Chemical and Isotopic Constraints for Recrystallization of Sedimentary Dolomites from the Western Canada Sedimentary Basin

Mississippian shoal carbonates of Western CanadaSedimentary Basin are important hydrocarbon hosts.Dolomitization plays a major role in the evolution ofreservoir porosity in these carbonates. This processvaries across the basin and reflects, in part, divergentsources and chemistry of pore fluids. Dolomites fromseveral petroleum reservoirs were analyzed formineralogical, geochemical and isotopic variation. Thedata clearly demonstrate the progressive and complexrecrystallization of dolomite during shallow and deepburial in modified marine, meteoric and burial fluids.These data include: change in crystal size,stoichiometry, cathodoluminscence characteristics,stable oxygen and carbon isotopic shifts and changesin radiogenic Sr isotopic composition. However,regional geology, tectonic history and fluid flowevolution play important roles in the diageneticimprints and the degree of recrystallization.Early microcrystalline dolomite formed in normalmarine and evaporative conditions in Mississippiancarbonates from Western Canada Sedimentary Basinhave undergone variable degrees of recrystallization, frompristine dolomite akin to Holocene sabkha dolomitewith preserved mineralogical and chemical attributesto highly recrystallized mesodolomite, however stillnonstoichiometric, but with highly altered chemicalsignatures. Careful attention should be made to localgeology, hydrodynamics and fluid flow when investigatingdolomite recrystallization in sedimentary basins.     

Biostratigraphy,microfacies and depositional environments of upper Viséan limestones from the Burren region,County Clare,Ireland

The Burren region in western Ireland contains an almost continuous record of Viséan (Middle Mississippian) carbonate deposition extending from Chadian to Brigantian times, represented by three formations: the Chadian to Holkerian Tubber Formation, the Asbian Burren Formation and the Brigantian Slievenaglasha Formation. The upper Viséan (Holkerian–Brigantian) platform carbonate succession of the Burren can be subdivided into six distinct depositional units outlined below. (1) An Holkerian to lower Asbian unit of skeletal peloidal and bryozoan bedded limestone. (2) Lower Asbian unit of massive light grey Koninckopora‐rich limestone, representing a shallower marine facies. (3) Upper Asbian terraced limestone unit with minor shallowing‐upward cycles of poorly bedded Kamaenella‐rich limestone with shell bands and palaeokarst features. This unit is very similar to other cyclic sequences of late Asbian age in southern Ireland and western Europe, suggesting a glacio‐eustatic origin for this fourth‐order cyclicity. (4) Lower Brigantian unit with cyclic alternations of crinoidal/bryozoan limestone and peloidal limestone with coral thickets. These cycles lack evidence of subaerial exposure. (5) Lower Brigantian bedded cherty dark grey limestone unit, deposited during the maximum transgressive phase of the Brigantian. (6) Lower to upper Brigantian unit mostly comprising cyclic bryozoan/crinoidal cherty limestone. In most areas this youngest unit is truncated and unconformably overlain by Serpukhovian siliciclastic rocks. Deepening enhanced by platform‐wide subsidence strongly influenced later Brigantian cycle development in Ireland, but localized rapid shallowing led to emergence at the end of the Brigantian. A Cf5 Zone (Holkerian) assemblage of microfossils is recorded from the Tubber Formation at Black Head, but in the Ballard Bridge section the top of the formation has Cf6 Zone (Asbian) foraminiferans. A typical upper Asbian Rugose Coral Assemblage G near the top of the Burren Formation is replaced by a lower Brigantian Rugose Coral Assemblage H in the Slievenaglasha Formation. A similar change in the foraminiferans and calcareous algae at this Asbian–Brigantian formation boundary is recognized by the presence of upper Asbian Cf6γ Subzone taxa in the Burren Formation including Cribrostomum lecomptei, Koskinobigenerina sp., Bradyina rotula and Howchinia bradyana, and in the Slievenaglasha Formation abundant Asteroarchaediscus spp., Neoarchaediscus spp. and Fasciella crustosa of the Brigantian Cf6δ Subzone. The uppermost beds of the Slievenaglasha Formation contain a rare and unusual foraminiferal assemblage containing evolved archaediscids close to tenuis stage indicating a late Brigantian age. Copyright © 2006 John Wiley & Sons, Ltd.     

