上新世以来伊豆-小笠原海脊黏土矿物的来源与古气候意义

对伊豆-小笠原海脊(ODP 782A孔)上新世以来沉积物中黏土矿物的组成、含量及矿物学特征进行了分析,结果表明:黏土矿物以伊利石(42%)和蒙皂石(42%)为主,绿泥石的平均含量为14%,高岭石的含量最低,平均仅为2%。伊利石的结晶度较好,平均为0.25°Δ2θ;化学指数较低,平均为0.31;表明伊利石主要形成于干冷的气候环境。通过将ODP 782A孔黏土矿物组合特征和含量与周边可能源区对比,并结合伊利石和蒙皂石的矿物学参数特征,我们认为蒙皂石主要来源于伊豆-小笠原海脊周边岛弧火山物质;伊利石、绿泥石和高岭石主要来自亚洲大陆风尘。上新世以来(伊利石+绿泥石)/蒙皂石比值总体上呈增加的趋势,并且在5.3~3.6、3.6~1.6、1.6~0 Ma的三个阶段表现出不同的变化特征,该比值与全球深海δ¹⁸O值所记录的全球变冷、北太平洋ODP 885/886孔风尘通量和灵台黄土沉积速率,以及日本海U1430站伊利石/蒙皂石比值所指示的亚洲内陆干旱变化的总体变化趋势和阶段性变化的时间点大致同步,表明该比值敏感地响应了全球变冷和亚洲内陆的干旱。上新世以来(伊利石+绿泥石)/高岭石比值表现为高/低交替变化,分别与中国灵台黄土磁化率高/低变化相对应,由于黄土磁化率记录了亚洲内陆干/湿变化,因此该黏土矿物比值敏感地响应了亚洲内陆的古气候变化,因而可以作为可靠的亚洲大陆干/湿变化示踪指标。     

大洋中脊海底热液系统的演化特征及其成矿意义

大洋中脊海底热液系统的演化与成矿是复杂、综合的地质过程.归纳、分析了前人研究的资料认为,热源供给和热液活动构造体系是控制热液系统演化与成矿的关键因素.在快速扩张洋中脊热液系统中,岩浆的供给充裕,构造体系渗透性极好,演化时间较短,海底的热液循环输出过程可分为发生、持续和衰退3个阶段;在慢速扩张洋中脊热液系统中,岩浆的供给...     

Evolution of the Grenada and Tobago basins and implications for arc migration

The tectonic mechanisms controlling how volcanic arcs migrate through space and geologic time within dynamic subduction environments is a fundamental tectonic process that remains poorly understood. This paper presents an integrated stratigraphic and tectonic evolution of Late Cretaceous to Recent volcanic arcs and associated basins in the southeastern Caribbean Sea using seismic reflection data, wide-angle seismic refraction data, well data, and onland geologic data. We propose a new tectonic model for the opening of the Grenada and Tobago basins and the 50-250-km eastward jump of arc volcanism from the Late Cretaceous Aves Ridge to the Miocene to Recent Lesser Antilles arc in the southeast Caribbean based on the mapping of three seismic megasequences. The striking similarity of the half-graben structure of the Grenada and Tobago basins that flank the Lesser Antilles arc, their similar smooth basement character, their similar deep-marine seismic facies, and their similar Paleogene sediment thickness mapped on a regional grid of seismic data suggest that the two basins formed as a single, saucer-shaped, oceanic crust Paleogene forearc basin adjacent to the now dormant Aves Ridge. This single forearc basin continued to extend and widen through flexural subsidence during the early to middle Eocene probably because of slow rollback of the subducting Atlantic oceanic slab. Rollback may have been accelerated by oblique collision of the southern Aves Ridge and southern Lesser Antilles arc with the South American continent. Uplift and growth of the southern Lesser Antilles arc divided the Grenada and Tobago basins by early to middle Miocene time. Inversion of normal faults and uplift effects along both edges of the Lesser Antilles arc are most pronounced in its southern zone of arc collision with the South American continent. The late Miocene to Recent depositional histories of the Grenada and Tobago basins are distinct because of isolation of the Grenada basin by growth and uplift of the Neogene Lesser Antilles volcanic ridge.     

Dampier Ridge,Tasman Sea,as a stranded continental fragment∗

Dredging of the Dampier Ridge recovered small fragments of granite, gabbro and sandstone. Dating of the igneous samples by the U‐Pb, K‐Ar and Rb‐Sr methods yielded precise ages mainly in the range 250 to 270 Ma, mid‐Permian. An imprecise Sm‐Nd mineral age of ～ 310 Ma might reflect slightly earlier emplacement of the gabbro. A granitic fragment has a composition approximating that of a minimum melt. Taken together with the Late Palaeozoic emplacement ages and other geochemical and geophysical data, the evidence strongly supports the conclusion that the Dampier Ridge is a continental fragment, formerly part of eastern Australia, with its present location a consequence of continental rifting and opening of the Tasman Basin by sea‐floor spreading.     

