“雪龙号”2003北极航次气相多环芳烃纬度分布观测

2003年“雪龙号”北极科学考察期间,对沿途海洋大气进行采样,分析其中气相多环芳烃的空间分布。结果显示,气相中主要是2-4环的多环芳烃,其中菲为主要的化合物,平均占到总多环芳烃的55.1%。在整个航程的广泛区域尺度内,气相总多环芳烃浓度在1043.9-92993.1pg/m3。空间分布上,远东亚的海面>北太平洋海面>北极圈以内海面;总多环芳烃的浓度随纬度升高呈现显著降低的趋势。通过Clausius-Clapeyron方程对浓度和温度相互关系的分析表明,温度是控制气相多环芳烃长距离传输的主要因素。     

兰州市2001年沙尘气溶胶质量浓度的特征分析

 分析了2001年沙尘暴期间兰州与靠近沙尘源区的武威的沙尘浓度和粒径分布特征,并运用对数正态分布规律拟合了沙尘粒径的分布。通过对比武威、皋兰和兰州沙尘暴期间沙尘浓度的变化以及武威与兰州的沙尘粒径分布特征,揭示了河西走廊沙漠对兰州市沙尘暴的影响。     

云南沿边境地带生态环境3S监测、 评价与调控研究

本文利用全球新千年整体生态系统评估的理论，以云南省沿边境地带生态系统变化跨境生态安全为研究对象，探寻并揭示我国陆疆系统的跨境生态系统变化监测、评价和生态安全综合调控的基础理论与信息机理；进而研究基于“3S”云南沿边境地带的生态环境监测、评价与综合调控的方法和关键技术，包括方法和技术体系的建立、指标体系的建立、多尺度效应和尺度转换、数学模型的建立、综合调控模式和决策方案的建立等；在案例研究部分，建立了背景数据库，然后选择大、中、小尺度进行了全区生态环境现状评价，重点河道、典型路段和重点口岸的影响评价和预测预报研究，最后进行了综合调控模式和方案的探讨，并对研究结果进行了动态仿真和虚拟表达研究。     

中国陆地净初级生产力的季节变化研究

了解不同季节陆地净初级生产力(NPP)的变化及与气候的相互关系以及在不同地类的差异对深刻理解我国陆地生态系统对全球气候变化的响应和陆地碳循环研究具有重要意义。本文使用1981～2000年间GLO-PEM模型模拟的我国陆地NPP数据和同期气温、降水以及土地利用数据, 研究不同季节我国陆地植被NPP的变化。结果表明,在1981～2000年期间,四个季节的NPP都呈显著增加趋势,春季是NPP增加速率最快的季节,夏季是NPP增加量最大的季节。耕地在春、夏和秋季NPP增长和增长率最高,林地冬季NPP增长最多而水域冬季NPP增长率最高。夏季NPP增长最高的区域分布于我国东部的多数地区、内蒙古东部、四川盆地、贵州东部、藏南和新疆西部;夏季NPP降低最多的区域分布于在呼伦贝尔高原、鄂尔多斯高原、黄土高原、青藏高原东部和新疆西北部。     

黄土区人类活动影响下的 产汇流模拟研究

日益频繁的人类活动改变了流域下垫面条件,对流域产汇流产生很大的影响。本文以黄河中游典型支流岔巴沟为研究区域,提出利用基于DEM的分布式水文模拟技术,探讨流域人类活动过程中的产汇流模拟,避免了经验公式的概化和由此引起的局限。模拟的结果证实了该方法的可行性。采用网格滞蓄的方法可以在子网格上体现人类活动引起的下垫面的变化及其对产汇流的影响,反映各个时期的产汇流条件,对降雨做出合理响应。     

273.15K下LiCl-Li2B4O7-H2O体系热力学性质的等压研究

用等压法研究了273 15K下LiCl-Li2B4O7-H2O体系中纯盐水溶液(离子强度范围为LiCl0 2046～2 5055mol·kg-1,Li2B4O70 1295～0 3700mol·kg-1)以及混合盐水溶液(离子强度范围为0 0931～2 4911mol·kg-1)渗透系数和水活度;计算了LiCl-Li2B4O7-H2O体系的饱和蒸汽压,获得饱和蒸汽压、渗透系数随离子强度的变化规律。用实验数据以最小二乘法求取了LiCl和Li2B4O7纯盐参数及体系的混合盐参数,拟合的标准偏差分别为0 0077和0 026。用该模型计算的渗透系数值与实验结果取得合理的一致。同时研究结果与273 15K下LiCl-Li2SO4-H2O体系的渗透系数随离子强度变化的规律作了比较。本研究对完善低温下含锂、硼盐湖卤水体系的热力学模型和盐湖资源的综合开发利用具有重要意义。     

用叠加谱比法研究新疆地区Lg尾波Q值的区域性变化

运用叠加谱比法,对分布于新疆地区的5个台站所记录的51个地震数据进行分析,得出与各射线路径相对应的Lg尾波Q0(Lg尾波在1Hz处的Q)值。结果表明:Q0值呈现出明显的区域性变化特点,与构造活动关系紧密。在较为稳定的塔里木地台,Q0呈现出高值,在350～450之间。在南部构造活动较为激烈的昆仑褶皱系,Q0呈现出较低的值,约为200～250。在构造活动最为激烈的帕米尔地区,Q0值在170～200之间。在北部的天山褶皱系,Q0值约为220～270。准葛尔褶皱系比天山褶皱系的Q0值略高,约为260～290。     

