Atmospheric noble gases in volcanic glasses from the southern Lau Basin: origin from the subducting slab?

Noble gas concentrations and isotopic compositions have been determined for four submarine volcanic glasses from the Valu Fa Ridge (VFR) in the southern Lau Basin. The samples are the least differentiated ones from this area, and they display enrichments in fluid-mobile elements similar to the nearby island arc. ³He/⁴He ratios are slightly below average MORB (6.8–7.8 times atmospheric), whereas Ne, Ar, Kr, and Xe have isotopic compositions very similar to air. Together with previously published data from the Valu Fa Ridge and other spreading segments in the Lau Basin, our data show a systematic latitudinal variation of increasing Ne, Ar, Kr, and Xe abundances from north to south as well as Ne and Ar isotopic compositions changing from MORB-like to atmosphere-like in the same direction. Moreover, isotopic compositions and noble gas abundances of the lavas correlate strongly with Ba/Nb ratios and H₂O concentrations. Based on these observations and mass balance arguments, we propose that the atmospheric noble gases come from the subducting oceanic crust and are not due to shallow contamination with air dissolved in seawater or assimilation of old crust. Our data suggest that the noble gases released from the subducting slab are atmospheric and thus contain little or no solar He and Ne. In addition to the fact that ratios of He to heavy noble gases are small in aged ocean crust, He has possibly fractionated from the other noble gases due to its higher diffusivity, and thus He transport from the subducting slab into the mantle wedge is probably insignificant. We propose that the ³He/⁴He ratios lower than MORB observed in the VFR lavas result from radiogenic ingrowth of He in a highly depleted, and hence degassed, mantle wedge after the enrichment of U and Th released from the downgoing slab.     

胶北晚中生代煌斑岩的岩石地球化学特征及其成因研究

胶北煌斑岩分别采自龙口、烟台和威海地区，包括拉辉煌斑岩、斜闪正煌岩和角闪煌斑岩，煌斑岩K—Ar全岩年龄变化于89．3～169．5Ma，为晚中生代岩浆活动的产物。在岩石化学组成上，SiO2=42．02％～54．95％，以钙碱性系列为主．岩石以富集大离子亲石元素（LILE）（Ba，U，K，Th）和LREE，亏损高场强元素（HFSE）（Nb，Ta和Ti）为特征，Mg^#=33．9～53．9，Eu／Eu^＊=0．71～0．89，^87Sr／^86Sr初始比值0．707642～0．709791，εNd（t）为-17．6～-10．4，^206Pb／^204Pb=37．588～38．431，^207Pb／^204Pb=15．423～15．531，^206Pb／^204Pb=17．204～18．179。表明煌斑岩源自俯冲陆壳（扬子下地壳）在地幔源区发生交代作用时形成的富集型地幔的部分熔融体．考虑到煌斑岩具有大陆边缘弧玄武岩的特征，我们认为煌斑岩在成因上同样与古大洋板块的俯冲作用有关，为碰撞后弧岩浆作用形成的脉岩。     

中国东部中生代岩浆岩的时空分布及其与热液型铀矿的关系

中国东部中生代岩浆活动强烈,热液型铀矿分布广泛。空间上,自北而南可划分出大兴安岭、小兴安岭-长白山、冀北-辽西、大别山北缘、长江中下游、扬子陆块东南缘、武夷-云开、东南沿海8个火山-侵入岩带和沽源-红山子、青龙-兴城、庐枞-栖霞、赣杭、武夷山、桃山-诸广、郴州-钦州、湘中、雪峰山-摩天岭9个热液型铀成矿带以及满洲里-额尔古纳、扎兰屯、伊春、金寨、天目山5个铀成矿远景带;时间上,从早到晚可划分出250~230Ma、228~205Ma、195~175Ma、165~150Ma、145~130Ma、126~115Ma、110~100Ma、97~80Ma 8个不同时期的岩浆活动和早期深源高温、晚期浅源低温两个成矿系统,深源高温成矿系统可划分出11个矿床式,浅源低温成矿系统可划分出15个矿床式。勘查成果显示,热液型铀矿对岩浆岩的岩性岩相没有选择性,但与特定时期的岩浆岩有密切的关系,其中与花岗岩有关的热液型铀矿主要赋存在三叠纪花岗岩中,与火山岩有关的热液型铀矿主要赋存在早白垩世早期高钾钙碱性流纹岩-碱性粗面岩组合中,而且晚期高侵位小岩体或火山斑岩体的内、外接触带是有利的赋矿部位。     

Mesozoic Granitoid Types and Metallogeny of the East China Circum-Pacific Continental Margin

Abstract: This paper synthesizes the geotectonic background, genetic types and metallogenetic relations of the Mesozoic granitoids in the East China continental margin. By the Mesozoic, the Siberia Plate, North China Plate and South China Plate amalgamated together, resulting in formation of a unified Eurasia super–continent. Since the late Triassic to early Jurassic period, the territory of East China gradually became a Cordilleran style active continental margin. During the Jurassic to early Cretaceous (early to middle episodes of Yanshanian orogeny), the Paleo-Pacific plate strongly collided with and subducted under the Eurasia continent, reactivated the consolidated East China continental margin. The granitoids of both transformation series and syntexis series were generated. Many granitoid-related large and giant metal deposits were formed. Furthermore, the W, Sn, Be, Nb, Ta and U mineralizations are mostly associated with the transformation series; while the Fe, Cu, Mo and Au mineralizations are mostly associated with the syntexis series. The late Yanshanian orogeny (late Cretaceous) began a transition to the western Pacific style continental margin. A tensional environment resulted in development of alkaline granitoids and formation of continental red basins. The Cenozoic orogeny was characterized by a backarc spreading and rifting regime in this region.     

