The Energy Relationship between Ions and Soil Particles based on Wien Effect and Its Application in Soil Science

The interaction between ions and soil particles plays an important role in the mobilization and bioavailability of ions in soils, which is one of the main research areas of soil chemistry. The new method based on suspension Wien effect has been developed recently to determine the binding energy and adsorption energy between ions and soil particles. Compared with other methods on the basis of adsorption isotherm or ions activity, Wien effect method has more advantages including convenience and direct measurement. The term suspension Wien effect refers to the increase of electrical conductivity of suspension with increasing applied electrical field. In this review paper, we introduced the fundamentals of suspension Wien effect, the apparatus about the Wien effect measurement, and along with demonstrating their application to quantifying the particles-ions interactions for several systems of soils. Our studies indicated that divalent cations have larger binding energies and adsorption energies on soil particles than monovalent because of the electrostatic interaction. However, few studies about the interaction between Cr³⁺ and La³⁺ on soil particles showed that the binding energy and adsorption energy of trivalent cations are lower than those of divalent cations because of hydrolysis. Soil properties such as soil organic matter, soil pH, and iron oxides significantly affected the binding energy and adsorption energy of ions. Our results deepened our understanding about the non specific adsorption of ions in soil chemistry, and enlarged the research area of soil chemistry in fundamental and methodology.     

一种提取遥感影像中道路信息的方法

由于合理有效地选择分割阈值较难,因此基于阈值分割的道路信息提取方法对于遥感影像中含有多种类型道路、或非道路地物干扰比较明显的情况适用性不理想。为此,提出了一种将Mean Shift和阈值分割相结合的方法来提取道路信息。首先,采用Mean Shift方法对遥感影像进行平滑处理,在较好地保持道路边缘信息的同时使道路内部的纹理分布更加均匀;其次,对平滑处理后的影像进行Mean Shift分割处理,将具有相同或相似灰度值的道路用一种灰度值显示;然后,选择灰度直方图中像素数量值高的线所对应的灰度值作为分割区间边界点进行多阈值分割,得到初始道路信息;最后,对初始道路信息进行后处理,得到最终的道路信息。实验证明,该方法可以完成对遥感影像中道路信息的提取,拓宽了阈值分割方法提取道路信息的使用范围。     

1961-2010年青海高原蒸发皿蒸发量变化及其对水资源的影响

利用1961-2010年青海省气象观测资料,分析了青海高原近50年蒸发皿蒸发量的时空分布特征和变化趋势,并采用偏相关及主成分分析法,探讨了青海高原蒸发皿蒸发量变化的气候成因及其对水资源的影响。结果表明：近50 a来青海高原蒸发皿蒸发量呈显著下降趋势,它是热力、水分、动力因子综合作用的结果,在三类因子中,动力及水分因子对蒸发皿蒸发量的影响较大,而热力因子相对较小;区域分析表明,影响东部农业区和柴达木盆地蒸发量的主导因子是平均风速和相对湿度,三江源区为相对湿度,而唐古拉山区为气温日较差。通过分析黄河上游可能蒸散量与地表水资源的关系发现,蒸散量对地表水资源的负效应十分显著,其中夏季蒸散量对于平均流量的影响最为显著,而秋季平均流量对蒸散量的响应最为敏感。     

THE QUALITY OF MEAN AND VARIANCE ESTIMATES FOR NORMAL AND LOGNORMAL DATA WHEN THE UNDERLYING DISTRIBUTION IS MISSPECIFIED

Theoretical and simulation results are employed to evaluate mean and variance estimaies for normal datawhen a lognormal distribution is assumed and for lognormal data when a normal distribution is assumed.Misspecifying the distribution leads to the use of suboptimal estimation methods.However,the resultsshow that the suboptimal methods still produce estimators of good quality(low bias and variance)relativeto the minimum variance unbiased estimators for each distribution,at least when practical efficiency isconsidered.     

COMPARISON OF MEASUREMENT METHODS BASED ON A MODEL FOR THE ERROR STRUCTURE

Comparison of methods is a technique often used for investigation of systematic errors of measurementmethods.As concerns the design and analysis of such comparisons,much variety of opinion and practiceexists.In one approach a few specimens are measured several times by different operators in differentlaboratories(reproducibility conditions)and in another approach several specimens are measured on oneor a few occasions by one operator in the same laboratory(repeatability conditions).In this paper amodel for the error structure of measurements is formulated and it is emphasized that one has todistinguish between two types of systematic errors:the first type depends only on the level of themeasured quantity and the second type is specific for the separate specimens.On the basis of this modelthe information which can be obtained from the different designs of method comparisons is discussed.A new approach for the analysis of method comparisons with many specimens is also proposed.     