Correlation of Mississippian (Upper Viséan) foraminiferan,conodont, miospore and ammonoid zonal schemes,and correlation with the Asbian–Brigantian boundary in northwest Ireland

The microbiota of the upper Viséan (Asbian–Brigantian) rocks in the Lough Allen Basin in northwest Ireland is analysed. The Middle Mississippian sequence studied extends from the upper part of the Dartry Limestone/Bricklieve Limestone formations of the Tyrone Group to the Carraun Shale Formation of the Leitrim Group. The rocks have been traditionally dated by ammonoid faunas representing the B_2a to P_2c subzones. The Meenymore Formation (base of the Leitrim Group) also contains conodont faunas of the informal partial‐range Mestognathus bipluti zone. The upper Brigantian Lochriea nodosa Conodont Zone was recognized by previous authors in the middle of the Carraun Shale Formation (Ardvarney Limestone Member), where it coincides with upper Brigantian ammonoids of the Lusitanoceras granosus Subzone (P_2a). Foraminifera and algae in the top of the Dartry Limestone Formation are assigned to the upper Cf6γ Foraminifera Subzone (highest Asbian), whereas those in the Meenymore Formation belong to the lower Cf6δ Foraminifera Subzone (lower Brigantian). The Dartry Limestone Formation–Meenymore Formation boundary is thus correlated with the Asbian–Brigantian boundary in northwest Ireland. For the first time, based on new data, a correlation between the ammonoid, miospore, foraminiferan and conodont zonal schemes is demonstrated. The foraminiferans and algae, conodonts and ammonoids are compared with those from other basins in Ireland, northern England, and the German Rhenish Massif. Historically, the Asbian–Brigantian boundary has been correlated with several levels within the P_1a Ammonoid Subzone. However, the new integrated biostratigraphical data indicate that the Asbian–Brigantian boundary in northwest Ireland is probably located within the B_2a Ammonoid Subzone and the NM Miospore Zone, but the scarcity of ammonoids in the Tyrone Group precludes an accurate placement of that boundary within this subzone. Copyright © 2006 John Wiley & Sons, Ltd.     

The upper Viséan–Serpukhovian in the type area for the Serpukhovian Stage (Moscow Basin,Russia): Part 2. bulk geochemistry and magnetic susceptibility

This study is the summary analysis of bulk XRF geochemistry (233 samples from three sections) of the Oka and Zaborie groups of the type Serpukhovian succession in the Moscow Basin. The siliciclastic wedges in the limestone‐dominated Oka Group are two to three times enriched in Fe, Ti, and Zr compared to Clarke values. Bulk iron strongly correlates with magnetic susceptibility. Iron tends to form ferruginized horizons (original siderites) in finer grained siliciclastic beds associated with coal seams. These beds also tend to be enriched in Cu, Ni, Pb, Zn, and other trace metals (metal enrichment horizons or MEHs). MEHs formed in ponded conditions of coastal low‐pH marshlands vegetated by mangrove‐like lycopsid bushes. Well‐drained environments of palaeokarst formation and alkaline everglades (Akulshino palustrine event) on the other hand did not accumulate Fe and trace metals. The thin shale seam (found close to the Viséan–Serpukhovian boundary in Polotnyanyi Zavod) has unusually high Rb and Sr values, which may contain volcanigenic material useful for absolute dating. The Gurovo Formation (Steshevian Substage of the Serpukhovian) is less enriched in Fe and Ti. In the Gurovo Formation, the transition from the lower montmorillonitic shale (Glazechnya Member) to the upper palygorskitic shale (Dashkovka Member) is expressed by a five‐fold increase in background MgO values, which indicates progressive shoaling and climatic aridization. Phosphorus remains close to 0% in the Oka Group and tends to increase in the Zaborie Group, in agreement with a dramatic increase of conodont numbers and other signatures of a lower Serpukhovian marine transgression. The lower half of the Glazechnya Member exhibits fluctuating enrichment in Fe, Cu, Ni, Pb, Zn, V, Cr, and Co. These fluctuations are mostly inverse to fluctuations of Mn. This pattern has been interpreted as a signature of seafloor oxygen deficiency, where Mn‐rich samples record oxygen‐poor environments (redox barrier level with the sediment surface) and Mn‐poor samples enriched in Fe and trace metals record transitions to anoxic setting. This interval is interpreted as the Lower Serpukhovian highstand. Enrichment in Fe, Ti, and Zr of Oka siliciclastic units of Polotnyanyi Zavod indicates provenance from the ore‐rich Voronezh Land, south of the Moscow Basin. The westerly flux regarded as a possible provenance in previous palaeogeographic reconstructions is discarded for the studied sections. The Gurovo Shale is also linked to the Voronezh province, although Fe, Ti, and Zr concentrations are lower than in the Oka shales. Copyright © 2014 John Wiley & Sons, Ltd.     