华北及其以北地区晚古生代—早中生代构造格架主体特点

从全球尺度对原大西洋与古亚洲洋构造域大地构造旋回及其演化特征进行对比研究,有助于了解巨型构造域内的区域构造演化的关联性。建立古大陆构造单元属性"动态行为"的理念,将复合造山区与毗邻大地构造单元进行关联分析,揭示出华北前陆盆地的形成发展与毗邻复合造山区的构造演化进程密切相关。华北及其以北地区晚古生代—早中生代构造格架的主体特点是:1)蒙古—兴安复合造山区发育石炭纪—二叠纪陆表海盆地、裂陷槽和上叠盆地,及三叠纪的山间盆地;2)华北前陆盆地与复合造山区构造演化进程同步,在古陆上形成石炭纪海相和海陆交互相沉积,二叠纪—中三叠世的陆相沉积,以发育红层和局部形成膏盐为特点;3)原华北古陆北缘"构造岩浆活化带"属晚古生代—早中生代蒙古—兴安复合造山区最南端的构造单元,具有构造前锋带属性。     

山东中生代橄榄安粗岩系火山岩的地质、地球化学特征及岩石成因

山东中生代橄榄安粗岩系火山岩主要分布在沂沭断裂带及其两侧的断陷型陆相火山盆地中，为早白垩世火山活动的产物．Ｒｂ－Ｓｒ全岩等时年龄变化于１１１．４～１１９．６Ｍａ．岩石组合主要为粗面玄武岩－橄榄安粗岩－安粗岩－粗面岩．这套岩石在化学上具有富碱富钾、富铝贫钛、高氧化系数及富轻稀土和大离子亲石元素的特点，并具有较高的ＩＳｒ值和明显偏低εＮｄ值．根据对岩石地质、地球化学特征和产出构造环境的详细分析，表明这套岩石的成因应主要是富集型地幔的部分熔融     

辽西义县四合屯义县组中部湖相沉积岩地球化学及物源特征

辽西北票上园镇四合屯地区义县组沉积层是热河生物群珍稀化石的重要产出层位之一, 其中蕴含丰富的地壳演化和古地理环境演化信息.分析了四合屯剖面上12m厚的含鸟化石沉积岩层的50件样品的微量元素组成和其中10件样品的主量元素组成.结合前人已发表数据, 得出以下认识: (1) 该套沉积岩具有与下伏火山岩类似的地球化学特征: Mg#值较高, 大离子亲石元素含量较高.稀土元素的分异程度较高, 在微量元素分布蛛网图中表现为明显的Nb负异常和Pb正异常等.因此我们认为义县组高镁火山岩构成了该沉积岩的主要源区之一; (2) 样品的Eu/Eu*=0.48~1.81, 其中大部分样品具负Eu异常.正的Eu异常(7件样品) 主要由于含有长石造成; (3) 通过微量元素Th-Co-Zr/10沉积构造环境判别图解对区域构造环境进行分析, 结果表明该沉积岩物源区具有大陆岛弧和活动大陆边缘物源特征.      

Lithospheric Stretching,Subsidence and Thermal History Modeling: Application to Yinggehai,Qiongdongnan and Songliao Basins in East China

ＬｉｔｈｏｓｐｈｅｒｉｃＳｔｒｅｔｃｈｉｎｇ，ＳｕｂｓｉｄｅｎｃｅａｎｄＴｈｅｒｍａｌＨｉｓｔｏｒｙＭｏｄｅｌｉｎｇ：ＡｐｐｌｉｃａｔｉｏｎｔｏＹｉｎｇｇｅｈａｉ，ＱｉｏｎｇｄｏｎｇｎａｎａｎｄＳｏｎｇｌｉａｏＢａｓｉｎｓｉｎＥａｓｔＣｈｉｎａ＊Ｌｉ...     

福建晋江中-基性岩墙群的锆石SHRIMP U-Pb定年和岩石地球化学

福建晋江晚中生代中-基性岩墙群可分为两期:早期岩墙群,岩性为角闪辉绿岩,近东西走向(N70-85E),锆石SHRIMP U-Pb年龄为90±2Ma;晚期岩墙群,岩性为微晶闪长岩,北东走向(N35～50E),锆石SHRIMP U-Pb年龄为87±2Ma。两期岩墙群沿晚中生代花岗片麻岩的节理侵入。在地球化学上,它们具有轻稀土元素和大离子亲石元素富集、高场强元素亏损等特点,I_(Sr)=0．7045～0．7053,ε_(Nd)(t)=-1．18～-1．97,与金门、小金门岛的镁铁质岩墙群相似,也和闽东南晚中生代基性火成岩(辉长岩、玄武岩)的一致。它们是起源于受消减作用影响的岩石圈地幔部分熔融而产生的玄武岩浆,经岩浆分异作用,在拉张的构造环境中侵入形成。     

Effect of volatiles erupted from Mesozoic and Cenozoic volcanic activities on paleo-environmental changes in China

Based on the determination of composition of volcanic volatiles and petrologic estimation of the total mass of volatiles erupted, we showed important advances in the study of the impact of Mesozoic and Cenozoic volcanic activities on paleo-environmental changes in China. The volcanic activities include western Liaoning and Zhangjiakou Mesozoic intermediate-acidic explosive eruptions, southern Tibet and Shanwang Cenozoic volcanism, and Mt. Changbai volcanic eruption around one thousand years ago. The paper predominantly discusses the earth’s surface temperature changes, ozone depletion, acidic rain formation and mass mortalities of vertebrate induced by the Mesozoic and Cenozoic volcanism in China. __________ Translated from Bulletin of Mineralogy, Petrology and Geochemistry, 2007, 26(4): 319–322 [译自: 矿物岩石地球化学通报]