Neoproterozoic collisional metamorphism in overthrust terranes of the Trans-Angarian Yenisey Ridge,Siberia

Four polymetamorphic complexes in the vicinity of regional faults in the Trans-Angarian region of the Yenisey Ridge were studied to determine their metamorphic evolution and to elucidate distinctive features of the regional geodynamic processes. Based on our geological and petrological studies using geothermobarometry and P–T path calculations, we show that a Neoproterozoic medium-pressure metamorphism of the kyanite-sillimanite type at c. 850 Ma overprinted regionally metamorphosed low-pressure andalusite-bearing rocks. A positive correlation between rock ages and P–T estimates for the kyanite-sillimanite metamorphism provides evidence for regional structural and tectonic heterogeneity. The medium-pressure recrystallization was characterized by (1) localized distribution of metamorphic zones in the area directly underlying thrust faults with a measured thickness of 2.5–8 km; (2) syntectonic formation of kyanite-bearing mineral assemblages related to thrusting; (3) gradual increase in metamorphic pressure towards the thrust faults associated with a low metamorphic field gradient (from 1–7 to 12°C/km); and (4) equally steep burial P–T paths recorded for the highest grade rocks. These specific features are typical of collisional metamorphism during overthrusting of continental blocks and are evidence of near-isothermal loading in accordance with the transient emplacement of thrust sheets. The proposed model for tectono-metamorphic evolution of the study areas due to crustal thickening at high thrusting rates and subsequent rapid exhumation explains these tectonic features. Data analysis allowed us to consider the medium-pressure kyanite-bearing metapelites as a product of collisional metamorphism, reflecting unidirectional thrusting of Siberian cratonal blocks onto Yenisey Ridge along regional deep faults (Angara, Mayakon, and Chapa areas) and by opposite movements in the zone of secondary splay faults (Garevka area).     

Geodynamics of the Amirante Ridge and Trench Complex,Western Indian Ocean

The formation and evolution of the ～600 km long arcuate Amirante Ridge and Trench Complex (ARTC) is a significant geomorphic–structural feature in the Western Indian Ocean (WIO). The WIO contains evidence of at least two major magmatic episodes followed by continental rifting within the span of a little more than 20 million years. This involved the splitting of Madagascar from India at around 85 Ma and then separation between India and the Seychelles at 64–63 Ma as a possible consequence of two powerful volcanic eruptions from the Marion and Reunion hot spots, respectively. Formation and evolution of the ARTC represents this tumultuous period in the Indian Ocean, approximately between 85 and 60 Ma (Late Cretaceous–Early Tertiary).

We integrated geophysical, palaeomagnetical, and petrological data to examine three existing models that attempt to explain the formation of ARTC. In contrast, our study hints at several stages of extension and compression responsible for its formation. Our integrated data also suggest that the Carlsberg Ridge may have played a prominent role in the evolution of the ARTC that seems to have formed through a ridge-jump process after the conjugate spreading centres – Mascarene and Palitana ridges formed earlier during the India–Madagascar separation – ceased spreading because of violent eruption of the Reunion hot spot at around 65 Ma. The eruption disturbed the plumbing system of magma ascent, resulting in cessation of spreading along the conjugate spreading centres, forcing a ridge jump.

A collage of seismic refraction and reflection, free-air gravity, magnetic anomaly data, and Ar dating of rocks indicates that as the Carlsberg Ridge swept the Seychelles towards south, the crust between Madagascar and the Seychelles was increasingly compressed, with the abandoned northern Mascarene spreading centre absorbing the maximum stress. With continued compression, the western limb of the abandoned spreading ridge was thrust below the eastern limb to a limited degree. This partial subduction agrees with the gravity and seismic results. Our new study also accounts for the anomalous presence of 14 km-thick oceanic crust beneath the ARTC and its characteristic difference in petrology with other established subduction zones in the world.     

Trace-element distributions in silicates during prograde metamorphic reactions: implications for monazite formation

To assess the petrogenetic relationship between monazite and major silicates during prograde metamorphism, REE were measured across coexisting zoned silicates in garnet through kyanite‐grade pelitic schists from the Great Smoky Mountains, western Blue Ridge terrane, southern Appalachians, to establish REE concentrations and distributions before and after the monazite‐in isograd, and to identify the role major silicates play in the formation of monazite. Results indicate significant scavenging of light rare‐earth elements (LREE) from silicates during the monazite‐in isograd reaction; however, the absolute concentration of LREE hosted in the silicates was insufficient to produce monazite in the quantity observed in these schists. Monazite must have formed mainly from either the dissolution of allanite or some other source of concentrated LREE (possibly adsorbed onto grain boundaries), even though direct evidence for allanite is lacking in a majority of the samples. Laser‐ablation ICP‐MS analyses and theoretical thermodynamic calculations show that monazite may have formed as a result of contributions from both allanite and major silicates. Allanite breakdown initially formed monazite, and monazite production drew LREE liberated from allanite, major silicates and possibly from crystal boundaries. In many rocks the reaction was further promoted by the staurolite‐in reaction, allowing for rapid, isogradic monazite growth.     