OSL测年中CGC法求D_e均值的计算方法之比较分析

光释光测年中等效剂量是计算样品埋藏年龄的一个重要参数,一般通过求多个实验测量值的均值得出。标准生长曲线法是求等效剂量的一种常用且有效的方法,分析讨论了此法计算的等效剂量存在小幅度的系统性的偏大及其原因,提出了改进的方法;展望了CGC法求De均值更优的估计——极大似然估计。     

“雨燕”中风暴算法在北京奥运天气预报示范项目中的应用及改进

介绍了临近预报系统“雨燕”中的风暴系列算法, 包括风暴识别、 风暴追踪、 基于TREC技术的风暴位置预报, 以及预报位置实时评分算法等。利用2008年北京奥运期间出现的多个强对流天气, 统计出该风暴产品在30 min和60 min预报时效的绝对距离误差分别约为13 km和23 km。分析了北京奥运天气预报示范项目期间该风暴产品误差较大的原因, 主要集中于TREC技术本身及其适用范围, 以及风暴预报方案中处理细节的不足, 具体为TREC技术不适用于孤立的回波单体, 雷达探测边界对TREC技术的影响, TREC矢量有时呈现出一定的空间不连续性, 以及对孤立少动单体的不当处理等。针对上述原因, 提出了一系列的改进方案, 包括对用于风暴位置预报的TREC矢量增加一致性检验, 利用风暴的历史轨迹校正不恰当的TREC矢量; 对TREC技术中象素阵列大小进行统计分析, 选择最适合北京地区的阵列大小; 风暴预报位置超出回波范围时新的处理技巧等。利用北京奥运期间的强对流资料, 对改进后的风暴算法进行评估。结果表明, 一方面, 改进后的算法能较好地控制风暴预报位置的绝对误差, 在30 min和60 min预报时效, 绝对误差分别减小了25%和26%。另一方面, 由于预报位置精度的提高, 能够提升相邻时刻风暴匹配的效率, 使得与以前算法相比有更多的风暴样本参与了各个预报时效的评分。     

On the swelling potential of compacted high plasticity clays

We conducted a study of the spatial distributions of seismicity and earthquake hazard parameters for Turkey and the adjacent areas, applying the maximum likelihood method. The procedure allows for the use of either historical or instrumental data, or even a combination of the two. By using this method, we can estimate the earthquake hazard parameters, which include the maximum regional magnitude Mˆ_max, the activity rate of seismic events and the well-known bˆ value, which is the slope of the frequency-magnitude Gutenberg-Richter relationship. These three parameters are determined simultaneously using an iterative scheme. The uncertainty in the determination of the magnitudes was also taken into consideration. The return periods (RP) of earthquakes with a magnitude M ≥ m are also evaluated. The whole examined area is divided into 24 seismic regions based on their seismotectonic regime. The homogeneity of the magnitudes is an essential factor in such studies. In order to achieve homogeneity of the magnitudes, formulas that convert any magnitude to an M_S-surface scale are developed. New completeness cutoffs and their corresponding time intervals are also assessed for each of the 24 seismic regions. Each of the obtained parameters is distributed into its respective seismic region, allowing for an analysis of the localized seismicity parameters and a representation of their regional variation on a map. The earthquake hazard level is also calculated as a function of the form Θ = (Mˆ_max,RP_6.0), and a relative hazard scale (defined as the index K) is defined for each seismic region. The investigated regions are then classified into five groups using these parameters. This classification is useful for theoretical and practical reasons and provides a picture of quantitative seismicity. An attempt is then made to relate these values to the local tectonics.     

基于NSCT与改进SIFT特征点的GF-2影像水印算法

现有基于SIFT特征点的水印算法因特征区域重叠导致算法鲁棒性较差,不能满足GF-2影像版权保护的需求。该文采用Mean Shift对SIFT特征点进行优化和改进,提出一种基于NSCT与改进SIFT特征点的GF-2影像数字水印算法。首先,提取GF-2影像的SIFT特征点,采用Mean Shift对其进行聚类处理,将所有聚类中心作为影像的关键点,并计算关键点的平均SIFT描述符,以保证所生成的影像关键点具有与SIFT特征点相同的特征属性;其次,根据关键点构建影像的特征区域,并对其进行几何归一化处理;最后,对特征区域进行NSCT分解,选择低频子带进行奇异值分解,根据加性规则将水印信息的奇异值嵌入低频子带的奇异值中,并通过相应的逆变换得到含水印影像。与其他算法对比验证结果表明,该算法既具有良好的不可见性,又对常规攻击以及旋转、裁剪、缩放等几何攻击具有较好的鲁棒性,且能有效减轻特征区域的重叠现象,适用于GF-2影像的版权保护。     

平均血小板体积变化在急性胰腺炎中的临床意义及治疗效果评估价值

目的 探讨平均血小板体积等参数在急性胰腺炎病程中变化的临床意义及其对治疗效果评估的价值。方法 回顾性分析53例轻症急性胰腺炎（MAP）患者、25例重症急性胰腺炎（SAP）患者和40例健康者（对照组）的临床资料,检测平均血小板体积（MPV）、血小板计数（PLT）、血小板分布宽度（PDW）、白细胞计数（WBC）、C反应蛋白（CRP）及血清钙离子浓度（Ca²⁺）等指标。比较并分析上述指标在急性胰腺炎病程中及治疗前后的变化。结果 与对照组比较,急性胰腺炎患者入院时MPV显著升高,差异具有统计学意义（P<0.05）;与MAP组比较,SAP组入院时MPV明显升高,差异具有统计学意义（P<0.05）;SAP组中,MPV在入院后第3天较入院时进一步升高,至入院第5天、第7天逐渐下降;SAP组中,MPV在病程中各时间点与MAP组比较均显著升高,差异有统计学意义（P<0.05）;与治疗前比较,急性胰腺炎患者治疗后MPV显著降低,差异有统计学意义（P<0.05）。结论 急性胰腺炎患者平均血小板体积与病情严重程度及治疗效果相关。