Solid phase characterization and metal deportment in a mussel shell bioreactor for the treatment of AMD,Stockton Coal Mine,New Zealand

The Stockton Coal Mine, located on the West Coast of New Zealand, is evaluating the use of a mussel shell bioreactor (MSB) to treat acidic metalliferous runoff from acid forming overburden. This novel approach is similar in concept to vertical flow wetlands (VFWs) and successive alkalinity producing systems (SAPS). The MSB system is a trapezoidal pit 2 m deep, 35 m long, 3–10 m wide with 60° angle sides. During operation it contained 160 tonnes (240 m³) of mussel shell material and was saturated with a 100–200 mm water cap. Influent flowed through the reactor at a mean rate of 0.3 L s⁻¹ resulting in a hydraulic retention time (HRT) of ≈6 days. The prototype MSB was in operation for a total of 1027 days, from June 2009 through March 2012, and effectively sequestered 99.7% of Al, 99.3% of Fe, 98.8% of Ni, 98.4% Tl and 99.3% of Zn, as determined from a previous evaluation of MSB performance. The MSB also effectively neutralized acidity, which resulted in an increase in influent pH from 2.8 to 6.9 in the effluent. Based on an examination of several excavated pits, five distinct reaction zones developed within the MSB. The reaction zones consisted of an allochthonous sediment layer (0–330 mm), an oxidized iron-rich ocherous layer (at 330–350 mm depth), an aluminum layer (at 350–600 mm depth) with geochemical variations throughout (350–500 mm and 500–600 mm); and a chemically reduced bottom shell layer (at 600–1100 mm). Representative samples were collected from each layer and analyzed using a combination of geochemical and physical methods to assess the stability of the secondary minerals and trace metal deportment within the MSB. Major elements Fe, Al, Ni, Tl, and Zn where preferentially associated with particular layers within the MSB. Elevated concentrations of Fe (110,000 mg kg⁻¹) were observed in the allochthonous sediment and ocherous precipitate layers, while Al (27,816 mg kg⁻¹), Ni (55 mg kg⁻¹), and Zn (655 mg kg⁻¹) were elevated within the aluminum and lower reduced depths within the MSB. Trace Tl (21 mg kg⁻¹) showed varying concentrations throughout the MSB, but was strongly correlated to lower layers of the system. Microbial biofilms were observed within the reduced portions of the shell layers often proximal to bacterial shaped sulfides. The geochemical assessment of the MSB presented in this study is the first of its kind for a MSB, and supports the argument that this system is another viable option for passive treatment of AMD.     

陕北榆神府矿区煤炭资源开发主要水工环问题及防治对策

分析了榆神府矿区煤炭资源开发所面临的主要水文、工程、环境地质问题。以水文工程地质条件研究为基础 ,给出了榆神府矿区土地沙漠化、水土流失和水环境受开采影响的预期结果。并提出了实现保水采煤的水工环技术方案和工程措施建议。     

用卫星高光谱数据提取德兴铜矿区植被污染信息

在深入分析研究德兴铜矿矿区植被光谱特征的基础上,利用美国EO-1卫星Hyperion高光谱数据,通过反演表征植物生理状态的光谱特征参数(红边位置和最大吸收深度)变异,提取与污染相关的信息,获取了矿山植被污染生态效应概况,为矿山污染的诊断和监测提供新技术和知识支撑。     

The First World War from above and below. Historical aerial photographs and mine craters in the Ypres Salient

During the First World War, ancient siege techniques were used in an attempt to break through the stalemate in the trenches. This paper approaches the mine crater war from a completely new perspective and focuses on a landscape-scale approach rather than on fragmented individual sites. Thousands of contemporary aerial photographs have been used as a primary source of information to detect and understand the historical mine crater landscape along the former Western Front in Belgium. The paper presents a methodology for dating war features by means of a time series analysis of aerial photographs, confronting this historical landscape with a high-resolution Airborne Laser Scanning (ALS) dataset.     

Arsenic distribution during formation and capping of an oxidised sulphidic minesoil, Macraes mine, New Zealand

A minesoil has developed over 5 years oxidative exposure on sulphide concentrate tailings (ca. 1 wt.% As) at the Macraes mesothermal gold mine, New Zealand. The minesoil has a dry crust which has formed due to evaporative drying. This dry crust is enriched in arsenic (ca. 5 wt.% As) as scorodite (FeAsO₄·2H₂O) because of upward mobility of dissolved arsenic during drying. Similar enrichment of arsenic has occurred along the walls of desiccation cracks which extend over 1 m into the minesoil. Capping of the tailings and minesoil with wet tailings (pH=8) results in dissolution of scorodite and remobilization of arsenic on the millimetre scale. Experimental capping of the minesoil with wet calcium carbonate remobilized some arsenic from scorodite on the centimetre scale, but much original arsenic enrichment was preserved after 400 days. A layer of gypsum (CaSO₄·2H₂O) and iron oxyhydroxide cementation developed at the interface between the minesoil and the experimental calcium carbonate cap, restricting water flow. This layer was ca. 1 mm thick after 400 days. Theoretical comparison between advection and diffusion in the minesoil suggests that diffusion is an important mechanism for chemical mobility on the 1–50-year time scale. However, advection can be important in secondary porosity of the dry crust of the minesoil and water penetrates this zone at a rate of 1.5 mm/day.     

