激进地理学的形成和演变——以《异端的传统》为例

当前国内对激进地理学的研究相当有限。从方法论角度,通过选取激进地理学的代表作《异端的传统》为案例,在分析其背景的基础上,从激进地理学的理论、实践以及它与马克思主义的关系等方面总结和提炼了激进地理学的发展历程与要点,评价了该文的方法论涵义,并总结了它对中国地理学方法论研究的启示。该案例剖析表明,激进地理学是资本主义危机和实证主义地理学存在内在缺陷的背景下产生;其理论前提在于地理学家固有的种族-阶级属性使地理学成为科学实证和文化属性相结合的产物;激进地理学家主要通过创办刊物、建立团体、开展运动树立了激进主义学派,使它由"异端"成为传统;马克思主义是多数激进地理学家的理论选择;批判和自我批判基础上的重构可能是当今和未来地理学方法论创新的主要途径。中国应该积极开展激进地理学和马克思主义地理学的理论研究和实践活动。     

Relative-rate study of the gas-phase reaction of hydroxy radicals with difunctional organic nitrates at 298 K and atmospheric pressure

Rate coefficients for the reactions of difunctional nitrates with atmospherically important OH radicals are not currently available in the literature. This study represents the first determination of rate coefficients for a number of C(3) and C(4) carbonyl nitrates and dinitrates with OH radicals in a 38 l glass reaction chamber at 1000 mbar total pressure of synthetic air by 298±2 K using a relative kinetic technique.The following rate coefficients (in units of 10^-12 cm³ molecule^-1 s^-1) were obtained: 1,2-propandiol dinitrate, <0.31; 1,2-butandiol dinitrate, 1.70±0.32; 2,3-butandiol dinitrate, 1.07±0.26; -nitrooxyacetone, <0.43; 1-nitrooxy-2-butanone, 0.91±0.16; 3-nitrooxy-2-butanone, 1.27±0.14; 1,4-dinitrooxy-2-butene, 15.10±1.45; 3,4-dinitrooxy-1-butene, 10.10±0.50.The possible importance of reaction of OH as an atmospheric sink for the compounds compared to other loss processes is considered.     

范各庄井田奥灰水NO^—3离子形成机理及在水源判别中的应用

在分析范各庄井田水文地质特征的基础上,利用水文地球化学理论初步探讨了奥陶系灰岩含水层地下水中赋存高含量ＮＯ－３离子的形成机理,介绍了应用这一水化学特征分析矿井充水条件的方法。     

泉州湾湿地南方碱蓬种子水提物总黄酮含量及其抗氧化能力评价

以聚酰胺吸附—硝酸铝显色法测定泉州湾湿地南方碱蓬(Suaeda australis)种子水提物的总黄酮含量,并测定评价其在羟基自由基体系、二苯代苦肼自由基(DPPH·)体系、超氧阴离子自由基体系中的抗氧化活性。结果表明,南方碱蓬种子水提物得率为18.49%;水提物的总黄酮含量为2.74%,显著大于95%乙醇提取物(1.94%)、丙酮提取物(0.62%)、乙酸乙酯提取物(0.51%)、甲醇提取物(0.37%)和石油醚提取物(0.10%)的总黄酮含量。在不同的自由基体系中,南方碱蓬种子水提物对超氧阴离子自由基的清除作用相对很弱,在水提物的浓度为153mg/mL时,清除率仅为30%;但其对羟基自由基的清除能力较强,在施测浓度为20mg/mL时,水提物对羟基自由基的清除率达79.50%,弱于95%乙醇提物(90.98%),强于乙酸乙酯提物(70.35%)、丙酮提物(68.40%)、甲醇提物(65.50%)和石油醚提物(63.18%),其半效应浓度为0.53mg/mL;水提物对二苯代苦肼自由基的清除呈现明显的量效关系,当水提物浓度为200mg/mL时,对二苯代苦肼自由基的清除率可达92.44%,其半效应浓度为57.56mg/mL。可见,南方碱蓬种子水提物具有较高的总黄酮含量和一定的抗氧化能力,具有作为植物源抗氧化剂开发的潜在价值。     

