Formation of Fe-Mn-Si oxide and nontronite deposits in hydrothermal fields on the Valu Fa Ridge, Lau Basin

Hydrothermal Fe-Mn-Si oxides and nontronite are pervasive in the Hine Hina, Vai Lili and Mariner hydrothermal fields along the central Valu Fa Ridge, Lau Basin. Morphometric and mineralogical analyses reveal that the iron-rich filaments are the most important constituents of these Fe-Mn-Si oxide deposits. Both the morphologies and chemical composition of the filaments indicate that neutrophilic Fe-oxidizing bacteria have played a key role in the formation of these deposits. A key process of the formation of these deposits is the creation of a complicated filamentous network in which a series of metabolic activities and passive sorption and nucleation processes occur. The precipitation of dissolved Si in unsaturated and saturated states leads to a “two-generation” growth model in the hydrothermal vents. The precipitation of amorphous opal occurs in a relatively narrow temperature range (41.1-42.9 °C) based on oxygen isotope analyses, indicating a fast precipitation rate of opal-A when conductive cooling of the hydrothermal fluid occurrs. Patchy nontronite in the Mariner fields is a product of the direct precipitation from hydrothermal fluids at a temperature of ∼87.9 °C, whereas the scattered nontronite at the Hine Hina field is the product of the replacement of hydrothermal Fe-Si oxides at a temperature of ∼46.2 °C.     

Geochemistry of basaltic lavas from the southern Lau Basin: input of compositionally variable subduction components

We present new major element, trace element, and Sr–Nd–Pb isotope data for 18 basaltic lavas and six glasses collected in situ from the Eastern Lau Spreading Centre (ELSC) and the Valu Fa Ridge (VFR). All lava samples are aphanitic and contain rare plagioclase and clinopyroxene microlites and microphenocrysts. The rocks are sub-alkaline and range from basalt and basaltic andesite to more differentiated andesite. In terms of trace element compositions, the samples are transitional between typical normal mid-ocean ridge basalt (MORB) and island arc basalt. Samples from the VFR have higher large ion lithophile element/high field strength element ratios (e.g. Ba/Nb) than the ELSC samples. VFR and ELSC Sr–Nd isotopic compositions plot between Indian MORB and Tonga arc lavas, but VFR samples have higher ⁸⁷Sr/⁸⁶Sr for a given ¹⁴³Nd/¹⁴⁴Nd ratio than ELSC analogues. The Pb isotopic composition of ELSC lavas is more Indian MORB-like, whereas that of VFR lavas is more Pacific MORB-like. Our new data, combined with literature data for the Central Lau Spreading Centre, indicate that the mantle beneath the ELSC and VFR spreading centres was originally of Pacific type in composition, but was displaced by Indian-type mantle as rifting propagated to the south. The mantle beneath the spreading centres also was variably affected by subduction-induced metasomatism, mainly by fluids released from the altered, subducting oceanic crust; the influence of these components is best seen in VFR lavas. To a first approximation, the effects of underflow on the composition and degree of partial melting of the mantle source of Lau spreading centre lavas inversely correlate with distance of the spreading centres from the Tonga arc. Superimposed on this general process, however, are the effects of the local geographic contrasts in the composition of subduction components. The latter have been transferred mainly by dehydration-generated fluids into the mantle beneath the Tonga supra-subduction zone.     

U–Pb detrital zircon evidence of transcontinental sediment dispersal: provenance of Late Mississippian Wedington Sandstone member,NW Arkansas

