Ca2+、Mg2+对凡纳滨对虾仔虾生存的影响

采用静态急性毒性试验的方法,研究了48h内水质中不同的Ca2 、Mg2 浓度及Ca2 /Mg2 值对凡纳滨对虾(Litopenaeus vannamei)仔虾存活的影响。结果表明,适宜凡纳滨对虾仔虾生存的Ca2 、Mg2 质量浓度分别为30.41～351mg/L和8.72～863mg/L;最适Ca2 /Mg2 值范围为0.15～0.67。     

延边地区明月沟组安山岩的形成时代与岩石成因:锆石U-Pb年代学、地球化学及Hf同位素证据

为确定延边地区明月沟组火山岩的形成时代、成因及构造背景,对明月沟组中的安山岩开展了岩石学、SIMS锆石U-Pb年代学、岩石地球化学及锆石Hf同位素特征研究。结果表明:明月沟组安山岩中的锆石为岩浆成因锆石。代表安山岩形成时代的两件样品中锆石的~(206)Pb/~(238)U加权平均年龄分别为(111±4)Ma(n=6,MSWD=3.2)和(113±3)Ma(n=6,MSWD=1.4),属早白垩世晚期。岩石地球化学特征上,明月沟组安山岩相对富钠,属高钾钙碱性系列,具有明显富集大离子亲石元素(K、Ba)和轻稀土元素,亏损重稀土元素和Ta、Nb等高场强元素的特征,结合其Hf同位素组成特征,暗示明月沟组安山岩的源岩应为受俯冲板片流体成份参与的亏损地幔。结合区域构造演化背景,明月沟组安山岩的形成应与早白垩世古太平洋板块向欧亚大陆板块的斜向俯冲作用相关。     

新疆乌什县卡恰金矿原生晕地球化学异常特征分析

卡恰金矿床属于与火山热液有关的蚀变岩型金矿床,金矿体多呈规模不大的脉状、透镜状、分支脉状等形态分布于构造蚀变带中。文章通过对矿区进行系统的坑道和地表原生晕地球化学取样,分析研究了主要元素的组合、异常特征;对比坑道和地表元素地球化学主要指标变化特征,推测了元素向深部变化的趋势,为矿区深部及外围找矿工作提供了参考依据。     

赣东北蛇绿岩带新元古代(~800Ma)高镁安山岩的发现及其意义

在赣东北蛇绿岩带中的樟树墩地区新发现新元古代高镁安山岩,其LA-ICP-MS锆石U-Pb法年龄为794.8±6.0 Ma。它们的Si O2介于54.90%~58.45%,Al2O3介于15.31%~16.77%(平均小于16%);Ca O为2.46%~6.73%,Fe OT/Mg O变化于0.87~1.20,具有高Mg O(6.39%~8.76%)、高Mg#(64~71)特点;富集轻稀土元素且具弱负Eu异常,明显富集LILE而亏损HFSE,Sr含量(普遍200×10-6)和Sr/Y比值(4.11~7.29)均较低,具有典型高镁安山岩的地球化学特征,类似于日本Setouchi火山带的Sanukitoids。锆石εHf(t)值介于10.23~17.79之间,反映它们起源于亏损地幔。主、微量及同位素特征均表明,本区高镁安山岩是被俯冲板片释放的含水流体交代的地幔楔部分熔融的产物,形成于大洋岛弧(洋内弧)环境,指示赣东北地区在约800Ma前时仍存在洋壳俯冲,双溪坞弧尚未增生到扬子东南缘,暗示扬子和华夏两大陆块此时尚未碰撞拼合。     

新疆阿舍勒铜锌矿区潜玄武安山岩的岩石地球化学特征及其地质意义

对新疆阿舍勒铜锌矿区潜玄武安山岩进行了岩石学、岩石地球化学和同位素地球化学研究,结果表明:岩石具有中等的SiO_2(51.90%~52.85%)、MgO(4.44%~5.08%)、Al_2O_3(14.94%~16.11%)、TiO_2(0.99%~1.03%)含量,较低的K_2O(0.01%~0.27%)含量,属于低钾拉斑玄武岩系列;岩石具有较低的稀土元素总量,ΣREE=38.07×10~(-6)~41.70×10~(-6),亏损轻稀土元素,LREE/HREE=0.57~0.61,(La/Yb)N=0.84~0.91,具有明显Eu正异常(δEu=1.13~1.23);富集Sr、Ba、Th等大离子亲石元素,亏损Nb、Ta、Zr、Hf等高场强元素,具有洋中脊玄武岩(MORB)和岛弧拉斑玄武岩(IAB)的特征,形成于岛弧(或弧前)环境;具有相对高的εNd(t)值(+6.9~+7.6),表明其原始岩浆来源于俯冲流体交代地幔楔的部分熔融,没有明显深海沉积物加入。结合阿尔泰造山带南缘的区域地质资料及潜玄武安山岩的地球化学特征,认为阿尔泰南缘在晚古生代处于活动大陆边缘,阿舍勒盆地处于岛弧(或弧前)背景。     

松潘-甘孜褶皱带复理石火山岩夹层时代及其地质意义

在四川北部松潘西北和甘肃南部合作市一带的上三叠统(深海沉积)复理石中发现了数套火山(碎屑)岩夹层。利用UPb同位素测年,获得4件安山岩、凝灰岩样品锆石的年龄加权平均值分别为205.9±1.6Ma、208.9±1.8Ma、210.4±1.6Ma和212.3±1.5Ma,时代属于晚三叠世诺利期晚期—瑞提期早期。此系第一次较为精准地报道松潘-甘孜褶皱带晚三叠世复理石火山岩夹层及其可能代表的火山喷发年龄。研究结果表明,直到瑞提期早期松潘-甘孜古残留海盆还未停止接受沉积物供给。该套火山(碎屑)岩的测年结果为松潘-甘孜褶皱带上三叠统复理石岩石地层单元的划分和对比提供了重要参考,同时为进一步约束华南与华北板块碰撞-造山事件时限提供了新证据。     