NUMERICAL MODELING OF CUMULUS CLOUD CHEMISTRY—PART Ⅱ:THE IMPACT OF CUMULUS CLOUD PROCESSES ON OZONE CHEMISTRY

Ozone chemistry processes are analyzed during a cumulus cloud process with the model(1CCCM)described in Part Ⅰ.The simulation results show that entire cumulus cloud process can bewell described with the development of vertical velocities and liquid water content which are the twomost outstanding features of cumulus clouds.Ozone chemistry is strongly influenced by cumulusclouds.NO_x can be transported upwards above 4 km in the first 20 minutes of the convection eventand form a relative higher concentration area which enhances the production of ozone.Two areas ap-pear during the convection event:area of net ozone production and area of net ozone depletion.Thearea of ozone depletion coincides with the area of liquid water within cloud.Results show that theaqueous phase(cloud water and rainwater)can alter gas ozone level through two ways:one is scav-enging free radicals(HO_2)from the gas phase and thereby inhibiting the reactions of transformationto NO_2 from NO,which results in reduction of the gas source of ozone;the other is aqueous phasechemical reactions which consume ozone in the aqueous phase.Calculations reveal that the reaction O_3+OH→HO_2 is the main pathway of ozone depletion in gas phase during the process of cumulusclouds.     

A study of the vertical distribution of methyl chloride (CH3Cl) in the midlatitude stratosphere

The vertical distribution of the CH₃Cl mixing ratio in the stratosphere has been measured from samples collected during two balloon flights on the 21 October 1982 and 10 September 1983. Measurements were made with two analytical techniques that were also employed for previous analyses of stratospheric samples: gas chromatography (GC) and a gas chromatograph/mass spectrometer (GC/MS) combination. The results from all balloon flights performed to date are combined to derive an average experimental profile of CH₃Cl at midlatitudes. The profile shows that the CH₃Cl mixing ratio decreases by about one order of magnitude between 20 and 30 km altitude. A comparison of the new observations with model profiles reveals discrepancies in the lower stratosphere that amount to a factor of about 3. Possible causes for these discrepancies are discussed.     

基于AIC准则的RBF神经网络在GPS高程拟合中的应用

本文采用AIC准则优化RBF神经网络参数的方法进行GPS高程拟合,在建立网络模型过程中,对不同的聚类半径由最近邻聚类法求出不同类别的聚类数目及相应的聚类中心和初始扩展常数,通过对不同类别分别进行调整扩展常数的网络训练,求出其最小AIC值,再根据AIC准则确定结构最优的RBF网络模型。实验结果表明:这种方法为确定最优RBF网络模型的隐节点数目及相应参数提供了途径;拟合精度较高,在较平坦测区可以替代三等水准测量。     

遗传根群类和半单群类

针对Li X.M分别给出的根群类和半单群类的若干特征性质,提出了根群类和半单群类之间应具有的联系。通过群的一类特殊的正规子群:本质正规子群将根群类和半单群类联系起来,并利用群的根性的一般理论,得到了两个结果:根群类P是遗传的当且仅当其对应的半单群类L是本质扩张闭的;当根群类P是遗传根群类时,根群类P和其对应的半单群类L所决定的群类M是根群类。     

Mineralization of Catechol by Fenton and Photo‐Fenton Processes

Catechol is one of the most abundant phenolic components of olive mill wastewaters. In this article, the mineralization of this compound in synthetic aqueous solutions by the Fenton and photo‐Fenton processes is studied. It has been found that for 1.44 mM catechol, the total organic carbon of solutions is reduced about 94.4% at best after 60 min of Fenton treatment at optimized conditions of pH 3.0, 0.2 mM Fe²⁺, 7.09 mM H₂O₂, and 25°C. A faster and overall mineralization is attained by applying photo‐Fenton with UVA irradiation. o‐Benzoquinone, 1,2,3‐trihydroxybenzene and 1,2,4‐trihydroxybenzene were identified by GC–MS as primary quinonic and polyhydroxylated derivatives. Small amounts of generated carboxylic acids like muconic, maleic, malonic, acetic, oxalic, and formic acids were detected by ion‐exclusion chromatography. The Fe(III) complexes of these acids persist in the medium under Fenton conditions, while their photolysis by UVA light and that of other by‐products account for by the faster degradation and total mineralization achieved in the photo‐Fenton process. A reaction sequence for catechol mineralization by Fenton and photo‐Fenton involving all intermediates detected is proposed.