Multiphysics modeling of arching effects in fill mass

A numerical modeling study is conducted to assess and gain a better understanding of the arching effects of field cemented tailings backfill (CTB). An integrated multiphysics model is developed that can illustrate and capture the changes in the material properties of CTB, consolidation behavior of CTB mass, and the shear behavior at the CTB/Rockwall interface. The predictive capability of the model has been successfully verified with comparisons of the predicted results with monitoring data taken from a series of field studies. The model is then used to simulate a series of applications that are relevant to CTB in practice.     

Environmental geochemistry of the Guanajuato Mining District, Mexico

The Guanajuato Mining District, once one of the major silver producers in the world, has been exploited for silver and gold from low-sulfidation quartz- and calcite-rich epithermal veins since 1548. Currently, there are some 150 million tonnes of low-grade ore piles and mine-waste material (mostly tailings) piles, covering a surface area of 15 to 20 km² scattered in a 100-km² region around the city of Guanajuato. Most of the historic tailings piles were not deposited as formal tailings impoundments. They were deposited as simple valley-filling piles without concern for environmental issues. Most of those historical tailings piles are without any vegetation cover and undergo strong eolian and hydrologic erosion, besides the natural leaching during the rainy season (which can bring strong thunderstorms and flash flows). There is public concern about possible contamination of the local aquifer with heavy metals (Fe, Mn, Zn, As and Se) derived from the mining activities.Experimental and field data from this research provide strong geochemical evidence that most of the mine-waste materials derived from the exploitation of the epithermal veins of the region have very low potential for generation of acid mine drainage due to the high carbonate/sulfide ratio (12:1), and very low potential for leaching of heavy metals into the groundwater system. Furthermore, geochemical evidence (experimental and modeled) indicates that natural processes, like metal adsorption onto Fe-oxy-hydroxides surfaces, control the mobility of dissolved metals. Stable isotope data from surface water, groundwater wells (150-m depth) and mine-water (300- to 500-m depth) define an evaporation line (δD=5.93 δ¹⁸O=13.04), indicating some deep infiltration through a highly anisotropic aquifer with both evaporated water (from the surface reservoirs) and meteoric water (not evaporated). Zinc concentrations in groundwater (0.03 to 0.5 ppm) of the alluvial aquifer, some 15 km from the mineralized zone, are generally higher than Zn concentrations in experimental tailings leachates that average less than 0.1 ppm. Groundwater travel time from the mineralized area to the alluvial valley is calculated to range from 50 to several hundred years. Thus, although there has been enough time for Zn sourced from the tailings to reach the valley, Zn concentrations in valley groundwater could be due to natural dissolution processes in the deep portions of the epithermal veins.     

三山岛金矿海边地下开采矿山稳定性的数值模拟分析

本文用数值模拟的分析方法, 评价了三山岛金矿地下开采引起的开采效应及地表下沉盆地的变形特征。结果表明, 矿山地表是稳定的, 上部一期工程开采引起的地表最大下沉量不超过700mm, 深部开挖时不超过995mm左右；在采场充填的情况下, 地表下沉值将降低55%左右；由于矿山地表变形较小, 加之覆盖层第四纪中存在着两层总厚度8～12m的隔水粘水层, 因此不致沟通地表水与井下的直接联系而危及矿山的安全。     

Hydrological and geomorphological criteria to evaluate the dispersion risk of waste sludge generated by the Aznalcollar mine spill (SW Spain)

Following the Aznalcóllar pyrite mine disaster (Seville, Spain) which caused the spilling of some 4.5?hm³ of acid water, the floodplains of the rivers Agrio and Guadiamar were rapidly cleaned of waste sludge. However, despite the efficiency of cleaning activities, there is still evidence of a fine superficial layer of sludge and some soil contamination, with the consequent risk of remobilisation of the pollutants by water erosion. There is much concern that these contaminated sediments may affect the precious ecosystems of the Doñana National Park and the Guadalquivir marshlands. This report describes the evaluation of the risk of mobilisation of the waste sludge through (1) detailed geomorphological analysis, indicating potential areas of erosion-sedimentation on the floodplains of the rivers Agrio and Guadiamar, and predicted dynamics of the waste sludge, and (2) evaluation of the potential dispersion of the waste sludge provoked by future flood events, including hydraulic calculations to model channel flow and the analysis of the texture of the sludge to obtain critical transport and sedimentation values. Findings suggest that the waste sludge is likely to be transported and deposited within the Doñana National Park during future flood events.     

Evaluation of proposed waste rock dump designs using the SIBERIA erosion model

Computer-based landscape evolution models offer the ability to evaluate landscape stability over the short (annual), medium (decades to hundreds of years) and long-term (thousands of years). Modeling has advantages in that design ideas can be tested, different surface material properties can be evaluated and risk analysis carried out. Landscape evolution models allow landscape surface change through time. These models also offer the advantage that the landscape can be evaluated visually as it develops through time, which is not possible with other types of models. Landscape evolution models can be used for not only soil loss assessment (i.e. tonnes/hectare/year), but also to evaluate the method of soil loss (i.e. rill or interrill erosion). This study examines a range of waste rock dump designs for the Minera Alumbrera Ltd. copper mine, Argentina. An erosion assessment using the SIBERIA erosion model over a 1000-year simulation period demonstrates waste rock dump designs using a conventional stepped design of backsloping benches and caps with angle of repose slopes provide the lowest average erosion rates and depths of incision than do other designs. Caution should be applied in interpreting these results as the SIBERIA erosion model is sensitive to parameter input and in this case was calibrated and run using a generic set of parameters that are not site specific. Nevertheless, the results provide a guide as to the strengths and weaknesses of different rehabilitation designs and demonstrate the insights that modeling studies can provide.