ABSTRACT

U–Pb ages of detrital zircons from the Wedington Sandstone member in northwest Arkansas provide evidence for Late Mississippian westward transcontinental sediment transport from the Appalachian foreland. The Late Mississippian Wedington Sandstone member of the Fayetteville Shale is a fine- to medium-grained quartzarenite. It separates the Fayetteville Shale into informal lower and upper intervals, and was deposited as a small constructive delta complex that prograded towards the south and southeast during the Late Mississippian. As a major influx of clastic sediments, the Wedington Sandstone member records the sediment source and dispersal in the mid-continent during the Late Mississippian. A total of 559 detrital zircon grains from six Wedington samples were recovered for U–Pb detrital zircon geochronological analysis. Results show that age distributions can be subdivided into six groups: ~350–500, ~900–1350, ~1360–1500, ~1600–1800, ~1800–2300, and > ~2500 Ma, and are characterized by a prominent peak for the age group of ~900–1350 Ma, a major peak at ~1600–1800 Ma, and a few other minor age clusters. Regional correlation and geological evidence from surrounding areas suggest that the transcontinental sediment dispersal started as early as the Late Mississippian. U–Pb detrital zircon age distribution suggests that the Wedington Sandstone member was likely derived from the Appalachian foreland with contributions from the Nemaha Ridge to the west where the Yavapai–Mazatzal sources were exposed during the Late Mississippian. Sediment was likely transported westward through or around the Illinois Basin, merged with mid-continent sediment, and then entered into its current location in northwest Arkansas. Transportation of this sediment from mixed sources continued along its course to the south, forming a delta on the Northern Arkansas Structural Platform.     

Fault systems and paleostresses in the Vestfirdir Peninsula. Relationships with the Tertiary paleo-rifts of Skagi and Snaefells (Northwest Iceland)

Abstract

The Vestfirdir Peninsula of northwestern Iceland mainly consists of tholeiitic lava flows, 8–14 Ma old, gently dipping to the southeast. A detailed study of strike-slip and normal faulting allowed identification of two main paleostress regimes. Two sets of normal faults were recognized. The largest set trends ENE-WSW to NNE-SSW; the minor set trends NW-SE to WNW-ESE. Concerning the major extension, the reconstruction of paleostress trajectories shows a gradual change in trend from ESE-WNW, in the northern half of the peninsula, to NNW-SSE to the south. The minor extension also shows a gradual change from NNE-SSW to ENE-WSW trends, from north to south. The nearly constant perpendicularity between the major and minor trends of extension is accounted for by permutation of stress axes within the general pattern of extension related to oceanic rifting. The progressive azimuthal change of the major extension trend, from northeast to southwest across the peninsula, is interpreted as the expression of a change in trend of the extinct Skagi-Snaefells rift, a structure that cannot be reconstructed directly through geological mapping. The average trends of extension in the southern Vestfirdir Peninsula, N150°E, suggest a N60°E trend for the ancient Snaefells rift segment. Likewise, the N100–110°E trends of extension in northern Vestfirdir suggest a N10–20°E trend for the Skagi paleo-rift., © Elsevier, Paris     

The occurrence of gold in hydrothermal sulfide at Southwest Indian Ridge 49.6°E

Massive sulfide precipitates found in the Southwest Indian Ridge(SWIR) 49.6°E hydrothermal field are enriched in gold.Here,the mineralogy and mineral chemistry of these massive sulfides to constrain the process of gold precipitation were studied.Sulfide samples in this field include lowertemperature Zn-rich sulfides and relative higher-temperature Fe-rich sulfides.Zn-rich sulfides are dominated by sphalerite-pyrite-chalcopyrite assemblages,with concentrations of gold ranging from 9.08 to 17.0 μg/g.Fe-rich sulfides consist mainly of pyrite-marcasite-isocubanite assemblages,with gold concentrations from 2.17 to 3.79 μg/g.The significant enrichment in gold within the lowertemperature Zn-rich sulfides and the effective separation of Zn and Fe in hydrothermal precipitates at the surface of this field are here interpreted to reflect the strong temperature dependence of gold transportation and deposition within the sulfides.In Zn-rich samples,large amounts of isolated native gold grains were identified.They were found mainly as inclusions up to 8 μm in diameter,occupying porous cavities in sphalerite or in the elevated iron content rim of sphalerite.The fineness of the gold ranged from 810 to 830.Unlike previously published results on other hydrothermal fields,these data show a low gold fineness values in SWIR 49.6°E.The FeS content of sphalerite associated with gold grains ranged from 3.2 mole % to 18.9 mole %.This was higher than in other fields,indicating that the sulfur activity is relatively low during the gold precipitation process and that sulfur activity may be one of the main factors affecting gold fineness in the SWIR 49.6°E hydrothermal field.Evidence regarding gold fineness and sulfur activity suggests that gold was quite likely transported as AuHS0 rather than as a Au(HS)-2 complex.     

