变质地质学中的扩散：原理、前沿应用和问题

变质地质学的研究离不开变质反应动力学。元素扩散具有完备的数理基础和丰富的实验数据, 相对成熟地应用于变质地质学, 是目前变质反应动力学的研究热点。本文从变质岩石学的视角, 对扩散的基本数理原理、矿物元素扩散系数及其影响因素、扩散在变质地质学中的应用及其存在的问题做了系统的介绍和总结。本文强调, 元素扩散是变质岩中普遍存在的动力学过程, 一方面会改造矿物原始的生长环带, 给传统温压计和相平衡模拟确定温压条件造成困恼, 另一方面也给变质作用的研究带来动力学视角, 为限定变质-构造热事件的时间尺度和速率提供精准的标尺, 比如扩散速率计或者扩散年代学。扩散这种动力学方法在变质地质学中的应用和进一步发展仍需未来工作。

     

基于相对资源承载力信息的主体功能区划分研究——以长江流域为例

在主体功能区划分的现有研究中,大多数学者将重点放在了多级指标的选取和权重的设置上,因而造成标准过于繁冗、应用受限的问题。通过考查资源承载力与主体功能区的内在联系,将主体功能区的划分建立在区域资源承载力的测度之上,构建了基于相对资源承载力的主体功能区划分模型。将这一模型运用于长江流域,得出如下结论:在全国层面上,长江上游地区应划为重点开发区;在区域层面上,重庆、四川为优化开发区,云南、贵州为重点开发区。     

四川盆地西部富钾卤水水文地球化学特征及其成因意义探讨

四川盆地西部宫钾卤水以深层卤水形式赋存于地下４０００余ｍ的中三叠统雷口坡组四段（Ｔ２ｌ４）盐系的碳酸盐岩储层中。富钾卤水与海水不同浓缩阶段相比，其中含Ｋ＋含量异常高，构成液态钾矿资源；Ｂｒ－、Ｉ－、Ｂ（３＋）、Ｌｉ＋等稀有组分也远超过综合利用工业品位，为优质化工原料水。富钾卤水为沉积变质和钾盐溶滤的复合成因，具有固夜态找钾的指示意义。本文为四川盆地固液态找钾提供了有价值的线索。     

Zircon U–Pb ages, Hf and O isotopes constrain the crustal architecture of the ultrahigh-pressure Dabie orogen in China

The crustal structure of the Dabie orogen was reconstructed by a combined study of U–Pb ages, Hf and O isotope compositions of zircons from granitic gneiss from North Dabie, the largest lithotectonic unit in the orogen. The results were deciphered from metamorphic history to protolith origin with respect to continental subduction and exhumation. Zircon U–Pb dating provides consistent ages of 751 ± 7 Ma for protolith crystallization, and two group ages of 213 ± 4 to 245 ± 17 Ma and 126 ± 4 to 131 ± 36 Ma for regional metamorphism. Majority of zircon Hf isotope analyses displays negative ε_Hf(t) values of − 5.1 to − 2.9 with crust Hf model ages of 1.84 to 1.99 Ga, indicating protolith origin from reworking of middle Paleoproterozoic crust. The remaining analyses exhibit positive ε_Hf(t) values of 5.3 to 14.5 with mantle Hf model ages of 0.74 to 1.11 Ga, suggesting prompt reworking of Late Mesoproterozoic to Early Neoproterozoic juvenile crust. Zircon O isotope analyses yield δ¹⁸O values of − 3.26 to 2.79‰, indicating differential involvement of meteoric water in protolith magma by remelting of hydrothermally altered low δ¹⁸O rocks. North Dabie shares the same age of Neoproterozoic low δ¹⁸O protolith with Central Dabie experiencing the Triassic UHP metamorphism, but it was significantly reworked at Early Cretaceous in association with contemporaneous magma emplacement. The Rodinia breakup at about 750 Ma would lead to not only the reworking of juvenile crust in an active rift zone for bimodal protolith of Central Dabie, but also reworking of ancient crust in an arc-continent collision zone for the North Dabie protolith. The spatial difference in the metamorphic age (Triassic vs. Cretaceous) between the northern and southern parts of North Dabie suggests intra-crustal detachment during the continental subduction. Furthermore, the Dabie orogen would have a three-layer structure prior to the Early Cretaceous magmatism: Central Dabie in the upper, North Dabie in the middle, and the source region of Cretaceous magmas in the lower.     

渤东凹陷东南斜坡构造变换带识别及其石油地质意义

根据渤东凹陷斜坡带新钻井以及新采集的三维地震等勘探资料,采用构造样式解剖、断裂分析以及油气成藏规律分析等方法研究构造变换带特征及其石油地质意义。结果表明,渤东凹陷东南斜坡带上存在构造变换带,此变换带具有调节局部构造变形和分割构造带的作用,把斜坡带分割为西、中、东3个整体呈NE向的似花状构造带。变换带对于明下段极浅水三角洲沉积体展布具有一定控制作用,是砂体形成岩性尖灭的有利场所,同时,近SN向变换断层对NEE向断裂的封堵易形成构造圈闭、构造—岩性圈闭,具有较大的勘探潜力。3个似花状构造带的南部3条断层的断面与地层呈顺向配置,形成断面汇聚脊到顺向地层的优势运移路径,同时受到南部呈雁行排列的密集断裂带的阻挡,形成了研究区一条似花状构造内部的优势运聚范围,最终在渤东凹陷东南斜坡带上形成密集断裂带横向遮挡的主控断层—地层产状耦合油气富集模式。     

