吉林东部延吉地区中生代火山岩地球化学特征

吉林东部延吉地区大面积出露的中生代火山岩,根据岩性特征可分为三个火山喷发旋回。各旋回火山岩均属ＳｉＯ２过饱和的中基性—中酸性岩类。从第一旋回至第三旋回岩石碱度变化较大,岩浆分异明显,特别是第三旋回分异作用明显高于第一、二旋回。火山岩中金、铜微量元素的平均含量普遍高于同类岩石的克拉克值几倍至几十倍,而且随着岩浆分异程度的升高,其平均含量有明显升高的趋势,为本区金、铜矿床的形成提供了物质来源。     

Determination of characteristics of steam reservoirs by Radon-222 measurements in geothermal fluids

The authors conducted a Rn²²² survey in wells of the Larderello geothermal field (Italy) and observed considerable variations in concentrations. Simple models show that flow-rate plays an important part in the Rn²²² content of each well, as it directly affects the fluid transit time in the reservoirs. Rn²²² has been sampled from two wells of the Serrazzano area during flow-rate drawdown tests. The apparent volume of the steam reservoir of each of these two wells has been estimated from the Rn²²² concentration versus flow-rate curves.List of symbols Q Flow-rate (kg h^–1) - Decay constant of Rn²²² (=7.553×10^–3 h^–1) - Porosity of the reservoir (volume of fluid/volume of rock) - ₁ Density of the fluid in the reservoir (kg m^–3) - ₂ Density of the rock in the reservoir (kg m^–3) - M Stationary mass of fluid filling the reservoir (kg). - E Emanating power of the rock in the reservoir (nCi kg _rock ^–1 h^–1). - P Production rate of Rn²²² in the reservoir: number of atoms of Rn²²² (divided by 1.764×10⁷) transferred by the rock to the mass unit of fluid per unit time (nCi kg _fluid ^–1 h^–1). - N Specific concentration of Rn²²² in the fluid (nCi kg^–1) - Characteristic time of the steam reservoir at maximum flow-rate (=M/Q)     

The effect of water on stress relaxation of faulted and unfaulted sandstone

A series of stress relaxation experiments have been carried out on faulted and intact Tennessee sandstone to explore the influence of pore water on strength at different strain rates. Temperatures employed were 20, 300 and 400°C, effective confining pressure was 1.5 kb and strain rates as low as 10^–10 sec^–1 were achieved. Most samples were prefaulted at 2.5 kb confining pressure and room temperature. This is thought to have secured a reproducible initial microstructure.The strength of the dry rock was almost totally insensitive to strain rate in the range 10^–4 to 10^–10 sec^–1. In contrast, the strength of the wet rock decreased rapidly with strain rate at rates less than 10^–6 sec^–1. Brittle fracture of the quartz grains which constitute this rock is the most characteristic mode of failure under the test conditions used.The experimental data are discussed in terms of the possible deformation rate controlling processes, and it is suggested that in the wet experiments at intermediate to high strain rates (10^–7 to 10^–4 sec^–1) the observed deformation rate is controlled by the kinetics of water assisted stress corrosion, whilst deformation at low strain rates (ca. 10^–9 sec^–1) is controlled by a pressure solution process.The results have implications for the rheology of fault rocks at depths of perhaps 10 to 15 km in sialic crust.     

Transient creep and semibrittle behavior of crystalline rocks

We review transient creep and semibrittle behavior of crystalline solids. The results are expected to be pertinent to crystalline rocks undergoing deformation in the depth range 5 to 20 km, corresponding to depths of focus of many major earthquakes. Transient creep data for crystalline rocks at elevated temperatures are analyzed but are poorly understood because of lack of information on the deformation processes which, at low to moderate pressure, are likely to be semibrittle in nature. Activation energies for transient creep at high effective confining pressure are much higher than those found for atmospheric pressure tests in which thermally-activated microfracturing probably dominates the creep rate. Empirical transient creep equations are extrapolated at 200° to 600°C, stresses from 0.1 to 1.0 kbar, to times ranging from 3.17×10² to 3.17×10⁸ years. At the higher temperatures, appreciable transient creep strains may take place but the physical significance of the results is in question because the flow mechanisms have not been determined. The purpose of this paper is to stimulate careful research on this important topic.     

