香格里拉红牛铜多金属矿成矿模式及深部找矿

红牛矿属印支晚期义敦岛弧带南段、中甸弧主弧期远程熔体(岩浆)—溶液改造型矽卡岩矿床,赋存于上三叠统曲嘎寺组第二段地层中。除典型矽卡岩铜矿床特征外,出现成矿温度较高的辉钼矿,推测矿区深部应发育含矿性较好的中酸性侵入体,具有寻找大—超大型矽卡岩—斑岩复合型铜钼多金属矿床的找矿前景。     

The geology and Re–Os geochronology of the Palaeoproterozoic Vaikijaur Cu–Au–(Mo) porphyry-style deposit in the Jokkmokk granitoid, northern Sweden

The Vaikijaur Cu–Au–(Mo) deposit is located in the ca. 1.88 Ga calc-alkaline Jokkmokk granitoid near the Archaean–Proterozoic palaeoboundary within the Fennoscandian shield of northern Sweden. The Skellefte VMS district lies immediately to the south and the northern Norrbotten Fe-oxide–Cu–Au deposits to the north. The Vaikijaur deposit occupies an area of 2×3 km within the Jokkmokk granitoid and includes stockwork quartz-sulphide veinlets and disseminated chalcopyrite, pyrite, gold, molybdenite, magnetite, and pyrrhotite. Porphyritic mafic dykes were emplaced along fractures in a ring dyke pattern. The Jokkmokk granitoid, dykes, and the mineralized area are foliated, indicating that mineralization predated the main regional deformation. The mineralized area is characterized by strong potassic alteration. Phyllic and propylitic alteration zones are also present. A pyrite-rich inner core is surrounded by a concentric zone with pyrite, chalcopyrite, and gold. Molybdenite is distributed irregularly throughout the chalcopyrite zone. Geophysical data indicate a strongly conductive central zone in the mineralized area bordered by conductive and high magnetic zones. Five high precision Re–Os age determinations for three molybdenite occurrences from outcrop and drill core samples constrain the age of porphyry-style Cu–Au–(Mo) mineralization to between 1889±10 and 1868±6 Ma. A younger molybdenite is associated with a much later metamorphic event at about 1750 Ma. These data suggest that primary porphyry-style mineralization was associated with calc-alkaline magmatism within the Archaean–Proterozoic boundary zone at ca. 1.89–1.87 Ga.     

Timing of carbonatite-hosted U-polymetallic mineralization in the supergiant Huayangchuan deposit,Qinling Orogen:Constraints from titanite U-Pb and molybdenite Re-Os dating

The newly-discovered supergiant Huayangchuan uranium(U)-polymetallic(Sr,Se,REEs,Ba,Nb and Pb) deposit is located in the Qinling Orogen,central China.The deposit underwent multistage mineralization,with the main carbonatite ore stage being the most important for the U,Nb,REE,Sr and Ba endowments.According to the mineral assemblages,the main carbonatite ore stage can be divided into three substages,i.e.,sulfate(Ba-Sr),alkali-rich U and REE-U mineralization.Main-stage titanite from the Huayangchuan igneous carbonatite are rich in high field strength elements(HFSEs,e.g.,Zr,Nb and REEs),and show clear elemental substitutions(e.g.,Ti vs.Nb+Fe+Al and Ca+Ti vs.Fe+Al+REE).High-precision LA-ICP-MS titanite dating yielded a U-Pb age of 209.0 ± 2.9 Ma,which represents the mainstage mineralization age at Huayangchuan,and is coeval with the local carbonatite dyke intrusion.This mineralization age is further constrained by the Re-Os dating of molybdenite from the Huayangchuan carbonatite,which yielded a weighted mean age of 196.8 ± 2.4 Ma.Molybdenite Re contents(337.55-392.75 ppm) and C-OSr-Nd-Pb isotopic evidence of the Huayangchuan carbonatite both suggest a mantle origin for the carbonatite.Our study supports that the Late Triassic carbonatite magmatism was responsible for the world-class U-Mo-REE mineralization in the Qinling Orogen,and that the regional magmatism and ore formation was likely caused by the closure of the Mianlue ocean and the subsequent North China-South China continent-continent collision.     