Amphibole Ar/Ar Geochronology from the Okcheon Metamorphic Belt, South Korea and its Tectonic Implications

An understanding of the Okcheon Metamorphic Belt (OMB) in South Korea is central to unraveling the tectono-metamorphic evolution of East Asia. Amphibole-bearing rocks in the OMB occur as calcsilicate layers and lenses in psammitic rocks, in the psammitic rocks themselves, and in the mafic volcanic layers and intrusives. Most amphiboles fail to show ⁴⁰Ar/³⁹Ar plateau ages; those that do have ages ranging from 132 to 975 Ma. The disturbed age pattern and wide variation in ⁴⁰Ar/³⁹Ar ages can be related to metamorphic grade, retrograde chemical reactions, excess Ar and amphibole composition. The oldest age (975 Ma) can be interpreted either as an old igneous or metamorphic age predating sedimentation or a false age caused by excess Ar. The youngest age of 132 Ma and the disturbed age pattern found in amphiboles from rocks located close to Jurassic granitoids are the result of retrograde thermal metamorphic effects accompanying intrusion of the granitoids. Some medium- or coarse-grained amphiboles in the calcsilicates are aggregates of fine-grained crystals. As a result, they are heterogeneous and prove to be readily affected by excess Ar. A disturbed age pattern in amphiboles from the calcsilicates occurring in the high-grade metamorphic zone may also be the product of excess Ar. On the other hand, the disturbed pattern of amphiboles present in the calcsilicates from the low-grade metamorphic zone could arise from both excess Ar and mixed ages. However, amphiboles from psammitic rocks and some calcsilicates in the high-grade metamorphic zone and in intrusive metabasites display real plateau ages of 237 to 261 Ma. The temperature conditions in the high-grade metamorphic zone were higher than the argon closing temperature for amphibole, and the amphiboles in this zone give plateau ages only when they are homogeneous in composition, lack excess Ar, and have not been thermally affected by intrusion of the granitoids. The unmodified ⁴⁰Ar/³⁹Ar ages prove rather younger than the age of the Late Paleozoic metamorphic event of 280 to 300 Ma, but they are close to muscovite K-Ar ages of 263 to 277 Ma. These ⁴⁰Ar/³⁹Ar amphibole ages are interpreted as the time of cooling that followed the main regional, intermediate-P/T metamorphic climax. The results demonstrate that interpretation of ⁴⁰Ar/³⁹Ar amphibole ages in an area subjected to several metamorphic events can be accomplished only by undertaking a thorough tectono-metamorphic study, accompanied by detailed chemical analysis of the amphiboles.     

Tectonique transpressive en terre Adélie au Paléoprotérozoı̈que (Est Antarctique)Palaeoproterozoic transpression in Terre Adélie (East Antarctica)

The Palaeoproterozoic units of Terre Adélie show two types of structural domains associated with HT–LP metamorphic conditions: domes and NS–N340° striking vertical shear zones. Shear zones reflect dextral transpressive motions. Domes reflect sub-vertical shortening and principal stretching subparallel to shear zones. They could partly result from longitudinal flow coeval with transpression. Deformations are comparable to those described along the eastern and western boundaries of the Archean Gawler Craton (South-East Australia), which underlines the continuity between these two areas before opening of the Austral Ocean. To cite this article: A. Pelletier et al., C. R. Geoscience 334 (2002) 505–511.     

鄂北—豫南地区榴辉岩相岩石变质作用演化特征

鄂北－豫南地区榴辉岩相变质岩石类型多样,其野外产状和岩石化学特征反映了原地变质成因。根据区域地质及榴辉岩相变质岩石的野外产状,结合榴辉岩中石榴石绿辉石的Ｆｅ２＋－Ｍｇ互换温度计所计算出的峰期变质温度,将本区榴辉岩分为两类,一类为中温榴辉岩,产于晚太古界—早元古界大别群,为Ｂ类榴辉岩,由绿帘角闪岩相岩石进变质形成。榴辉岩相变质作用分为两阶段,首先为柯石英榴辉岩相阶段,其峰期变质条件为Ｔ＝６００℃～７００℃,Ｐ＝２．７～３．０ＧＰａ,然后近等温降压,出现蓝闪石等含水矿物,为蓝闪石榴辉岩相阶段,此时水活度在榴辉岩相变质过程中起着重要作用;另一类为低温榴辉岩,产于中元古界七角山组,为Ｃ类榴辉岩,由蓝片岩相岩石进变质形成,其峰期变质条件为Ｔ＝４９０℃～５６０℃,Ｐ＜１．５ＧＰａ。中温榴辉岩与低温榴辉岩具有不同的变质作用特征。最后讨论了本区高压变质带的成因演化。     

三江源地区水资源的涵养和保护

分析了三江源区水资源现状,论述了建立水资源三级保护区的意义、作用和划分方案,实施林草植被的保护和恢复的水文生态效益及健全水资源补偿机制的必要性。