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171.
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Sodalites have been proposed as a possible host of certain radioactive species, specifically 99Tc and 129I, which may be encapsulated into the cage structure of the mineral. To demonstrate the ability of this framework silicate mineral to encapsulate and immobilize 99Tc and 129I, single-pass flow-through (SPFT) tests were conducted on a sodalite-bearing multi-phase ceramic waste form produced through a steam reforming process. Two samples made using a steam reformer samples were produced using non-radioactive I and Re (as a surrogate for Tc), while a third sample was produced using actual radioactive tank waste containing Tc and added Re. One of the non-radioactive samples was produced with an engineering-scale steam reformer while the other non-radioactive sample and the radioactive sample were produced using a bench-scale steam reformer. For all three steam reformer products, the similar steady-state dilute-solution release rates for Re, I, and Tc at pH (25 °C) = 9 and 40 °C were measured. However, it was found that the Re, I, and Tc releases were equal or up to 4.5x higher compared to the release rates of the network-forming elements, Na, Al, and Si. The similar releases of Re and Tc in the SPFT test, and the similar time-dependent shapes of the release curves for samples containing I, suggest that Re, Tc, and I partition to the sodalite minerals during the steam reforming process. 相似文献
173.
As an important geothermal resource, hot dry rock(HDR) reserves have been studied in many countries. HDR resources in China have huge capacity and have become one of the most important resources for the potential replacement of fossil fuels. However, HDR resources are difficult to develop and utilise. Technologies for use with HDR, such as high–temperature drilling, reservoir characterisation, reservoir fracturing, microseismic monitoring and high–temperature power stations, originate from the field of oil and drilling. Addressing how to take advantage of these developed technologies is a key factor in the development of HDR reserves. Based on the thermal crustal structure in China, HDR resources can be divided into four types: high radioactive heat production, sedimentary basin, modern volcano and the inner–plate active tectonic belt. The prospective regions of HDR resources are located in South Tibet, West Yunnan, the southeast coast of China, Bohai Rim, Songliao Basin and Guanzhong Basin. The related essential technologies are relatively mature, and the prospect of HDR power generation is promising. Therefore, analysing the formation mechanisms of HDR resources and promoting the transformation of technological achievements, large–scale development and the utilisation of HDR resources can be achieved in China. 相似文献
174.
JIAO Yangquan WU Liqun RONG Hui PENG Yunbiao MIAO Aisheng WANG Xiaoming 《《地质学报》英文版》2016,90(6):2117-2132
Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan'an Formation and the lowstand system tract of the Zhiluo Formation,and there is a regional unconformity between them. The Dongsheng uranium deposit is associated with the Jurassic coal measures. Research data indicate that the Jurassic coal measures in the study area have a certain hydrocarbon-generating capacity,although the metamorphic grade is low(Ro=0.40%–0.58%). In the Dongsheng region alone,the accumulative amount of generated coalbed methane(CBM) is about 2028.29 × 108 –2218.72 × 108 m~3; the residual amount is about 50.92 × 108 m~3,and the lost amount is about 1977 × 108 m~3. Analysis of the burial history of the host rocks and the evolutionary history of the Dongsheng uranium deposit suggests that the Jurassic coal measures generated hydrocarbon mainly from Middle Jurassic to Early Crataceous,which is the main mineralization phase of the Dongsheng uranium deposit. By the Late Cretaceous,a mass of CBM dissipated due to the strong tectonic uplift,and the Dongsheng uranium deposit stepped into the preservation phase. Therefore,the low-mature hydrocarbon-containing fluid in the Jurassic coal measures not only served as a reducing agent for the formation of sandstone-type uranium deposits,but also rendered the second reduction of paleo-interlayer oxidation zone and become the primary reducing agent for ore conservation. Regional strata correlation reveals that the sandstone-type uranium reservoir at the bottom of the Zhiluo Formation is in contact with the underlying industrial coal seams in the Yan'an Formation through incision or in the form of an unconformity surface. In the Dongsheng region with poorly developed fault systems,the unconformity surface and scour surface served as the main migration pathways for low-mature hydrocarbon-containing fluid migrating to the uranium reservoir. 相似文献
175.
产于含油(气)盆地中的地浸砂岩型铀矿床与油(气)关系密切,在空间上常与油(气)藏呈共生关系。文章认为其成矿条件和控矿因素相似,并且具有成因联系是二者共生的主要原因。砂岩型铀矿和油(气)藏具有相似的成矿大地构造背景、岩相古地理条件、容矿地层、岩性圈闭、构造控矿条件和有机质基础;在成因上油(气)中的不同组分及其次生矿物对铀有重要的吸附和还原作用,是铀沉淀富集的重要因素之一,铀等放射性元素的存在也有利于油气的生成。由于成矿机理的差异性,砂岩型铀矿与油(气)藏属于异体共生矿床,二者的产出位置并不完全重叠,砂岩型铀矿的产出位置往往更靠近盆缘,且在油(气)储层上方,或以单一矿种产出。 相似文献
176.
东昆仑祁漫塔格矿带典型矿田构造背景与岩浆-热力构造特征 总被引:1,自引:0,他引:1
以矿田构造–岩相填图为主要方法,研究确定矿田构造和岩浆-热力构造类型及矿床类型,进行成矿富集中心的圈定及找矿预测,是矿田构造背景复杂地区的有效调研方法之一。东昆仑西段祁漫塔格矿带多期构造–岩浆活动强烈,断裂发育,以印支晚期岩浆侵入成矿与找矿进展较大。本次选择景忍–虎头崖、卡尔却卡B区、乌兰乌珠尔三个矿田区,进行1∶10000构造–岩相填图,填制了三个矿田区岩浆–热力构造类型分布图,认为晚三叠世岩浆侵入作用是该区多金属大规模成矿的主要内因,叠加其上的不同方向断裂控矿作用不同,近东西向和北西西向断裂控矿显著,明确了各矿田构造背景和印支期岩浆侵入形成的花岗斑岩+矽卡岩+断裂带热液成矿的模式,厘定了岩浆–热力构造的识别标志,即主要是印支晚期中酸性侵入岩、花岗斑岩、矽卡岩带、大理岩带、接触交代蚀变带、断裂破碎带叠加热液蚀变带等,圈定了成矿和找矿富集中心。 相似文献
177.
白石坝一带花岗岩具高硅低铝、富钾贫钠、非常低Sr(24.9×10~(-6)~82.9×10~(-6))高Yb(2.61×10~(-6)~5.74×10~(-6))的南岭型花岗岩特征,A/CNK介于0.91~0.98之间,σ在1.92~2.22之间。明显富集Rb、Th、K等大离子不相容元素,亏损Ba、Sr、P、Ti等元素,并具有弱Nb亏损,稀土元素分布曲线呈明显的"燕式"型,其形成可能来源于下地壳底部部分熔融与地壳物质发生混合形成的产物,源区深度较浅、水含量低和氧逸度低,处于还原状态下的伸展构造背景,有利于锡矿的萃取和富集,研究其区域构造-岩浆演化,对指导区域矿产预测和评价均具有重要的理论和实际意义。 相似文献
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180.
简述了从国外到国内的砂岩型铀矿概况及成矿理论研究的发展,归纳出了我国砂岩型铀矿的"叠合复成因氧化-还原成矿理论",并就"预富集"、"板状矿体成因"、"深部油气作用"、"可地浸概念"、"大砂体"等问题进行了粗浅的讨论。 相似文献