Early Serpukhovian (late Mississippian) microflora from the Guadiato Area (southwestern Spain)

Calcareous microflora occur commonly in the early Serpukhovian (late Mississippian) rocks from the Guadiato Area (southwestern Spain) despite the fact that this area contains mostly siliciclastic sediments. The microflora recorded in the carbonate beds is regarded as representative of both relatively deep‐water and shallow‐water facies and can be compared with the slope and shelf facies environments distinguished in the Guadiato Area. Up to 45 algal taxa have been identified in the carbonate beds, of which 26 taxa occur in the relatively deep‐water assemblages, whereas the shallow‐water assemblages are composed of up to 43 taxa. The entire algal assemblage is dominated by calcifoliids, common cyanobacteria and incertae sedis, but the shallow‐water assemblages contain more commonly dasyclads, red algae and aoujgaliids. Most of these taxa are present, but poorly known, in other Serpukhovian carbonate platforms in the western Palaeotethys. Some algae (Hortonella uttingii, Kamaenella tenuis and Koninckopora inflata), usually regarded as being restricted to the Viséan, have been found in Serpukhovian rocks in the Guadiato Area, and also in Algeria, thus their stratigraphic ranges might be extended up to the Serpukhovian. Other important taxa include: Archaeolithophyllum, Cabrieropora, Calcifolium, Falsocalcifolium, Fourstonella, Frustulata, Kulikia, Neoprincipia and ‘Windsoporella’, which are exceptionally recorded in Serpukhovian rocks, or not recorded at all, because they are typically recorded in the Pennsylvanian (cf. Clavaporella), although some of them show earlier occurrences in Viséan rocks (Claracrusta, Paraepimastopora and Sparaphralysia). Some of the algal taxa can be considered as potential regional markers for the Serpukhovian, such as Archaeolithophyllum, cf. Clavaporella, Frustulata and Girvanella (?) sp. The algal assemblages found in the Guadiato Area show the greatest similarities with those in the Béchar‐Mézarif (Algeria), Pyrenees and Montagne Noire (southern France). Copyright © 2005 John Wiley & Sons, Ltd.     

Three-dimensional sequence analysis of a subsurface carbonate ramp, Mississippian Appalachian foreland basin, West Virginia, USA

Well‐cuttings, wireline logs and limited core and outcrop data were used to generate a regional, three‐dimensional sequence framework for Upper Mississippian (Chesterian), Greenbrier Group carbonates in the Appalachian foreland basin, West Virginia, USA. The resulting maps were used to document the stratigraphic response of the basin to tectonics and to glacio‐eustasy during the transition into ice‐house conditions. The ramp facies include inner ramp red beds and aeolianites, lagoonal muddy carbonates, mid‐ramp ooid and skeletal grainstone shoal complexes, and outer ramp wackestone–mudstone, that grades downslope into laminated silty lime mudstone. The facies make up fourth‐order sequences, a few metres to over 90 m (300 ft) thick. The sequences are bounded along the ramp margin by lowstand sandstones and calcareous siltstones. On the ramp, sequence boundaries are overlain by thin transgressive siliciclastics and aeolianites, and only a few are calichified. Maximum flooding surfaces on the outer ramp lie beneath deeper water facies that overlie lowstand to transgressive siliciclastic or carbonate units. On the shallow ramp, maximum flooding surfaces overlie siliciclastic‐prone transgressive systems tracts, that are overlain by highstand carbonates with significant grainstone units interlayered with lagoonal lime mudstones. The fourth‐order sequences are the major mappable subsurface units; they are bundled into weak composite sequences which are bounded by red beds. In spite of differential subsidence rates across the foreland basin (1 to 3 cm/k.y. up to 25 cm/k.y.), eustatic sea‐level changes controlled regional sequence development. Thrust‐load induced differential subsidence of fault‐blocks, coupled with in‐plane stress, controlled the rapid basinward thickening of the depositional wedge, whose thickness and facies were influenced by subtle structures such as arches trending at high angles as well as parallel to the margin.     