A Quantitative Method for Active Fault Migration Distance Assessment on both Sides of Mid-Ocean Ridges—Based on Multi-Beam Data

Fracture-fissure systems found at mid-ocean ridges are dominating conduits for the circulation of metallogenic fluid. Ascertaining the distribution area of active faults on both sides of mid-ocean ridges will provide a useful tool in the search for potential hydrothermal vents, thus guiding the exploration of modern seafloor sulfides. Considering the Mid-Atlantic Ridge 20°N–24°N (NMAR) and North Chile Rise (NCR) as examples, fault elements such as Fault Spacing (?S) and Fault Heave (?X) can be identified and quantitatively measured. The methods used include Fourier filtering of the multi-beam bathymetry data, in combination with measurements of the topographic slope, curvature, and slope aspect patterns. According to the Sequential Faulting Model of mid-ocean ridges, the maximal migration distance of an active fault on either side of mid-ocean ridges—that is, the distribution range of active faults—can be measured. Results show that the maximal migration distance of active faults at the NMAR is 0.76–1.01 km (the distance is larger at the center than at the ends of this segment), and at the NCR, the distribution range of active faults is 0.38–1.6 km. The migration distance of active faults on the two study areas is positively related to the axial variation of magma supply. In the NCR study area, where there is an abundant magma input, the number of faults within a certain distance is mainly affected by the variation of lithospheric thickness. Here a large range of faulting clearly corresponds to a high proportion of magmatism to seafloor spreading near mid-ocean ridges (M) value, and in the study area of the NMAR, there is insufficient magmatism, and the number of faults may be controlled by both lithospheric thickness and magma supply, leading to a less obvious positive correlation between the distribution range of active faults and M.     

Mineralogy and trace element geochemistry of sulfide minerals from the Wocan Hydrothermal Field on the slow-spreading Carlsberg Ridge,Indian Ocean

The basalt-hosted Wocan Hydrothermal Field (WHF), located on the NW slope of an axial volcanic ridge at a depth of ∼3000 m at 6°22′N on the slow-spreading Carlsberg Ridge, northwest Indian Ocean, was discovered in 2013 during Chinese DY28th cruise. Preliminary investigations show that the field consists of two hydrothermal sites: Wocan-1, which shows indications for recent high-temperature hydrothermal activity, is located near the peak of the axial volcanic ridge at a water depth of 2970–2990 m, and Wocan-2 site, located at a water depth of 3100 m, ∼1.7 km to the northwest of Wocan-1. The recovered hydrothermal precipitates can be classified into four groups: (i) Cu-rich chimneys; (ii) Cu-rich massive sulfides; (iii) Fe-rich massive sulfides; and (iv) silicified massive sulfides. We conducted mineral texture and assemblage observation and Laser-ablation ICP-MS analyses of the hydrothermal precipitates to study the mineralization processes. Our results show that there are distinct systematic trace element distributions throughout the different minerals in the four sample groups. In general, chalcopyrite from the group (i) is enriched in Pb, As, Mo, Ga, Ge, V, and Sb, metals that are commonly referred to as medium- to low-temperature elements. In contrast these elements are present in low contents in the chalcopyrite grains from other sample groups. Selenium, a typical high-temperature metal, is enriched in chalcopyrite from groups (ii) and (iv), whereas Ag and Sn are enriched only in some silicified massive sulfides. As with chalcopyrite, pyrite also shows distinct trace element associations in grains with different habitus. The low-temperature association of elements (Pb, Mo, Mn, U, Mg, Ag, and Tl) is typically present in colloform/framboidal pyrite, whereas the high-temperature association (Se, Co, and Bi) is enriched in euhedral pyrite. Sphalerite in the groups (i) and (iii) at Wocan-1 is characterized by high concentrations of Ga, Ge, Pb, Cd, As, and Sb, indicating that sphalerite in these sample groups likely precipitated at intermediate temperatures. Early bornite, which mainly occurs in the central part of the Cu-rich chimney, is typically enriched in Sn and In compared to the other minerals. In contrast, late bornite that likely formed during increasing interaction of hydrothermal fluids with cold, oxygenated seawater has low Sn and In, but significantly higher concentrations of Ag, Au, Mo and U. Digenite, also forming in the exterior parts of the samples during the late stages of hydrothermal fluid venting, is poor in most trace elements, except Ag and U. The notable Ag enrichment in the late-stage mineral assemblages at both Wocan-1 and Wocan-2 may therefore be related to lower temperatures and elevated pH. Our results indicate that Wocan-1 has experienced a cycle of heating with Cu-rich chimney growth and subsequent cooling, followed by late seafloor weathering, while Wocan-2 has seen intermediate- to high-temperature mineralization followed by intense silicification of sulfides. Seafloor weathering processes or mixing of hydrothermal fluids with seawater during the waning stages of hydrothermal fluid flow result in significant redistributions of trace elements in sulfide minerals.     