Anomalous drip in the Punkva caves (Moravian Karst): relevant implications for paleoclimatic proxies

The anomalous drip in the Punkva caves (Moravian Karst) shows specific hydrogeochemical properties such as low SI_calcite ~ 0.14 ± 0.11 (standard deviation), low mineralization (4.53 ± 0.42) × 10^?3 mol l^?1, and enhanced values of δ¹³C (?7.85 to ?8.35‰ VPDB), Mg/Ca × 1000 ratio (45.7 ± 3.3), and Sr/Ca × 1000 ratio (0.65 ± 0.06). By these properties, the anomalous drip significantly differs from other regular drips in the same cave and other caves in the region. The study suggests that the anomalous drip properties are a consequence of prior calcite precipitation or/and water mixing along the water flow path. As the former processes are spatially controlled, the knowledge of dripwater flow path seems to be necessary for correct paleoclimatic/paleoenvironmental reconstructions. Copyright © 2015 John Wiley & Sons, Ltd.     

Time-series of δ26Mg values in a headwater catchment reveal decreasing magnesium isotope variability from precipitation to runoff

Data on temporal variability in Mg isotope ratios of atmospheric deposition and runoff are critical for decreasing the uncertainty associated with construction of isotope mass balances in headwater catchments, and statistical evaluation of isotope differences among Mg pools and fluxes. Such evaluations, in turn, are needed to distinguish between biotic and abiotic contributions to Mg²⁺ in catchment runoff. We report the first annual time-series of δ²⁶Mg values simultaneously determined for rainfall, canopy throughfall, soil water and runoff. The studied 55-ha catchment, situated in western Czech Republic, is underlain by Mg-rich amphibolite and covered by mature spruce stands. Between 1970 and 1996, the site received extremely high amounts of acid deposition and fly ash form nearby coal-burning power plants. The δ²⁶Mg values of open-area precipitation (median of −0.79‰) at our study site were statistically indistinguishable from the δ²⁶Mg values of throughfall (−0.73‰), but significantly different from the δ²⁶Mg values of soil water (−0.55‰) and runoff (−0.55‰). The range of δ²⁶Mg values during the observation period decreased in the order: open-area precipitation (0.57‰) > throughfall (0.27‰) > runoff (0.21‰) > soil water (0.16‰). The decreasing variability in δ²⁶Mg values of Mg²⁺ from precipitation to soil water and runoff reflected an increasing homogenization of atmospheric Mg in the catchment and its mixing with geogenic Mg. In addition to atmospheric Mg, runoff also contained Mg mobilized from the three major solid Mg pools, bedrock (δ²⁶Mg of −0.32‰), soil (−0.28‰), and vegetation (−0.31‰). The drought of summer 2019 did not affect the nearly constant δ²⁶Mg value of runoff. Collectively, our data show that within-catchment processes buffer the Mg isotope variability of the atmospheric input.     

Generation of calc-alkaline andesite of the Tatun volcanic group (Taiwan) within an extensional environment by crystal fractionation

The Pliocene–Pleistocene northern Taiwan volcanic zone (NTVZ) is located within a trench-arc–back-arc basin and oblique arc–continent collision zone. Consequently the origin and tectonic setting of the andesitic rocks within the NTVZ and their relation to other circum-Pacific volcanic island-arc systems is uncertain. Rocks collected from the Tatun volcanic group (TTVG) include basaltic to andesitic rocks. The basalt is compositionally similar to within-plate continental tholeiites whereas the basaltic andesite and andesite are calc-alkaline; however, all rocks show a distinct depletion of Nb-Ta in their normalized incompatible element diagrams. The Sr-Nd isotope compositions of the TTVG rocks are very similar and have a relatively restricted range (i.e. I_Sr = 0.70417–0.70488; εNd_(T) = +2.2 to +3.1), suggesting that they are derived directly or indirectly from the same mantle source. The basalts are likely derived by mixing between melts from the asthenosphere and a subduction-modified subcontinental lithospheric mantle (SCLM) source, whereas the basaltic andesites may be derived by partial melting of pyroxenitic lenses within the SCLM and mixing with asthenospheric melts. MELTS modelling using a starting composition equal to the most primitive basaltic andesite, shallow-pressure (i.e. ≤1 kbar), oxidizing conditions (i.e. FMQ +1), and near water saturation will produce compositions similar to the andesites observed in this study. Petrological modelling and the Sr-Nd isotope results indicate that the volcanic rocks from TTVG, including the spatially and temporally associated Kuanyinshan volcanic rocks, are derived from the same mantle source and that the andesites are the product of fractional crystallization of a parental magma similar in composition to the basaltic andesites. Furthermore, our results indicate that, in some cases, calc-alkaline andesites may be generated by crystal fractionation of mafic magmas derived in an extensional back-arc setting rather than a subduction zone setting.     

颗石藻元素地球化学研究进展

颗石藻元素地球化学研究在古海洋学研究中有着重要意义。目前开始研究的主要有Sr/Ca和Mg/Ca比值。研究发现,颗石的Sr/Ca比值主要受颗石藻生长和钙化速度控制,其次受温度影响;而Mg/Ca比值主要与温度有关,属种间受影响程度有差别。样品清洗和单种分离是颗石藻元素地球化学分析的重点和难点。倒置显微镜挑出单种颗石是目前最为方便且准确的分析方法。颗石Sr/Ca比值可以用来反映古生产力,Mg/Ca比值可以用来重建古温度。