北祁连山西段西柳沟钨钼矿的Re-Os定年及地质意义

从北祁连山西段西柳沟钨钼矿床中选取9个辉钼矿样品进行了Re-Os定年,结果显示西柳沟钨钼矿床的等时线年龄为421.0±3.8Ma,而岩体的Rb-Sr等时线年龄为426.1Ma。表明西柳沟钨钼矿床与北祁连山西段最大的岩体-金佛寺岩体是同一时期形成。通过讨论分析西柳沟钨钼矿床的控矿构造特征、金佛寺岩体的形态及地球化学特征结合区域构造演化,提出成岩成矿发生在晚志留世,是华北与柴达木两板块碰撞之后的产物,成矿物质来源主要为壳源。     

西昆仑大同地区加里东期成岩、成矿事件:来自LA-ICP-MS锆石U-Pb定年和辉钼矿Re-Os定年的证据

大同地区相继发现了一系列与侵入岩有关的铜钼矿点和矿化点,布斯拉津铜钼矿化点是在大同地区新发现的岩浆热液脉状铜钼矿化点。首次采用LA-ICP-MS锆石U-Pb测年技术对大同地区布斯拉津含矿黑云母石英二长岩和花岗细晶岩进行锆石U-Pb同位素测年,获得成岩年龄分别为446Ma和449Ma;对辉钼矿中Re-Os同位素进行测试,获得等时线年龄为435±25Ma,表明大同地区成矿作用略晚于成岩作用,岩浆热液铜钼矿化是加里东中期的构造、岩浆活动的产物,成矿物质来源以壳幔混源为主,成矿作用与古亚洲构造域和特提斯构造域的复合演化有关。发生于加里东中期的这一成矿事件,是在俯冲挤压背景下的间歇拉张作用影响下的强烈岩浆活动和成矿作用的产物。     

Genesis of the Ore-related Granite Porphyry and Molybdenite Re-Os Age of Laomiaogou Porphyry-skarn Mo Deposit,Western Henan Province: Implications for Regional MineralizationEI北大核心CSCD

The newly discovered Laomiaogou porphyry-skarn Mo deposit is located south of the Machaoying fault in western Henan province. The ore-body is hosted in the contact between the Laomiaogou granite porphyry dyke and the Duguan Formation. LA-ICP-MS U-Pb analyses for zircons from the granite porphyry yield a weighted mean 206Pb/238U age of 152.1±0.6 Ma, and seven molybdenite separates yield a weighted mean age of 151.9±0.9 Ma and isochron age of 151.6±5.1 Ma. Thus, the granite porphyry dyke and Mo mineralization are contemporaneous. The ore-related granite porphyry dyke is a peraluminous I-type granite with high contents of SiO2 and K2O. The rocks are strongly depleted in P, Nb, Ta and Ti, indicative of intensive fractionation of apatite and Fe-Ti oxides, and characterized by low whole-rock εNd(t) (-20.6 to -17.6) and zircon εHf(t) values (-26.9 to -22.6). The old tDM2(Nd) ages (2.37 to 2.61 Ga) and zircon tDM2(Hf) ages (2.62 to 2.88 Ga) suggest that the granite porphyry was likely derived from an ancient crustal source. Considering the tectonic evolution and geochemical characteristics of the granite as well as other Mesozoic granites in the southern margin of the North China Craton, we suggest that the Laomiaogou granite porphyry dyke and Mo were most likely derived from partial melting of the Taihua Group metamorphic rocks under extensional tectonic regime related to the subduction of the paleo-pacific plate. © 2018, Science Press. All right reserved.     

Geochronology of the Xingshan molybdenum deposit,Jilin Province,NE China,and its Hf isotope significance

The Xingshan porphyry Mo deposit is located in the Lesser Xing’an Range–Zhangguangcai Range metallogenic belt, NE China. Mineralization occurred in granodioritic porphyry and monzogranite, which have zircon U–Pb ages of 171.7 ± 2.2 Ma and 170.9 ± 4.6 Ma, respectively. Molybdenite Re–Os dating indicates that Mo mineralization occurred at 167.3 ± 2.5 Ma. These geochronological data suggest that the magmatic and hydrothermal activities of the Xingshan Mo deposit happened during the Middle Jurassic in Mesozoic. Positive ε_Hf values (6.2–11.6) and young T_DM2 (473–826 Ma) of the monzogranite (XS-3) and granodioritic porphyry (XS-5) indicate that the source materials of Xingshan ore-bearing rocks are the juvenile crust, which mainly accreted on the Songnen block during the Meso-Neoproterozoic. Xingshan porphyry Mo deposits resulted from the magmatism and tectonism induced by the subduction of Paleo-Pacific Ocean.     