The Mineral Composition and Sources of the Fine-Grained Sediments from the 49.6°E Hydrothermal Field at the SWIR

We used the X-ray diffraction method to determine systematically the mineral phases in bulk sediment samples and acid undissolved residuals of the fine-grained fraction of the surface sediments from the 49.6°E hydrothermal field at the Southwest Indian Ridge(SWIR)and discussed the mineral sources of the surface sediments.The results showed that the surface sediments in this region were composed of calcareous ooze,and calcite was the dominant mineral.The sediments also contained quartz,feldspar,clay minerals,pyroxene,sphalerite,barite,serpentine,and magnetite.The quartz,feldspar,and clay minerals were exogenous minerals that mainly originated from the Namib and Kalahari deserts in southern Africa.The pyroxene,serpentine,magnetite,sphalerite,calcite,and barite were endogenous minerals from weathering of seafloor basement rocks and seafloor hydrothermal activities.The sulfide particles in the sediments were mainly deposited from upwelling plumes.     

Mineralogy and Chemistry of Sulfides from the Longqi and Duanqiao Hydrothermal Fields in the Southwest Indian Ridge

Recent investigations found that hydrothermal activity and sulfide mineralization occurs along the Southwest Indian Ridge (SWIR). The Longqi and Duanqiao hydrothermal fields between 49° E and 53° E of the SWIR are two prospective mineralization areas discovered by Chinese scientists. With the aim to determine the mineralogical and chemical characteristics of sulfide minerals, we have conducted detailed studies for samples from the two areas using an optical microscope, X-ray diffractometer, scanning electron microscope, and electron microprobe. The mineralization processes in the Longqi area are divided into three main stages: (1) the low-medium-temperature stage: colloform pyrite (Py I) + marcasite → euhedral pyrite (Py II), (2) the high-temperature stage: isocubanite (±exsolved chalcopyrite) + pyrrhotite → coarse-grained chalcopyrite (Ccp I), and (3) the medium–low-temperature stage: sphalerite + fine-grained chalcopyrite inclusions (Ccp II) → aggregates of anhedral pyrite (Py III) ± marcasite → Fe-oxide (-hydroxide) + amorphous silica. The mineralization processes in the Duanqiao area are divided into two main stages: (1) the medium–high-temperature stage: subhedral and euhedral pyrite (Py I′) → coarse-grained chalcopyrite (Ccp I′) and (2) the medium–low-temperature stage: sphalerite → fine-grained chalcopyrite (Ccp II′) + chalcopyrite inclusions (Ccp II′) → silica-cemented pyrite (Py II′) + marcasite → Fe-oxide + amorphous silica. We suggest that the fine-grained chalcopyrite inclusions in sphalerite from Longqi and Duanqiao were formed by co-precipitation and replacement mechanisms, respectively. Primary sphalerites from both fields are enriched in Fe (avg. 5.84 wt% for the Longqi field vs. avg. 3.69 wt% for the Duanqiao field), Co (avg. 185.56 ppm for the Longqi field vs. 160.53 ppm for the Duanqiao field), and Cd (avg. 1950 ppm for the Longqi field vs. avg. 525.26 ppm for the Duanqiao field). Cu contents in pyrite from the Duanqiao field (Py I′: avg. 849.23 ppm and Py II′: avg. 1191.11 ppm) tend to be higher than those from the Longqi field (Py I: avg. 26.67 ppm, Py II: avg. 445 ppm, and Py III: avg. 179.29 ppm). Chalcopyrite from both fields is enriched in Zn (Ccp I: avg. 3226.67 ppm, Ccp II: avg. 9280 ppm, Ccp I′: avg. 848 ppm, Ccp II′ (inclusions): avg. 1098 ppm, and Ccp II′ (fine-grained): avg. 1795 ppm). The varying contents of Zn in the different pyrite and chalcopyrite generations may result from the zone refining process. An integrated study of the mineralogy and mineralogical chemistry suggests that the hydrothermal fluids of the Longqi area are likely conditioned with higher temperatures and relatively lower fO2 and fS2 than those of the Duanqiao area, but in contrast to the former, the latter is much affected by the compositions of the surrounding rocks.