Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance

<正>The Central Asian metallogenic domain(CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems.The Balkhash metallogenic belt in Kazakhstan,in which occur many large and super-large porphyritic Cu—Mo deposits and some quartz vein- and greisen-type W—Mo deposits,is a well-known porphyritic Cu—Mo metallogenic belt in the CAMD.In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re—Os compositional analyses and Re—Os isotopic dating.Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W—Mo deposits—East Kounrad.Akshatau and Zhanet—all have relatively high Re contents(2712—2772μg/g for Borly and 2.267—31.50μg/g for the other three W—Mo deposits),and lower common Os contents(0.670—2.696 ng/g for Borly and 0.0051—0.056 ng/g for the other three).The molybdenites from the Borly porphyry Cu—Mo deposit and the East Kounrad,Zhanet,and Akshatau quartz vein- and greisen-type W—Mo deposits give average model Re—Os ages of 315.9 Ma,298.0 Ma,295.0 Ma,and 289.3 Ma respectively.Meanwhile,molybdenites from the East Kounrad,Zhanet,and Akshatau W—Mo deposits give a Re—Os isochron age of 297.9 Ma,with an MSWD value of 0.97.Re-Os dating of the molybdenites indicates that Cu—W—Mo metallogenesis in the western Balkhash metallogenic belt occurred during Late Carboniferous to Early Permian(315.9—289.3 Ma),while the porphyry Cu—Mo deposits formed at—316 Ma,and the quartz vein-greisen W—Mo deposits formed at ~298 Ma.The Re—Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercynian movement.Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China,the formation of the Cu—Mo metallogenesis in the Balkhash metallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively,the large-scale Late Carboniferous porphyry Cu—Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.     

湘西北地区民乐式锰矿成矿地质特征及矿床成因

在野外考察和室内综合研究基础上,从地层岩性、岩相古地理、地质构造等成矿地质条件的分析入手,结合稳定同位素测试数据分析,以古丈锰矿田中的野竹锰矿为例,对湘西北民乐式锰矿床的成矿地质特征及成矿机制进行了探讨,认为区内成矿物质（锰）是多来源的,但主要来源于海底火山活动。在成矿作用过程中,堆集在火山喷口附近的沉积物被烘热的海水淋滤改造,从中析出锰质,由热海水体所挟带,随海流迁移,成矿物质在裂陷槽中沉积下来富集形成锰矿床。民乐式锰矿床属离火山喷发中心较远的海底火山喷发-沉积锰矿床。     

全球湿地的状况、未来情景与可持续管理对策

简要介绍了千年生态系统评估（MA）项目针对湿地与水编写的《生态系统与人类福祉：湿地与水综合报告》的核心内容。报告表明：①据估算,2000年全球的湿地面积大约为1.28×10⁹hm²,但是这一数据显著偏低,尤其是对新热带区的湿地以及有些特殊类型湿地的估算因数据源问题可能远低于实际面积;②根据MA构建的4种情景的分析结果,未来50年（2000—2050年）内,在对生态系统实行被动式管理的全球协同和实力秩序2种情景中,预计全球的湿地面积将会减少,而在对生态系统实行主动式管理的技术家园和适应组合2种情景中,预计全球的湿地面积将保持相对稳定;③湿地的丧失和退化会对人类福祉和减轻贫困产生极为不利的影响,尤其是对低收入国家湿地附近居民的影响更为严重。为了实现湿地的可持续管理,必须从经济、制度和管理以及相关驱动力方面采取积极对策,减轻湿地生态系统承受的各种压力,保育各项生态特征,增强其自恢复能力,减缓和扭转湿地的丧失和退化趋势。     

水平井和大斜度井中的感应测井响应计算

感应测井受井斜影响十分严重,在水平井和大斜度井中,感应测井曲线几乎面目全非．水平井和大斜度井中感应测井响应的正演计算是正确认识这种复杂环境中感应测井响应特征的重要手段,是进行井斜环境影响校正的必要准备,是研究用感应测井曲线探测水平井井眼离最近界面距离的基础,同时也是感应测井理论的新发展．本文将论述水平井和大斜度井中感应测井响应正演计算的理论和方法;分析水平井、大斜度井中感应测井的响应特征     

