脑膜瘤旁巨型矿化灶矿物成分分析

脑膜瘤旁复发性巨大矿化灶是罕见的病例,对其中矿物成分的分析可能会对肿瘤复发病因的研究提供辅助信息。本文利用X射线物相分析、红外光谱分析、环境扫描电镜观察和高分辨透射电镜观察分析等方法,对该矿化灶样品的矿物成分进行了分析。结果表明,该矿化灶的矿物颗粒大小统计值约为4.3nm,主要成分为碳酸磷灰石,笔者推测可能还含有少量不定形的磷酸钙系列其他矿物。     

江西永平铜矿花岗质岩石的岩石结构、地球化学特征及其成矿意义

江西永平铜矿位于华南怀玉山—北武夷山铜铅锌多金属成矿带内,是赣东北地区除了德兴铜矿外的另一个大型铜矿基地。该矿区存在两种类型的花岗质岩石,一种是花岗岩;另一种是英安斑岩。英安斑岩具有典型斑状结构和石英眼结构,而花岗岩则具有单向固结结构。在化学成分上,两者属于高钾的钙碱性系列岩石,英安斑岩贫硅、富Al、Fe、Mg、Ca,以及具有较大的Na_2O/K_2O(0.02～0.64)等特点;而花岗岩富硅、贫Al、Ca,以及富碱和具有较小的Na_2O/K_2O(0.02～0.03)等特点。两种类型的岩石具有一致的REE配分曲线。它们均富集大离子亲石元素(Ba、Rb、K),亏损高场强元素(Th、Nd、Ta、Ti)以及元素Sr和P,显示了与俯冲作用有关的岩浆作用。在结构和化学成分上,花岗岩则类似于美国Climax斑岩钼(铜)矿成矿斑岩的性质(如具有单向固结结构、较高的分异指数、富Si、贫Al、Ca、富Na_2O K_2O以及K_2O>Na_2O)。与英安斑岩有关的蚀变作用主要有夕卡岩化、黑云母化、白云母化、绿泥石化和萤石化,而与花岗岩有关的蚀变作用主要是白云母化和萤石化;相应地,与英安斑岩有关的成矿作用主要为铜,而与花岗岩有关的成矿作用则主要为钼。2件辉钼矿样品的Re-Os年龄分别为156.7±2.8Ma和155.7±3.6Ma,表明与花岗岩有关的钼成矿作用发生在156Ma左右。本文认为,永平铜钼矿的成矿地球动力学背景应是由挤压向伸展的转换环境。     

Lead isotope study of the late Archean Lac des Iles palladium deposit,Canada: enrichment of platinum group elements by ponded sulfide melt

Lead isotopic compositions of mineral separates are presented from the mineralized zones (Roby, Twilight, and High Grade zones) of the Lac des Iles palladium deposit (approximately 2.69 Ga) and tonalitic country rocks (approximately 2.727 to 2.775 Ga) in the Wabigoon subprovince of the western Superior Province of Canada. Plagioclase separates show Pb isotope ratios similar to those of the late Archean depleted mantle. Sulfide minerals coexisting with plagioclase have a more radiogenic Pb isotope composition, but very low concentrations of U (<0.2 ppb U) and Th (<0.01 ppb) compared to Pb (≫50 ppb). The isotope data are consistent with a model involving the incorporation of radiogenic Pb from country rocks to sulfide melt near the base of the magma chamber or along the conduit of the parental magmas. The proposed interpretation is also supported by decreasing Cu/Pd ratios from earlier barren to late fertile gabbro intrusions in the complex. The ponding sulfide melt became enriched in platinum group elements, as it was interacting with a large magma volume during the evolution of the Lac des Iles igneous complex.     