Multi‐proxy constraints on the significance of covariant δ13C values in carbonate and organic carbon during the early Mississippian

This study investigates the covariation between carbonate and organic δ¹³C values in a proximal to distal transect of four outcrops in the Madison Limestone in the Western United States Rockies, combined with δ³⁴S values of carbonate associated sulphate, the concentration of acid‐insoluble material and measurements of total organic carbon. These new geochemical datasets not only allow for an evaluation of carbon isotope covariance during one of the largest perturbations to the global carbon cycle over the past 550 Myr, but also constrain the cause of the excursion in carbonate δ¹³C values. The results support the hypothesis that a period of anoxia did not play a role in generating the positive carbonate δ¹³C values, but rather favour interpretations by previous workers that the proliferation of land plants destabilized the Carboniferous carbon cycle, setting the stage for a significant change in the carbonate δ¹³C values of contemporaneous marine carbonates. These results also demonstrate that one of the largest perturbations to the global carbon cycle did not produce synchronous variations in carbonate and organic δ¹³C values, emphasizing the importance of local depositional controls on carbon isotope covariance in the geological record in both modern and ancient environments.     

Palaeozoic micro-pelmatozoan thecae from the bedload of the River Maas (province of Limburg,the Netherlands)

In the Netherlands, Late Palaeozoic pelmatozoans – that is, stalked echinoderms – are known from building stones and cobbles in rivers, but there are no in-situ carbonate rocks from which they might be collected. Unsurprisingly, most recognisable specimens are columnals and pluricolumnals. Two small thecae, collected in the mid-1970s from silexite cobbles in the bedload of the River Maas in the Venlo-Tegelen area (province of Limburg, south-east Netherlands) are exceptional finds. One specimen, the diplobathrid camerate crinoid Rhodocrinites sp., has an unsculptured theca and some minor differences of form, yet otherwise satisfies the diagnosis of this genus. The other, the pentremitid blastoid Doryblastus? sp. is rather poorly preserved, yet is the first blastoid to be recorded from the Netherlands. Either or both of these specimens may be juveniles, particularly the blastoid. They are unlikely to be coeval, coming from separate cobbles and being of slightly different preservation. Their provenance from silexite cobbles suggest they originated from Lower Carboniferous (Tournaisian-Visean = Mississippian) carbonates in the southern Ardennes (south-central Belgium).     

A new crinoid from the Mississippian (Early Carboniferous) of South Pembrokeshire,Wales

A new species of cladid crinoid, Hylodecrinus cymrus, is described from the Pembroke Limestone Group (Mississippian, Tournaisian, Courceyan) of West Angle Bay in south Pembrokeshire, Wales. It has a medium bowl‐shaped aboral cup, with strong ridges extending across the basals and radials forming pits at the plate corners. It is most similar to the late Tournaisian H. carinatus (Hall, 1861) of North America but differs in having less strongly cuneate brachials that are longer than wide with more subtle carinae on the aboral side. This specimen represents the first report of this genus from Europe, which most probably migrated from North America. Copyright © 2013 John Wiley & Sons, Ltd.     

Conodonts of the Mississippian/Pennsylvanian boundary interval in Central Iran

The record of conodonts related to the Mississippian/Pennsylvanian boundary interval was investigated in four sections in Central Iran from two different structural units. Two sections from the Sanandaj–Sirjan trend zone (Asad-abad, and Darchaleh sections) and two from the East-Central Iran Microplate (Shesh-angosht and Kale-Sardar sections) exhibit a nearly complete record previously described across the Mississippian/Pennsylvanian boundary in Iran. The investigated sections can be subdivided in three formations (Ghaleh-, Absheni-, and Zaluda Formation) which belong to the Sardar Group. The mid-Carboniferous boundary was defined by the occurrence of Declinognathus noduliferus s.l.. Bio-event characteristics of the Carboniferous conodont fauna (Mississippian genera Gnathodus and Lochriea have been replaced by Pennsylvanian genera Declinognathus and Idiognathodus) as well as sedimentological changes within overall shallow water deposits were located approximately 33° S of the paleoequator and suggest sea-level changes within the framework of the Late Paleozoic Ice Age (LPIA). Furthermore, a widespread crinoid marker horizon previously described from two localities in Iran can be subdivided into three units of different ages.