Engineering source model for strong ground motion

A new engineering source model consistent with seismological concepts for simulating strong-motion accelerograms (SMAs) is presented in this paper. The source region is modeled as a horizontally layered elastic medium to cater for site dependency. The moment field acting on the rupture plane is decomposed into space and time functions, which is a novel concept. The spatial and temporal components are determined for six well-recorded earthquakes using the corresponding recorded SMA. The obtained spatial variations indicate that they can be modeled as an anisotropic random field. The temporal components of all the six events are transients, with typical frequency spectra. Based on these results, a simplified source model is proposed for the synthesis of SMA during strong earthquakes. The model is validated by simulating strong-motion acceleration time histories at stations deliberately kept out of the modeling exercise. It is found that the present model is efficient in simulating observed time histories. The proposed model is also illustrated by simulating an ensemble of acceleration time histories for the Kutch earthquake of 26th January 2001 using only the few known source parameters.     

海南岛抱板群岩石高温高压实验及金成矿机理探讨

高温高压实验岩石学是地质学、岩石学领域中的“硬科学”犤1999,王德滋,等犦。目前高温高压实验岩石学研究主要是针对单一岩石的熔化和融离实验,而针对多物源成因的花岗岩模拟其物源贡献大小的实验岩石学及同时发生的成矿作用研究基本上是一个空白。文章根据海南岛戈枕含金剪切带中元古代花岗岩的物源特征及与之有关的戈枕式金矿成因特点,通过高温高压实验岩石学模拟,初步探讨古中元古代抱板群岩石高温高压下的熔融行为及金的成矿机理。实验结果表明,具原地-半原地性质的中元古代花岗岩很可能是由6份(或4份)石英绢云母片岩+1份斜长角闪片麻岩、在压力为1.879～2.143GPa、温度849～901℃的条件下部分熔融形成的,部分熔融过程同时还发生了金的聚集和活化迁移。     

易门式大型铜矿床构造成矿动力学模型

针对金属矿床隐伏矿定位预测的关键问题,在提出构造成矿动力学的分支学术方向的基础上,以易门式大型铜矿床为例,从成矿地质背景、矿田构造、构造地球化学和成矿构造应力场等方面进行构造成矿动力学研究,阐述在构造应力场控制下成矿流体运移和聚集的规律。构造地球化学研究认为,构造地球化学异常反映矿体的原生晕;构造地球化学异常受构造控制,其分带特征可指示成矿流体的流向,并提供矿床成因和隐伏矿(化)体相对埋深的信息。构造应力场的控矿特征主要表现在:构造应力场导致控矿构造的形成,并驱动成矿流体的运移;构造应力场控制了成矿能量场;应力和能量的高值集中区分布特点可反映某些构造型式。在此基础上建立构造成矿动力学模型,概括隐伏矿成矿预测准则,据此提出若干重点找矿靶区和靶位,其中部分靶区得到工程验证,表明构造成矿动力学方法对隐伏矿定位预测和评价具有重要的指导意义。     

The oldest Mo porphyry mineralization in the Yangtze Valley Metallogenic Belt of eastern China: Constraints on its origin from geochemistry,geochronology and fluid inclusion studies at Matou

The Matou Mo(-Cu) deposit, located in the Yangtze Valley Metallogenic Belt of central-eastern China, is a typical porphyry-type Mo deposit. The orebodies at the deposit are hosted by Matou porphyritic granodiorite, which is the largest intrusive in the area. Quartz vein-type and disseminated sulfide mineralization are well developed in the porphyry and near its contact with Silurian sandstone. Crosscutting relationships indicate that porphyritic granodiorite is the oldest phase in the pluton, which is crosscut by a porphyritic diorite containing traces of chalcopyrite, and later dolerite dykes. These phases have U-Pb zircon dates of 147 ± 3, 140 ± 1 and 135 ± 1 Ma, which confirms the cross-cutting relationships observed in the field. A Re-Os molybdenite isochron age of 147 ± 4 Ma indicates that the porphyritic granodiorite is the source of the oldest Mo mineralization in the metallogenic belt and was formed during a change of the tectonic setting in the area, from an intracontinental orogeny to extensional tectonics. From 147 to 135 Ma, crust-mantle interaction played an important role in the formation of magmatic rocks at Matou. Systematic petrological and geochemistry investigations reveal that the three phases have a crust source with minor input from the mantle. Investigation of ore-forming fluid, H-O isotopes, S isotopes, and the Re content of molybdenite indicate that the ore-forming fluid and metals were derived from the lower crust. During the evolution of fluid from initial magmatic fluids (stage I) to ore-forming fluids (stage II), fluid boiling accompanied by the input of relatively cooler meteoric water led to the deposition of the Mo mineralization.     