Stress in the lithosphere: Inferences from steady state flow of rocks

Mechanical data and flow processes from steady state deformation experiments may be used to infer the state of stress in the lithosphere and asthenosphere. Extrapolations of flow equations to a representative geologic strain rate of 10^–14/sec. for halite, marble, quartzite, dolomite, dunite and enstatolite are now warranted because the steady state flow processes in the experiments are identical to those in rocks and because the geotherms are reasonably well established. More direct estimates are obtained from free dislocation densities, subgrain sizes and recrystallized grain sizes all of which are functions only of stress. Using the last of these techniques, we have estimated stress profiles as a function of depth from xenoliths in basalts and kimberlites, whose depths of equilibration were determined by pyroxene techniques, from four different areas of subcontinental and suboceanic upper mantle. The results are similar and indicate stress differences of about 200 to 300 bars at 40 to 50 km, decaying to a few tens of bars at depths betow 100 km. These stresses are reasonable and are in accord with extrapolations of the mechanical data provided that allowance is made for a general increase in strain rate and decrease in viscosity with depth.     

Reconstruction of protoliths of metamorphic rocks and tectonic setting of Wolegen Group

Parametamorphic rocks from Arong County in southeastern Inner Mongolia-Daxinganling district are regarded as Proterozoic in age,belonging to the Wolegen Group and composed of volcanoclastic and sandstone in origin,and have been disputed in tectonic setting.Because of the stability in metamorphism,the rare earth dements indicate the features of their protoliths.The authors integrated the petrologic methods with the geochemical parameters which include ∑REE,∑LREE/∑HREE,δCe,δEu,La/Yb,Sm/Nd,Th/Sc and the standard values of chondrite.The results show that the protoliths of Wolengen Group may be a group of voleanoclastic and continental margin elastic rocks,and their tectonic setting is the continent island arc.     

Zircon U-Pb dating of intermediate-acid intrusive rocks in the middle section of Ningzhen district and their metallogenic implicationsEI北大核心CSCD

The Ningzhen metallogenic district is an important part of the Middle-Lower Yangtze River Valley metallogenic belt. LA-ICP-MS zircon U-Pb dating of the three intermediate-acid intrusions, i.e., Anjishan, Xinqiao, and Shima, in the central part of the Ningzhen district, indicates that those intrusions were emplaced in the Late Early Cretaceous, with ages of 107.0±1.1 Ma-108.0±1.6 Ma, 108.0±1.3 Ma, and 102.5±1.1 Ma, respectively. Combined with the molybdenite Re-Os isotope age (106-108 Ma) of porphyry copper deposit in this regions, the Ningzhen district exists an intensively magmatic-metallogenic-thermal event at 102.5-108.0 Ma. The age of this event is similar with the age of the third period of large scale mineralization in South China, however obviously later than the magmatic activity of other ore field (124-148 Ma) in the Middle-Lower Yangtze River Valley metallogenic belt. It is suggested that the tectonic-magmatic-thermal events in the Ningzhen area is formed under regional lithospheric extension environment, which is also consistent with the tectonic background of the third period of large scale mineralization in South China. The zircon U-Pb ages of the intrusions and the Re-Os ages of molybdenites from the porphyry deposits in the study area demonstrate that the Ningzhen district underwent intensive magmatism and hydrothermal mineralization during the period from 102.5 to 108.0 Ma, which is consistent with the third pulse of large scale mineralization in the South China. ©, 2015, Science Press. All right reserved.     

Characteristics and origin of carbon isotopes of n-alkanes in crude oils from the western Pearl River Mouth Basin,South China sea

The quantitative characterization of carbon isotopes of n-alkanes is commonly carried out in organic geochemical studies. Possible controls on carbon isotopes include source organic matter, maturity, fractionation during oil expulsion and migration, and the mixing of different oils. In this study of the origin of crude oils in the western Pearl River Mouth Basin, the influences of all of these factors have been considered in reaching a conclusion. Carbon isotopes of n-alkanes in the crude oils, and the extracts of the two effective source rocks (the Wenchang and Enping formations) in the basin, exhibit clear differences. The Wenchang source rocks have heavy δ¹³C values that remain almost constant or become slightly heavier with increasing carbon number. The Enping source rocks have light δ¹³C values that become lighter with increasing carbon number. Two groups of oils in this area were identified based on the carbon isotopes of the n-alkanes; groupIoils are similar to extracts of the Wenchang source rocks. However, the groupIIoils are different from both the Wenchang and Enping source rocks and the carbon isotopic profiles of their n-alkanes exhibit a “V” feature with increasing carbon number. The results of artificial thermal maturation experiments indicate that, from the early stage to the peak stage of oil generation (with EasyRo between 0.64% and 1.02%), the δ¹³C values of n-alkanes in the pyrolysis oils become heavier by about 3‰ with increasing thermal maturity, but the shape of the carbon isotopic profiles are not significantly changed. Calculated δ¹³C values of n-alkanes in “mixed” artificial pyrolysis oils indicate that the mixture of oils generated from the same source rocks with different maturities could not change the carbon isotopic profile of the n-alkanes, however, a mixing of the Wenchang and Enping oils could give the “V” feature in the profiles, similar to the groupIIoils in this area. The groupIIoils appear to be mixed Wenchang and Enping oils, the latter being the dominant component in the mixture. We conclude that the source organic matter and the degree of mixing are the main factors controlling the carbon isotopic characteristics of n-alkanes in crude oils in the western Pearl River Mouth Basin.     

