field experiments and data,the difference of meanvalues is 0.0009.The first method is superior to the indirect method,and is also more convenient.     

极光粒子沉降研究:谱形式及其在极区大气中的传输

分析了近年来南极地区极光沉降粒子的卫星、火箭、地面观测和研究结果,分别给出了极光椭圆区、极盖区、南大西洋异常区和极尖／极隙区粒子沉降的形式来源和特点。并根据磁尾研究的新进展,提出极光粒子沉降谱存在另外两种形式谱：（１）κ分布谱;（２）κ分布加上一个或多个脉冲谱,这两种谱来源于磁尾中性片区（绝热区非绝热区）。南极不同的区域,极光粒子有不同的沉降特点。这些沉降对极区电离层产生极大的影响。根据带电粒子在磁化大气中运动的Ｆｏｋｋｅｒ Ｐｌａｎｋ 方程,利用带电粒子在大气中传输的电离理论,导出极光粒子谱在极区大气中传播的解析表达式,对各种极光粒子谱在极区中的演化规律加以分析,并以此来解释在南极地区探测到的不同高度的极光电子谱的演化     

基于X射线荧光光谱法测定少量样品的主次元素

在某些实验中,由于样品来源的有限性,导致样品数量有限,因而有必要探讨少量样品中主次元素的测定方法。X射线荧光光谱法具有样品制备简单、分析速度快、重现性好、测量范围宽和多元素同时进行分析的特点,目前在众多领域中得到了广泛的应用。基于回归曲线法、经验系数法和康普顿散射线内标法求取了各待测元素的工作曲线常数、元素间效应的影响系数和谱重叠系数,并对4 g(32 mm内径,常规)和1 g(10 mm内径,少量)样品测量的精密度和准确度进行了比较分析。结果表明,4 g(32 mm内径,常规)样品测量平均精密度约为1%,1 g(10 mm内径,少量)样品的平均精密度约为3%。测定结果基本能够满足覆盖区多目标地球化学调查样品的质量要求。     

浓硫酸钠水溶液中的离子对

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。