Yerranderie a Late Devonian Silver–Gold–Lead Intermediate Sulfidation Epithermal District, Eastern Lachlan Orogen, New South Wales, Australia

Felsic volcanic units of the Early Devonian Bindook Volcanic Complex host the Yerranderie epithermal silver–gold–lead district 94 km west–southwest of Sydney. Mineralization in the district forms part of a fault‐controlled, intermediate sulfidation, epithermal silver–gold–base metal vein system that has significant mineral and alteration zonation. Stage 1 of the mineral paragenesis in the veins developed quartz and carbonate with early pyrite, whereas stage 2 is a crustiform banded quartz–pyrite–arsenopyrite assemblage. Stage 3, the main stage of sulfide deposition, comprises early sphalerite, followed by a tetrahedrite–tennantite–gold assemblage, then a galena–chalcopyrite–native silver–pyrite assemblage, and finally a pyrargyrite–polybasite–pearceite assemblage. Stage 4 involves the deposition of quartz veins with minor (late) pyrite and stage 5 is characterized by siderite that infilled remaining voids. Mineral zonation occurs along the Yerranderie Fault, with bornite being restricted to the Colon Peaks–Silver Peak mine area, whereas arsenopyrite, which is present in both the Colon Peaks–Silver Peak and Wollondilly mine areas, is absent in other lodes along the Yerranderie Fault. The Yerranderie Fault, which hosts the major lodes, is surrounded by a zoned alteration system. With increasing proximity to the fault the intensity of alteration increases and the alteration assemblage changes from an outer quartz–muscovite–illite–(ankerite) assemblage to a quartz–illite–(pyrite–carbonate) assemblage within meters of the fault. ⁴⁰Ar/³⁹Ar dating of muscovite from the alteration zone gave a 372.1 ± 1.9 Ma (Late Devonian) age, which is interpreted to be the timing of the quartz–sulfide vein formation. Sulfur isotope values for sulfides range from 0.1 to 6.2‰ with one outlier of ?5.6 δ³⁴S‰. The results indicate that the initial ore‐forming fluids were reduced, and that sulfur was probably sourced from a magmatic reservoir, either as a direct magmatic contribution or indirectly through dissolution and recycling of sulfur from the host volcanic sequence. The sulfur isotope data suggest the system is isotopically zoned.     

Numerical Modeling of the Coupled Mechanical and Hydrological Processes during Deformation and Mineralization in the Mount Isa Block, Australia

Mount Isa is a major Australian and world Pb‐Zn‐Ag mineral province. The wide varieties of mineralization in the province are believed to be closely related to the geodynamic processes of Isan Orogeny, which occurred between ca 1500 and 1620 Ma. In order to understand the geodynamic processes associated with the Isan Orogeny and the giant mineralization systems in the Mount Isa district, a series of numerical models has been constructed to simulate coupled mechanical–hydrological processes, using Fast Lagrangian Analysis of Continua (FLAC), a finite difference computer code. The numerical modeling results have demonstrated that the most probable far‐field stress orientation during the Isan Orogeny is the asymmetrical E–W shortening, which led to greater easternward tectonic movement at the west boundary of the district in comparison with westward movement at the east boundary. During the initial and early stage of the Isan Orogeny, the mechanical and hydrological conditions in the Leichardt Fault Trough of the West Fold Belt are much more favorable for fluid accumulation and mineralization than in the East Fold Belt. The Mount Isan fault zone developed as a high dilation shear zone where the fluids were focused. As the asymmetrical shortening progressed, shortening deformation and shear strain localization became intensified in the eastern part of the orogenic district. The eastern region therefore became a more favorable locality for hydrothermal mineralization. This structural development feature seems to explain why mineralization in the East Fold Belt is generally later than in the West Fold Belt. Fluid production from the Williams–Naraku granites could result in fluid over‐pressuring, and this probably contributed to the extensive brecciation and related mineralization in the East Fold Belt.     

