Field measurements of NO and NO2 emissions from fertilized and unfertilized soils

Field measurements of NO and NO₂ emissions from soils have been performed in Finthen near Mainz (F.R.G.) and in Utrera near Seville (Spain). The applied method employed a flow box coupled with a chemiluminescent NO _x detector allowing the determination of minimum flux rates of 2 g N m^-2 h^-1 for NO and 3 g m^-2 h^-1 for NO₂.The NO and NO₂ flux rates were found to be strongly dependent on soil surface temperatures and showed strong daily variations with maximum values during the early afternoon and minimum values during the early morning. Between the daily variation patterns of NO and NO₂, there was a time lag of about 2 h which seem to be due to the different physico-chemical properties of NO and NO₂. The apparent activation energy of NO emission calculated from the Arrhenius equation ranged between 44 and 103 kJ per mole. The NO and NO₂ emission rates were positively correlated with soil moisture in the upper soil layer.The measurements carried out in August in Finthen clearly indicate the establishment of NO and NO₂ equilibrium mixing ratios which appeared to be on the order of 20 ppbv for NO and 10 ppbv for NO₂. The soil acted as a net sink for ambient air NO and NO₂ mixing ratios higher than the equilibrium values and a net source for NO and NO₂ mixing ratios lower than the equilibrium values. This behaviour as well as the observation of equilibrium mixing ratios clearly indicate that NO and NO₂ are formed and destroyed concurrently in the soil.Average flux rates measured on bare unfertilized soils were about 10 g N m^-2 h^-1 for NO₂ and 8 g N m^-2 h^-1 for NO. The NO and NO₂ flux rates were significantly reduced on plant covered soil plots. In some cases, the flux rates of both gases became negative indicating that the vegetation may act as a sink for atmospheric NO and NO₂.Application of mineral fertilizers increased the NO and NO₂ emission rates. Highest emission rates were observed for urea followed by NH₄Cl, NH₄NO₃ and NaNO₃. The fertilizer loss rates ranged from 0.1% for NaNO₃ to 5.4% for urea. Vegetation cover substantially reduced the fertilizer loss rate.The total NO _x emission from soil is estimated to be 11 Tg N yr^-1. This figure is an upper limit and includes the emission of 7 Tg N yr^-1 from natural unfertilized soils, 2 Tg N yr^-1 from fertilized soils as well as 2 Tg N yr^-1 from animal excreta. Despite its speculative character, this estimation indicates that NO _x emission by soil is important for tropospheric chemistry especially in remote areas where the NO _x production by other sources is comparatively small.     

陕西略阳煎茶岭镍矿床成矿及矿石变质过程的地球化学研究

矿床中存在着岩浆离熔成因的磁黄铁矿-镍黄铁矿矿石和热液改造成因的黄铁矿-针镍矿-辉镍矿矿石。研究证明现在矿石中存在的硫化物均为较低温度条件下的变质产物,并且矿物组合的更替不仅同温度变化有关,同时还受体系中氧逸度和硫离子活度的控制。矿物组合的地球化学分析表明,现有Fe-Ni-S体系低温（<300℃）相平衡图解之间存在着矛盾的原因可能是忽略了氧化-还原条件的影响。     

Isofactorial models for granulodensimetric data

Existing isofactorial models developed for disjunctive kriging using a cutoff grade on one variable are extended to the bivariate case which arises when dealing with granulo-densimetric data, such as are obtained from coal washing or mineral processing.     

长春市深部地下水赋存规律之我见

长春市北西或北北西向扭性断裂或断裂带是客观存在，它对长春市深部地下水循环与循存起控制作用，是深部基岩裂隙水的主要导水通道，且大都为富水带。原北东向压扭性断裂或断裂带起阻水作用，二者相得益彰。笔者于长春北郊贫水区，利用这一新理论，在水文地质调查基础上，结合多种水文物探手段布孔凿井，打出一口水量丰富的优质矿泉水井，进而验证了北西向富水说，了箕市深部地下水赋存规律的新认识，此说不但对长春市供水有实际意义     

塔里木盆地北部构造样式

塔里木盆地北部发育５种典型的构造样式；基底卷入型压性逆冲构造组成、盖层滑脱型逆冲－褶皱构造组合、隐刺穿刺底檗同幅度褶皱构造组合及张性正断层组合，无论是构造变形时间还是组合分布，在塔北均呈现规律变化，其变形特征及发布受如下３个地质因素控制：（１）区域挤压作用；（２）岩性条件的差异：（２）先期构造格局。     

漫话矿泉水的浴疗作用

本文综述了矿泉浴的医疗作用机理，主要的几种矿泉水浴疗条件和适应症，井阐述了矿泉浴疗应注意的问题。     

对胶南群的异议

对苏北～胶南一带胶南群的变质岩系进行研究，其边界特征、横向不连续性、岩石类型及相互关系、同位素年龄等资料表明，胶南群不具有单一地层单元的含义，而是挟于五莲－荣成断裂与海州－泗阳断裂之间的构造岩石组合体，它由上壳岩类和深源岩类组成，前者包括了３个构造位。其形成可能与边界深大断裂的开合作用有关     

山东沂沭裂谷系含金斑岩铜矿床成矿地质特征

沂沐裂谷是中国东部呈扇形展布的大陆裂谷系,从晚侏罗至白垩世裂谷岩浆活动强烈,发育了一套碱性、钙碱性火山建造,尤以中生代钙碱性火山活动具有特色,并常常形成许多巨大的古火山机体,本文通过对产于古火山机体中两个含金斑岩铜岩床研究,初步得出其主要成矿地质特征。     

内蒙古东五分子地区韧性剪切变质作用的特征

东五分子地区花岗-绿岩地体经受了三种类型变质作用的改造。韧性剪切带不仅控制了区域变质岩组合的分布,而且也导致其变质作用的强度出现了逆转序列。根据岩石的结构、碎斑含量及矿物成分,韧性剪切变质岩划分为三类,其共同特点是具有碎斑结构。其变形结构分为单矿物型及组合型。同一块韧性剪切变质岩由处在单变平衡的一组矿物组成。根据岩石变形及重结晶的特点,结合其产状,确定出两种不同类型韧性剪切变质带。共生矿物对的研究证明它们形成于地壳不同深度及温度、压力条件。本区的金矿化、运移、沉淀与韧性剪切变质带紧密相关。     

黄钇钽矿形成条件的实验研究

本文实验表明,黄钇钽矿需要在温度≥500℃,溶液pH≈4.0-7.5,压力500—1500bar的范围内形成,与褐钇铌矿相比,其形成条件的范围要窄得多。 不同的稀土元素在形成黄钇钽矿时的成矿温度亦不同。钇族稀土成矿温度相对较低且相互接近,铈族稀土的成矿温度比钇族稀土高得多,并随原子序数减小而迅速增高,以致La、Ce、Pr、Nd在一般的地质条件下难以形成这种结构的矿物,这就是至今在自然界发现的黄钇钽矿均为钇族稀土占优势的原因之一。实验还表明,大量F、P等组分的存在,对黄钇钽矿的形成是不利的。