Refined modeling and movement characteristics analyses of irregularly shaped particles

Irregularly shaped (IRS) particles widely exist in many engineering and industrial fields. The macro physical and mechanical properties of the particle system are governed by the interaction between the particles in the system. The interaction between IRS particles is more complicated because of their complex geometric shape with extremely irregular and co‐existed concave and convex surfaces. These particles may interlock each other, making the sliding and friction of IRS particles more complex than that of particles with regular shape. In order to study the interaction of IRS particles more efficiently, a refined method of constructing discrete element model based on computed tomography scanning of IRS particles is proposed. Three parameters were introduced to control the accuracy and the number of packing spheres. Subsequently, the inertia tensor of the IRS particle model was optimized. Finally, laboratory and numerical open bottom cylinder tests were carried out to verify the refined modeling method. The influence of particle shape, particle position, and mesoscopic friction coefficient on the interaction of particles was also simulated. It is noteworthy that with the increase of mesoscopic friction coefficient, the fluidity of IRS particle assembly decreases, and intermittent limit equilibrium state may appear. Copyright © 2014 John Wiley & Sons, Ltd.     

Mercury and methylmercury biogeochemistry in a thawing permafrost wetland complex,Northwest Territories,Canada

In arctic and sub‐arctic environments, mercury (Hg), more specifically toxic methylmercury (MeHg), is of growing concern to local communities because of its accumulation in fish. In these regions, there is particular interest in the potential mobilization of atmospherically deposited Hg sequestered in permafrost that is thawing at unprecedented rates. Permafrost thaw and the resulting ground surface subsidence transforms forested peat plateaus into treeless and permafrost‐free thermokarst wetlands where inorganic Hg released from the thawed permafrost and draining from the surrounding peat plateaus may be transformed to MeHg. This study begins to characterize the spatial distribution of MeHg in a peat plateau–thermokarst wetland complex, a feature that prevails throughout the wetland‐dominated southern margin of thawing discontinuous permafrost in Canada's Northwest Territories. We measured pore water total Hg, MeHg, dissolved organic matter characteristics and general water chemistry parameters to evaluate the role of permafrost thaw on the pattern of water chemistry. A gradient in vegetation composition, water chemistry and dissolved organic matter characteristics followed a toposequence from the ombrotrophic bogs near the crest of the complex to poor fens at its downslope margins. We found that pore waters in poor fens contained elevated levels of MeHg, and the water draining from these features had dissolved MeHg concentrations 4.5 to 14.5 times higher than the water draining from the bogs. It was determined through analysis of historical aerial images that the poor fens in the toposequence had formed relatively recently (early 1970s) as a result of permafrost thaw. Differences between the fens and bogs are likely to be a result of their differences in groundwater function, and this suggests that permafrost thaw in this landscape can result in hotspots for Hg methylation that are hydrologically connected to downstream ecosystems. Copyright © 2016 John Wiley & Sons, Ltd.     

A multi‐proxy record of changing environments from ca. 30 000 to 9000 cal. a BP: Onepoto maar palaeolake,Auckland, New Zealand

We present a high‐resolution record of lacustrine sedimentation spanning ca. 30 000 to 9000 cal. a BP from Onepoto maar, northern North Island, New Zealand. The multi‐proxy record of environmental change is constrained by tephrochronology and accelerator mass spectrometric ¹⁴C ages and provides evidence for episodes of rapid environmental change during the Last Glacial Coldest Period (LGCP) and Last Glacial–Interglacial Transition (LGIT) from northern New Zealand. The multi‐proxy palaeoenvironmental record from Onepoto indicates that the LGCP was cold, dry and windy in the Auckland region, with vegetation dominated by herb and grass in a beech forest mosaic between ca. 28 500 and 18 000 cal. a BP. The LGCP was accompanied by more frequent fires and influx of clastic sediment indicating increased erosion during the LGCP, with a mid‐LGCP interstadial identified between ca. 25 000 and 23 000 cal. a BP. Rapid climate amelioration at ca. 18 000 cal. a BP was accompanied by increased terrestrial biomass exemplified by the expansion of lowland podocarp forest, especially Dacrydium cupressinum. Increasing biomass production is reversed briefly by LGIT perturbations which are apparent in many of the proxies that span ca. 14 000–10 500 cal. a BP, suggesting generally increased wetness and higher in situ aquatic plant productivity with reduced terrestrial organic matter and terrigenous detrital influx. Furthermore, conditions at that time were probably warmer and frosts rare based on the increasing importance of Ascarina. The subsequent early Holocene is characterised by podocarp conifer forest and moist mild conditions. Postglacial sea‐level rise breached the crater rim and deposited 36 m of estuarine mud after ca. 9000 cal. a BP. Copyright © 2011 John Wiley & Sons, Ltd.