Geochemical Characteristics and Genetic Significance of Datangpo‐Type Manganese Ore Deposits during the Cryogenian Period

The Datangpo‐type manganese ore deposits, which formed during the Nanhuan (Cryogenian) period and are located in northeastern Guizhou and adjacent areas, are one of the most important manganese resources in China, showing good prospecting potential. Many middle‐to‐large deposits, and even super‐large mineral deposits, have been discovered. However, the genesis of manganese ore deposits is still controversial and remains a long‐standing source of debate; there are several viewpoints including biogenesis, hydrothermal sedimentation, gravity flows, cold‐spring carbonates, etc. Geochemical data from several manganese ore deposits show that there are positive correlations between Al₂O₃ and TiO₂, SiO₂, K₂O, and Na₂O, and strong negative correlations between Al₂O₃ and CaO, MgO, and MnO in black shales and manganese ores. U, Mo, and V show distinct enrichment in black shales and inconspicuous enrichment in Mn ores. Ba and Rb show strong positive correlations with K₂O in manganese ores. Cu, Ni, and Zn show clear correlations with total iron in both manganese ores and black shales. ∑REE of manganese ores has a large range with evident positive Ce anomalies and positive Eu anomalies. The Post Archean Australian Shale (PAAS) normalized rare earth element (REE) distribution patterns of manganese ores present pronounced middle rare earth element (MREE) enrichment, producing “hat‐shaped” REE plots. ∑REE of black shales is more variable compared with PAAS, and the PAAS‐normalized REE distribution patterns appear as “flat‐shaped” REE plots, lacking evident anomaly characteristics. δ¹³C values of carbonate in both manganese ores and the black shales show observable negative excursions. The comprehensive analysis suggests that the black shales formed in a reducing and quiet water column, while the manganese ores formed in oxic muddy seawater, which resulted from periodic transgressions. There was an oxidation–reduction cycle of manganese between the top water body and the bottom water body caused by the transgressions during the early Datangpo, which resulted in the dissolution of manganese. Through the exchange of the euphotic zone water and the bottom water, and episodic inflow of oxygenated water, the manganese in the bottom water was oxidized to Mn‐oxyhydroxides and rapidly buried along with algae. In the early diagenetic stage, Mn‐oxyhydroxides were reduced and dissolved in the anoxic pore water and then transformed into Mn‐carbonates by reacting with HCO₃^? from the degradation of organic matter or from seawater. In the intervals between transgressions, continuous supplies of terrigenous clastics and the high productive rates of organic matter in the euphotic zone resulted in the deposition of the black shales enriched in organic matter.     

大兴安岭北部甲乌拉铅锌银矿床Rb-Sr同位素测年及其地质意义

甲乌拉铅锌银矿床位于内蒙古自治区满洲里市南西150km。矿床产于中蒙古-额尔古纳兴凯造山带南东缘之得尔布干断裂北西侧。本文在甲乌拉矿床选取7件闪锌矿和6件黄铁矿样品开展了Rb-Sr定年。获得闪锌矿的Rb-Sr等时线年龄为143.0±2.0Ma(MSWD=3.2),锶同位素初始值I Sr=0.71265;黄铁矿的Rb-Sr等时线年龄为142.0±3.0Ma(MSWD=5.7),锶同位素初始值ISr=0.71267;闪锌矿与黄铁矿的Rb-Sr等时线年龄为142.7±1.3Ma(MSWD=3.8),锶同位素初始值ISr=0.71266。上述定年结果表明,甲乌拉矿床形成于早白垩世初期。甲乌拉矿床硫化物的Rb和Sr含量分别介于0.1034×10-6～7.367×10-6和1.301×10-6～7.148×10-6之间,Sr同位素初始比值(87Sr/86Sr)i介于0.71238～0.71277之间,平均值为0.71264,暗示甲乌拉矿床的成矿物质主要来源于地壳。甲乌拉矿床形成于蒙古-鄂霍茨克造山过程的后碰撞阶段。