德兴金山金矿田不同尺度构造特征及其与成矿作用的关系

德兴市金山金矿田是与赣东北深大断裂带内次一级剪切带有关的中温热液矿床。其矿石类型主要由与断裂充填有关的小尺度石英脉组成，这些石英脉主要呈纹层状。不同尺度的构造研究表明，金山金矿是同构造的产物，递进变形作用与成矿作用密切相关，在成矿过程中，普遍发育压溶作用，导致早期的石英颗粒发生溶解以及形成黄铁矿压力影。金山金矿蚀变硫化物以黄铁矿为主，说明成矿流体中硫主要以H2S和HS-形式存在。断层阀机制引起压力波动，进而导致成矿流体的相分离和水—岩反应，是金山金矿的主要成矿机制。     

江西邹家山铀矿绿泥石形成温度及其成矿关系

本文采用电子探针分析技术，对产于邹家山火山岩型铀矿床深部的绿泥石进行蚀变特征、化学组成、形成环境研究，并初步探讨该矿床中的绿泥石的形成环境与铀矿化关系。指出绿泥石的形成温度为217.64-295.30℃。矿脉中与铀矿物共生的绿泥石主要是鲕绿泥石，而围岩中则是蠕绿泥石和铁镁绿泥石。含矿溶液沉淀时是一个还原环境，绿泥石不仅活化了火山岩中的铀，还为铀矿化提供了良好的沉淀环境。     

Multiphase origin of the Cu–Co ore deposits in the western part of the Lufilian fold-and-thrust belt, Katanga (Democratic Republic of Congo)

A multiphase origin of the Cu–Co ores in the western part of the Lufilian fold-and-thrust belt in Central Africa is proposed based on literature, satellite image interpretations and petrographic and fluid inclusion analyses on samples from the stratiform mineralization of Kamoto and Musonoi (DR Congo). The various mineral occurrences in the Katanga Copperbelt can be classified in distinct categories: stratiform, supergene enrichment and vein-type. The stratiform mineralization form the largest group and can be found mainly in Lower Roan (R-2) rocks, which can be identified as ridges on satellite imagery. Ore deposits outside the R-2 occur along lineaments and result often from supergene enrichment.The main phase of the stratiform mineralization in the Katanga Copperbelt occurred during diagenesis preceding the Lufilian orogeny. Petrographic observation identified various mineralizing phases, which played a role in the formation of these stratiform mineralization. Mineralization started during early diagenesis, but mainly occurred during further burial. After the formation of early diagenetic pyrite, the circulation of diagenetic Cu–Co-rich fluids resulted in the formation of the main mineralization. Preliminary microthermometric investigation of primary inclusions in authigenic quartz, associated with the main stage of stratiform mineralization, indicates that an H₂O–NaCl fluid with a minimum temperature between 80 and 195 °C and a salinity between 8.4 and 18.4 eq. wt% NaCl circulated during the main phase of mineralization.Numerous faults and fractures formed during the Lufilian orogeny cut the stratiform mineralization. They are, however, at Kamoto and Musonoi only associated with minor sulphides. Supergene alteration along faults and fractures resulted in an enrichment of the mineralization, with the formation of secondary Cu-oxides, -carbonates and -silicates.The importance of the interaction of various processes for the formation of economic Cu–Co ore deposits is confirmed by the straightforward relationship on satellite imagery between the location of economic mineral occurrences and faults, which acted as pathway for descending waters that caused the supergene enrichment and upgrading of the primary mineralization.     

华南中生代花岗岩型、火山岩型、外接触带型铀矿找矿思路（I）

华南中生代铀成矿作有处于中国东部燕山期强烈火山岩浆作用、壳幔作用及流体作用时期,铀具有大规模聚集成矿的前景。因此,中生代花岗岩型、火山岩型、外接触带型铀矿找矿必须引进深源成矿理论,淡化“浅成低温活化成矿理论”,充分认识铀矿既可形成于浅源浅成条件,也能形成于深源深成高温条件及深源浅成中温条件的特点,重视早阶段（130－95Ma）铀矿化,打破以主岩类型找矿的人为界限,加强白垩纪岩浆岩体系的研究。