辽宁姚家沟钼矿床辉钼矿Re-Os同位素年龄测定及其地质意义

本文对青城子矿田姚家沟钼矿床中的8件辉钼矿样品进行Re-Os同位素分析,所获辉钼矿的模式年龄值为166.1±2.3Ma~169.1±2.5Ma,等时线年龄为168.8±3.9Ma(MSWD=1.12),代表流体成矿年龄,结合姚家沟花岗岩体已有的年代学数据,我们推测姚家沟地区可能存在多期次岩浆侵入,姚家沟钼矿床与168.8±3.9Ma 的岩浆侵入活动有关。结合区域成矿地质背景,我们推断早中侏罗纪时期,姚家沟钼矿床可能受古亚洲洋闭合的影响,是华北板块与西伯利亚板块后碰撞造山阶段构造-岩浆作用及相关流体活动的产物。     

赣西北大湖塘钨矿床辉钼矿Re-Os同位素定年及其意义

江西省武宁县大湖塘钨矿位于武宁县西南方向41km,赣西北地区武宁、靖安、修水3县交界处,矿区处于下扬子成矿省之江南隆起东段成矿带之西部,是与燕山期花岗质岩浆活动有关的钨矿床, 也是最近刚勘查出的我国规模最大的钨矿床。本文采用辉钼矿Re-Os同位素定年技术,测得大湖塘石门寺矿段辉钼矿Re-Os等时线年龄为143.7±1.2Ma(n=6,MSWD=0.84); 狮尾洞矿段辉钼矿Re-Os等时线年龄为140.9±3.6Ma (n=6,MSWD=2.30)。说明其成矿于早白垩世,与其北侧的、同处于下扬子成矿省的长江中下游成矿带九瑞-鄂东南矿集区的铜多金属矿床成岩成矿年龄非常一致,但与华南成矿省之南岭成矿带的钨矿成矿作用有诸多不同。下扬子成矿省主要为早期两大古陆碰撞对接、构造格局开始大转换时期成矿,而华南成矿省为地壳重熔形成的花岗质岩浆经过多期次和多阶段分异演化在最晚阶段富集成矿。     

兰坪盆地西缘沉积岩容矿脉状Cu-Ag-Pb-Zn多金属矿床成矿时代

兰坪盆地是中国著名的三江构造-成矿带的重要组成部分。兰坪盆地西缘发育大量沉积岩容矿脉状Cu-Ag-Pb-Zn多 金属矿床,矿体的分布受一个逆冲推覆构造控制。逆冲推覆构造的根部带主要发育脉状Cu-Ag（Mo） 矿床（包括金满 Cu-Ag、连城Cu-Mo及一系列脉状Cu矿床）;前锋带主要发育Pb-Zn-Ag（±Cu） 矿床（包括白秧坪Pb-Zn-Ag-Cu多金属矿 集区及一系列小型的Pb-Zn矿床)。为了探讨兰坪盆地西缘脉状Cu-Ag-Pb-Zn多金属矿床成矿时代,该文在系统总结前人年 代学数据的基础上,补充进行了金满Cu矿床与黄铜矿密切共生的方解石的Sm-Nd法和连城Cu-Mo矿床成矿早阶段辉钼矿 的Re-Os法测年。金满Cu矿床方解石Sm-Nd等时线年龄为58±5 Ma,连城Cu-Mo矿床Re-Os年龄为48±2 Ma,结合前人的资 料表明：（1） 根部带Cu矿床主成矿时代为56~48 Ma,对应于印度-亚洲大陆碰撞造山主碰撞阶段,后期（47~35 Ma） 很可 能存在一期Cu-Ag（Mo） 的叠加或改造成矿作用;（2） 前锋带Pb-Zn-Ag（±Cu） 多金属矿床的成矿作用主要发生在31~29 Ma 左右,对应于印度-亚洲大陆碰撞造山的晚碰撞构造转换期。