扬马延海脊构造-沉积演化及油气潜力

扬马延海脊位于北大西洋的北极圈附近,东格陵兰板块和挪威板块之间,冰岛东北方向。北极地区地域辽阔,油气资源丰富,但是恶劣的环境一直制约油气的勘探进展。在扬马延海脊的沉积演化过程中,扬马延海脊在第三纪前有着和东格陵兰陆架、挪威陆架相似的沉积序列,其构造演化经历了二叠纪陆内裂谷、三叠纪—侏罗纪同裂谷和微陆块漂移、白垩纪至今热沉降和被动陆缘等3个阶段。结合前人研究成果,对搜集的东格陵兰陆架、挪威陆架的油气地质资料分析,认为扬马延海脊可划分为扬马延盆地、扬马延西部构造带、扬马延中部凸起带、扬马延海槽、扬马延东部斜坡、扬马延南部复杂构造带6个构造单元,在其上发育着2套油气系统。同时扬马延海脊发育有伸展构造圈闭、地垒断块圈闭、构造圈闭和地层圈闭,这些圈闭为油气的赋存提供了良好的环境,也有利于划分有利油气勘探区带。研究结果可为进一步分析扬马延海脊构造特征等方面提供基础信息,同时对我国参与研究开发北极油气资源具有重大意义。     

中印度洋脊Edmond热液区成矿流体属性与来源:来自流体包裹体和He-Ar同位素的证据

To understand the source and nature of the ore-forming fluids of the Edmond hydrothermal field on the Central Indian Ridge, we studied the He-Ar isotope composition and fluid inclusions of the hydrothermal precipitates.Our results show that the sulfide samples contain noble gases He, Ne, Kr, and Xe with their abundances in between those of air-saturated water(ASW) and mid-ocean ridge basalt(MORB). The ~3He/~4He ratio varies from1.3 to 8.7 R_a(n=10, average: 5.1 R_a), whereas the ~(40)Ar/~(36) Ar ratio is from 285.3 to 314.7(n=10, average: 294.8). These results suggest that the He was derived from a mixture of MORB with variable amounts of seawater, but the Ar in the ore-forming fluids trapped in the sulfides is predominantly derived from seawater. The fluid inclusions of barite have a wide range of homogenization temperatures and salinities varying from 163°C to 260°C and 2.6 wt%to 8.5 wt% Na Cl equiv., respectively. It is suggested that the ore-forming fluids were produced by phase separation, which agreed with the present-day vent fluid study.