塔里木克拉通北缘阔克塔格西富碱侵入岩成因及其构造意义——锆石U- Pb年代学、岩石地球化学及Sr- Nd- Hf- O同位素制约

富碱侵入岩具有深源浅成的属性,是示踪地幔组成的窗口。位于东天山与塔里木克拉通北缘交界处的阔克塔格以西出露一处以正长岩为主体、包含少量中—基性岩石单元的富碱侵入岩。LA- ICP- MS锆石U- Pb测年显示其侵位于227~224 Ma之间,为印支期岩浆作用产物。该岩体具有富碱（Na2O+K2O=7. 93%~ 12. 28%）、富铝（Al2O3=15. 62%~18. 67%）、贫镁（MgO=0. 12%~4. 01%）、贫钛（TiO2=0. 14%~1. 63%）的特征,属于准铝质的（A/CNK=0. 78~1. 00）高钾钙碱性—钾玄岩系列。微量元素表现出高场强元素Nb、Ta、Th、U、Zr、Hf的富集,不相容元素Sr、P、Ti的亏损特征;轻重稀土分馏明显（（La/Yb）N=15. 09~34. 90）,表现为轻稀土强烈富集的右倾型曲线,Eu异常变化较大（δEu=0. 12~1. 72）。在同位素组成上,富碱侵入岩呈现相对宽泛但总体富集的全岩Sr- Nd和锆石Hf同位素特征,(87Sr/86Sr)i=0. 70489~0. 70581,εNd(t)=14. 56~6. 74,εHf(t)=11. 48~+3. 06,锆石δ18O值（5. 49‰~6. 87‰）略高于地幔值（5. 3‰±0. 6‰）。阔克塔格西富碱侵入岩具A1型花岗岩特征,形成于板内伸展构造环境中。基于主、微量元素及Sr- Nd- Hf- O同位素特征,笔者认为该杂岩体为同源岩浆演化产物,源于富集岩石圈地幔的原始岩浆上升并经历AFC（同化混染- 分离结晶）过程。晚三叠世塔里木克拉通北缘—东天山—北山地区处于板内构造体制,A1型花岗岩和正长岩差异化的时空分布特征很可能记录了古亚洲洋自西到东 “剪刀式”的闭合过程。     

南阿尔金地区早古生代中酸性侵入岩的岩石成因及其对构造演化的指示意义

南阿尔金造山带位于塔里木盆地和柴达木盆地之间,是中国西北地区重要的俯冲-碰撞杂岩带,其早古生代构造演化过程是近年来的研究热点之一,然而,洋壳俯冲的时限一直存在争议。本文对茫崖石英二长岩开展岩石学、地球化学、锆石U-Pb年代学和锆石Lu-Hf同位素地球化学研究,探讨其岩石成因及成岩时的构造环境。样品显示高碱、富钾、低钛、贫铁及Nd-Ta-Ti异常等与钾玄岩相似的地球化学特征,成岩年龄为511～495 Ma, ε_Hf(t)主要为-3.51～-0.08,少量介于0.04～1.69之间。我们认为俯冲洋壳到达角闪岩相边界时释放大量水并上升进入地幔楔,导致地幔楔橄榄岩发生角闪石化交代作用,由于地幔楔沿俯冲带向下拖曳而温度升高,角闪石化橄榄岩熔融形成的熔体在上升过程诱发上地壳物质部分熔融,壳源岩浆混合少量幔源岩浆形成了石英二长岩,该期花岗岩是对造山带从大洋岛弧环境向活动大陆边缘过渡的岩石学响应。因此,南阿尔金洋壳可能在约517 Ma前已经开始俯冲。